Navegando por Assunto "Agregado sintético"
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Item Acesso aberto (Open Access) Caracterização mineralogica do agregado obtido a partir da lama vermelha do processo bayer(Universidade Federal do Pará, 2014-12-27) REIS, André Wilson da Cruz; NEVES, Roberto de Freitas; http://lattes.cnpq.br/9559386620588673; MARTELLI, Marlice Cruz; http://lattes.cnpq.br/1213009262936026The industrial activities increasingly generate a lot of waste and by-products being stored in the environment, with physicochemical characteristics which can most often be reused. The red mud residue from the Bayer process, is being studied for use in the production of synthetic aggregates, which aims to replace natural aggregates used in construction. This work studies the physical, chemical and mineralogical characteristics of the aggregates synthesized from a mixture of red mud, clay, sand and charcoal in 4 compositions, varying amounts of red mud and clay. The raw materials were pretreated and analyzed by X-ray fluorescence, X - ray diffraction, thermal and particle size analysis. The samples were calcined at 1200 °C for 4 hours. Then subjected to analysis by X-ray diffraction, X- ray fluorescence, differential thermal analysis and scanning for characterization and physical tests electron microscopy. For the study of the observation of synthetic mullite aggregate specimens embedded in resin, and adding 5% HF for 3 to 4 minutes were made. The material presented after sintering, apparent specific gravity average below 2 g\cm3 main crystalline phases by XRD quartz and hematite and the presence of mullite from the HF treatment can be observed.Item Acesso aberto (Open Access) Concreto com utilização de agregado graúdo sintético produzido a partir da lama vermelha: estudos de dosagem, propriedades e microestrutura(Universidade Federal do Pará, 2013-08-13) ROSÁRIO, Kátia Alrelhia do; MACEDO, Alcebíades Negrão; http://lattes.cnpq.br/8313864897400179Currently sustainability issues have gained prominence on the world stage in various sectors of society. Several researchers (LIMA, 2006; Hildebrand, 1998; SOUZA, J., 2010, ROSSI, 2009, etc..) Have tried to propose an interaction between the construction industry and those who engage in mineral production and processing, such as the beneficiation of bauxite. In this context, finding viability for the recovery of waste generated in large quantities and no use would contribute to the preservation of the environment, insofar as it would reduce consumption of resources from natural sources and increase the supply of inputs in construction market. This work is discussed the feasibility of producing a concrete, it has characteristics which renders itself to use as raw material in the construction industry, by using an synthetic aggregate obtained from the red mud (bauxite waste improvement) . According to the experimental program to be executed, the aggregates and the concrete produced will have their properties analyzed in order to study the production process and measurement respectively. Aggregates are analyzes of: porosity, water absorption, bulk density and Los Angeles abrasion and concrete, workability, density in fresh and hardened, compressive strength, tensile strength by diametrical compression, tensile bending, water absorption and elastic modulus. It is noteworthy that significant importance is given to the transition zone paste / aggregate, by analysis of the microstructure of concrete produced. Analysis is performed by means of tests: Mercury intrusion porosimetry (MIP) and Scanning Electron Microscopy (SEM). The results of the analyzes of the synthetic aggregates and concrete produced satisfactory results, showing that they have potential for use in the construction industry.Item Acesso aberto (Open Access) Estudo da influência do óxido de cálcio nas reações de estado sólido na produção de agregado cerâmico a base de aluminossilicatos e resíduo do processo Bayer(Universidade Federal do Pará, 2023-02-10) BRITO, Carlos Eduardo Costa; SOUSA, Jose Antonio da Silva; http://lattes.cnpq.br/6157348947425968; MACÊDO, Emanuel Negrão; http://lattes.cnpq.br/8718370108324505The most important worry involving the generation of industrial waste is associated with the effects those materials can have on the environment and human health, considering that the dangerous waste produced by the industry requires particular care and attention, because if managed improperly, it can become a serious environmental threat. Therefore, this paper demonstrates the studies conducted to recycle the residue from the Bayer process, as a raw material in the production of synthetic aggregate, intended for civil construction. Furthermore, this paper has analyzed the influence of calcium oxide in the solid state reactions during sintering in the production of ceramic aggregates based on residue from bauxite processing because this oxide, besides being a melting material, also influences the formation of glass with lower viscosity, and may positively influence the mechanical strength of the material. For the conformation of the aggregates a composition based on bauxite residue and silica was adopted with and without the addition of calcium oxide. The pellets were produced in a rotating cylinder and sintered at temperatures of 1180, 1200 and 1250 °C with a burn time of 3 hours. For the characterization of the raw materials the techniques of X-ray Fluorescence (XRF), X-ray Diffraction (XRD), Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TG) were employed. For the characterization of the aggregate, scanning electron microscopy (SEM), XRD and DSC tests were performed on the formulations composed of bauxite residue and clay with and without the addition of calcium oxide. The physical and technological properties determined were: Water absorption, apparent porosity and apparent specific mass. The results of this paper indicate that bauxite residue can be used as a source of alternative raw material for the production of synthetic ceramic aggregate. The results obtained also prove that the use of calcium oxide directly influenced the solid state reactions, especially in the mullite formation reaction. Therefore, the production of synthetic aggregate with the addition of calcium oxide proved to be a promising destination for the Bayer process residue.Item Acesso aberto (Open Access) Estudo da reciclagem de cinza volante para produção de agregado sintético utilizando reator de leito fixo(Universidade Federal do Pará, 2016-02-16) PEREIRA, Luiz Felipe Silva; SOUZA, José Antônio da Silva; http://lattes.cnpq.br/6157348947425968The use of such industrial waste boiler fly ash for recycling and reuse, has intensified in recent years much for its physico-chemical characteristics that may result after the processing, in a material with good mechanical strength and can be designed for use in several areas such as construction. In this paper we obtain synthetic aggregates, after sintering process in a fixed bed reactor. For the production of aggregates pellet sewed up mixer from a mixing wheel boiler ash, clay and charcoal. After the process of ceramic sintering were measured material properties such that: porosity, density and water absorption. For the characterization of phases and mineralogical structures of the sintered material, we used the techniques of X-ray diffraction and scanning electron microscopy. Thus the contribution of this work is aimed at reducing environmental impacts, due to the possibility that the material produced has to replace natural aggregates.Item Acesso aberto (Open Access) Estudo da reciclagem de lodo de eta na fabricação de agregado sintético em mistura com cinza volante de carvão mineral(Universidade Federal do Pará, 2016-11-22) SILVA, Elzelis Muller da; SOUZA, José Antônio da Silva; http://lattes.cnpq.br/6157348947425968The Wastes (sludge) generated in the Water Treatment Plants (WTP) and fly ash from coal-fired power plants cause problems by the amount and concentration of harmful substances in them. Thus, this study aimed to produce synthetic aggregates using sludge WTP Bolonha (Belém/PA) and fly ash assessing their technical and environmental viability. The composition of the synthetic aggregates consisted of a high concentration of these residues in mixture with clay to molding and sintering at temperatures of 1200°C and 1250°C. The physical, mineralogical and microstructural analyzes of the synthetic aggregate were performed. Two concrete were produced, one with synthetic aggregate, and other references. In concrete were assessed their physical and mechanical properties in fresh and hardened state, and their microstructures. For the characterization of the concrete waste leaching and dissolution testing were performed. Synthetic aggregates were classified as lightweight aggregate for its low bulk density (<2.0 g / cm3) according to NBR 7211 (ABNT, 2009). The concrete produced with sintered aggregate (AGS-02) at 1250 °C was classified as non structural lightweight concrete according to the norms NBR 6118 (ABNT, 2014) and NBR 8953 (ABNT, 2015). The concrete of waste were classified as waste class IIB, non-hazardous and inert by NBR 10004 (ABNT, 2004) and within the limits of Resolutions No. 20/1986 and 430/2011 CONAMA into rivers class 2. It is noteworthy the synthetic aggregate meets the demands of the construction industry, reduces the consumption of raw materials and offers an alternative to the final disposal of waste.Item Acesso aberto (Open Access) Estudo da sinterização em reator vertical de leito fixo para produção de agregado sintético(Universidade Federal do Pará, 2017-06) QUARESMA, Danielly da Silva; NEVES, Alacid do Socorro Siqueira; MELO, Alvino Oliveira; PEREIRA, Luiz Felipe Silva; BEZERRA, Pamela Tais Silva; MACÊDO, Emanuel Negrão; SOUZA, José Antônio da SilvaThe synthetic aggregates are being employed in civil construction for the reduction of mineral extraction activities. Within this context, the recycling of industrial waste is the basis of the majority of processes to reduce the exploitation of mineral resources. In this work the sintering in a vertical fixed bed reactor for synthetic aggregate production using 20% pellets and 80% charcoal was studied. The pellets were prepared from a mixture containing clay, charcoal and fly ash. Two experiments varying the speed of air sucking were carried out. The material produced was analyzed by X-ray diffraction, scanning electron microscopy, measures of their ceramic properties, and particle size analysis. The results showed that the solid-state reactions, during the sintering process, were efficient and the produced material was classified as coarse lightweight aggregate. The process is interesting for the sintering of aggregates, and can be controlled by composition, particle size, temperature gradient and gaseous flow.Item Acesso aberto (Open Access) Estudo da sinterização em reator vertical de leito fixo: desenvolvimento de processo para produção de agregado sintético a partir de cinza volante e biomassa(Universidade Federal do Pará, 2016-05-19) QUARESMA, Danielly da Silva; SOUZA, José Antônio da Silva; http://lattes.cnpq.br/6157348947425968; MACÊDO, Emanuel Negrão; http://lattes.cnpq.br/8718370108324505The synthetic aggregates have been employed in civil construction as a measure for the reduction of mineral extraction. Within this context, the recycling of industrial waste configured today as the basis of the majority of processes to reduce the exploitation of mineral resources. This paper presents the formulation of a process of environmental character and self-sustaining from an energy point of view parameters to develop a process for the production of synthetic aggregate from fly ash and biomass fixed bed reactor. Thus, for the production of aggregate pellets were made from a mixture of clay, fly ash and charcoal in fixed proportions. The reactor is filled with 20% pellets (6.35 mm > pellet ≥ 4 mm) and 80% charcoal (3.36 mm > carbon ≥ 1.70 mm) rated for promoting the efficiency of combustion reactions and subsequent sintering process at different air velocities (Darcy at 20 °C) of 0.0059 m.s-1 (1º Experiment), 0.0098 m.s-1 (2º Experiment) and 0.017 m.s-1 (3º Experiment). By means of X-ray diffraction and scanning electron microscopy was identified the presence of mullite in synthetic aggregate. This material is characterized as lightweight aggregate, in accordance with current standards. With synthetic aggregates manufactured to lightweight concrete, according to the established standard, without structural function in civil construction, but with applications of moderate resistance and may be used in the counterfloor. The process if showed interesting for the sintering of aggregates with good adhesion to the matrix of cement, and can easily be controlled by composition, granulometry, temperature gradient and gaseous flow, reducing environmental impacts, to the extent that the material produced implies in not extraction of natural aggregates.Item Acesso aberto (Open Access) Influência da sílica e da temperatura nas propriedades físicas dos agregados sintéticos produzidos com resíduo do processo bayer(Universidade Federal do Pará, 2019-03-21) SANTOS, Diego Hildebrando dos; SOUZA, José Antônio da Silva; http://lattes.cnpq.br/6157348947425968The use of waste from the mining and metallurgy industry has become indispensable, so that this industrial segment is inserted in the concept of sustainable development. The work shows an application for red mud that, in combination with other materials such as silica and clay, produces a material with mechanical resistance and specific mass, which can be compared to the natural aggregates used by the civil construction industry. In the work all the raw materials and the final sintered product were submitted to x-ray diffraction analysis, scanning electron microscopy. Red mud and clay were also analyzed by x-ray fluorescence. The synthetic aggregates were produced with the intention of studying the relationship between the amount of silica used and the apparent specific mass, which had satisfactory results on sintered specimens at 1300 ° C, obtaining heavy aggregates with 10% silica and aggregates with values below 2 g/cm3 with 20% and 30% silica samples, characterizing so the aggregate as light. Therefore, the silica content, the amount of clay used together with the oxides present in the red mud, together with the ideal granulometry of these materials and the temperature, form a glassy phase that will give the aggregates important characteristics such as porosity, mechanical strength and apparent specific mass.Item Acesso aberto (Open Access) Produção de agregados sintéticos para construção civil a partir de materiais geopoliméricos(Universidade Federal do Pará, 2023-06-20) CRUZ, Kamila Sindy Pinheiro da; SILVA, Alisson Clay Rios da; http://lattes.cnpq.br/7389345867032737; http://lattes.cnpq.br/7389345867032737The civil construction industry is one of the sectors of the economy that consume the most natural resources, from the production of inputs to the execution of the work, which can significantly affect the environment and the quality of life of the population. Geopolymers are inorganic polymers with great ecological potential, produced from aluminosilicates and synthesized by alkaline solutions, providing the material with better mechanical resistance. Geopolymeric cement is a high-tech material developed using clay minerals, with characteristics such as durability, mechanical resistance, strong adhesion, heat resistance, in addition to being easily mixed and applied. The present study sought, through a correct proportion of the components that constitute the geopolymer, the production of a Geopolymeric Synthetic Aggregate (ASG), making variations with percentages of blast furnace slag and variations in the alkaline concentration of sodium hydroxide (NaOH). Soon after, physical tests were carried out on the powdered materials to verify the fineness index, loss on fire and moisture content of kaolin, metakaolin and blast furnace slag. The samples underwent characterization and the main analyzes involved in the process were: X-ray diffraction (DRX), infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and EDS. A compression test was also carried out on the geopolymer synthetic aggregate specimen. The results of the compressive strength test indicated that the specimen with a percentage of 35% blast furnace slag and an alkaline concentration of sodium hydroxide at 10 molar presented better results. In the analysis of the microstructure of the paste, a dense morphology was observed, which gives the material high resistance to compression.