Navegando por Assunto "Amazonian"
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Dissertação Acesso aberto (Open Access) Avaliação microestrutural e mecânica das fibras de cotia e dos compósitos de matriz poliéster(Universidade Federal do Pará, 2025-01-20) NASCIMENTO, Damares da Cruz Barbosa; OLIVEIRA, Michel Picanço; http://lattes.cnpq.br/6383844066460475; https://orcid.org/0000-0001-9241-0194; CANDIDO, Verônica Scarpini; http://lattes.cnpq.br/8274665115727809; https://orcid.org/0000-0002-3926-0403The search for sustainable and low-cost materials has driven the use of natural fibers in the development of polymer composites, due to their mechanical and sustainable properties. The aim of this work is to study and characterize a new natural fiber, as well as to study the mechanical properties of composites made with in natura fibres (FC) and mercerized fibres (FM) in volumetric percentages of 10, 20 and 30%. The fibres and composites were characterized using Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Thermogravimetry (TGA), Scanning Calorimetry (DSC), Energy Dispersive Spectroscopy (EDS) and Raman Spectroscopy, as well as mechanical characterization. The physical characterization of the fiber indicated an average density of around 0.34 g/cm3. The FTIR of the FC and FM fibers indicated chemical structural changes, which were confirmed with Raman, SEM and EDS. The thermal stability of Cotia fiber in natura was close to 145 and 272 ºC. The mechanical properties of the FC and FM fibers showed average strengths of around 151.32 and 99.98 MPa, respectively. The FTIR and Raman scans of the composites showed few changes related to the variation in chemical treatment, but differences when percentages of fibers were added. The tensile and flexural results indicated that the CF fibers were stronger and stiffer in relation to the matrix than the modified fibers. The SEM confirmed the existence of defects and flaws that caused early rupture of the composites with FM fibers. The single and double F ANOVA confirmed that both factors, chemical modification and increase in volume percentage, had an impact on the final properties. Although the results of the FM fibers did not have a positive impact, the properties of the in natura fibers stand out as efficient reinforcements for engineering applications.Dissertação Acesso aberto (Open Access) Caracterização de tintas industriais aplicadas na região amazônica a partir de análises físico-químicas, mecânicas e de durabilidade(Universidade Federal do Pará, 2024-02-28) LUCAS, Mathaus Moraes; SILVA, Alisson Clay Rios da; http://lattes.cnpq.br/7389345867032737; https://orcid.org/0000-0001-9186-2287In Brazil, the industrial sector of paints and varnishes is among the five largest in the market. The manufacture of paints for various applications, with technology and technical responsibility, equals the most advanced global production centers. The durability of a paint refers to its resistance to weathering. For weathering, a weather-resistant paint is necessary so that fading does not occur on the substrate where it will be used, which can occur among some factors, due to the incidence of sunlight and heavy rains. The North region, with high rainfall, influenced by instability lines, presents significant spatial and seasonal heterogeneity of rainfall and has the highest annual rainfall total. Given this reality, a paint commercially applied in the Amazon region was developed. In the standard formulation, variations of mineral loads (Kaolin, Dolomite and Precipitated Calcium Carbonate) were made and subsequently analyses and tests were carried out to evaluate the performance of this paint, compared with the original formulation, such as abrasion resistance and weathering resistance. The paint production methodology will be according to Castro (2009) using Hare’s technique (1974). The characterization of the paints in the fresh state was carried out through the Viscosity, pH and specific weight tests, while the characterization of the paints in the hardened state was carried out through the abrasion resistance tests, weathering resistance test and Scanning Electron Microscopy. The physico-chemical tests revealed that, in relation to Stormer viscosity, all formulations exceeded the standard (130 KU), with the exception of the paints containing 30% Dolomite, 15% PCC, 15% Dolomite and the ternary combination of 5% Kaolin, 5% Dolomite and 20% PCC. As for the specific weight, the formulation that came closest to the standard was the binary paint with 15% Kaolin and 15% PCC, presenting an average value of 1.43 g/cm³. In terms of pH, all formulations showed alkalinity, with values ranging between 7.5 and 9.6. After a period of exposure of 180 days, none of the mixtures, including the standard formulation, showed the formation of pathologies, demonstrating resistance to weathering. The formulations with 30% Dolomite; 15% PCC and 15% Dolomite; 5% PCC, 5% Kaolin and 20% Dolomite; 10% Kaolin, 10% PCC and 10% Dolomite, exhibited respectively 300, 290, 240, 270 cycles of abrasion resistance, indicating the potential of these paints for a variety of applications, such as floor paints, external paints and road paints.Artigo de Periódico Acesso aberto (Open Access) Diagnóstico da qualidade da água do rio Parauapebas (Pará - Brasil)(Instituto Nacional de Pesquisas da Amazônia, 2012-09) SIQUEIRA, Gilmar Wanzeller; APRILE, Fábio Marques; MIGUÉIS, Antonio Miguel BorreganaThe objective of this research was to develop a diagnostic of the water quality of the Parauapebas River (Pará, Brazil), in the dry periods of 2004, 2007 and 2009. In 20 sampling sites in Parauapebas River, around of the Parauapebas City, physical (transparency, water temperature and total solid residues), chemical (dissolved oxygen, pH, turbidity, alkalinity, hardness, acidity, chloride, Biochemical Oxygen Demand, Chemical Oxygen Demand, total phosphorus, total iron and total nitrogen), and biological parameters (thermotolerant coliforms) were measured. The results were used for the determination of Water Quality Index (WQI). As support to the interpretation of these parameters, a Principal Components Analysis (PCA), multiple regression and linear regression analyses and, a general survey of physical, biotical and social-economic of the region were performed. WQI for the Parauapebas River, in the monitored area, was 40.01, which classifies it in the category "Regular". The PCA and multiple regression analysis identified four parameters that have been employed in the WQI determination and that influenced significantly the variation of the Index: dissolved oxygen, BOD, total phosphorus and thermotolerant coliforms, which explained 75% of the variation of the results. The results indicate that the urban expansion, in especial in the directions N-NW and S-SW, has reached the areas surrounding the Riparian Forest, and affected partially the surface water quality of the Parauapebas River.Artigo de Periódico Acesso aberto (Open Access) Distribuição de mercúrio total em sedimentos da plataforma continental Amazônica: Brasil(Instituto Nacional de Pesquisas da Amazônia, 2012-06) SIQUEIRA, Gilmar Wanzeller; APRILE, Fábio MarquesThis study was developed at the Amazon Continental Shelf aims to determine the levels of total mercury in the sediment bottom, and them to contribute as environmental matrix for the general plan of coastal monitoring in the North Region of the Brazil. Twenty sampling sites between May and June from 1999 to 2002, 2005 and 2007 were analyzed. The results indicate there is not evidence of anthropic activities associated to the contamination by mercury in the region. The levels of total mercury founded range between 0.047 and 0.166 mg kg-1 with average of 0.085±0,026 mg kg-1. The results are inside of the background interval determined to not contaminated or not polluted Amazon Rivers, which the interval ranges from 0.05 to 0.28 mg kg-1. The mercury concentrations in the sediment bottom, especially in the mud sediment, had shown a narrow dependence with both the clay levels (fine material) and organic matter, corroborating important geochemical mechanisms in Hg dynamics. The largest adsorption of the mercury can be associated to the increase of the oxides and hydroxides compounds of iron, aluminum, manganese and others primary and secondary minerals from the rocks of the Amazon drainage basin.Dissertação Acesso aberto (Open Access) Redes e vigilância no Xingu: a reconfiguração do território ribeirinho(Universidade Federal do Pará, 2022-04-29) BAITELLO, Clara Bezerra de Menezes; HERRERA, José Antônio; http://lattes.cnpq.br/3490178082968263; https://orcid.org/0000-0001-8249-5024This work examines how the construction of the Belo Monte Hydroelectric Dam at Xingu River, in Altamira city, Pará state is transforming the relationship between ribeirinhos, riverine people, and their traditional territories. Before the dam, the riverine people maintained relative territorial and social-economic autonomy. Since the construction of Belo Monte, the State and private companies are abusing their power in an attempt to gain territorial control and influence local dynamics. Subsequently, land-use planning in the region is changing. Previously organized by the ribeirinhos according to their own rules and subsistence needs, the land is now regulated by new private actors, impacting and altering the nature and purpose of the communities’ traditional activities. In order to conduct this analysis, I use the dialectical method due to its ability to analyze the contradictions of the territory.
