Navegando por Assunto "Chemical balance"

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Acesso aberto (Open Access)
Predição do desempenho de gasificadores de biomassa utilizando equilíbrio químico
(Universidade Federal do Pará, 2007-08-10) OLIVEIRA, Antônio Geraldo de Paula; NOGUEIRA, Manoel Fernandes Martins; http://lattes.cnpq.br/2324813094737469
The gasification technology has been object of study of many researchers, especially those involved in power generation use biomass. This paper presents a simplified model for biomass gasification based on chemical equilibrium considerations. The model consists in the minimization of the Gibbs free energy of the produced gas, constrained by mass and energy balances for the system. Despite the simplicity of the model, its results are reliable in identifying the tendencies of the working parameters for the system. Biomass composition, gasification temperature (air supplied), moisture content, air temperature, and heat losses are parameters that may be varied in order to evaluate different operational points. Results obtained are compared to those found in real operation of gasification processes and they shown good agreement.
Acesso aberto (Open Access)
Simulação numérica da gaseificação de biomassa em leito fixo
(Universidade Federal do Pará, 2011) ITAI, Yuu; MALICO, Isabel; BRASIL, Augusto César de Mendonça; http://lattes.cnpq.br/0571960641751286
The objective of this study was to evaluate the potential of açaí seeds rejected after processing in Belém - Pará, in order to be used as a source of biomass for energy production by gasification. Elemental analysis results obtained in LABCAT - UNB on a dry basis were obtained with percentages of Carbon, 46.06% Hydrogen, 6.01%, Oxygen, 43.37% , Nitrogen 4.33%and Sulfur 0.08%. These values and other parameters obtained in an experimental study carried out by the studies of Santos (2011) and Cruz (2010), were used to perform a numerical simulation of the gasification process by means of a zero dimensional FORTRAN code developed specifically for this purpose. Variations of the influence of equivalence ratio and moisture content in the concentrations of CO, H2 and CH4 were compared with experimental results. A transient one-dimensional model developed by Hla (2004) was also analyzed. Using the application of a mechanism of two steps pyrolysis where the primary tar (or oxygenated) are initially formed and then cracked into secondary tar (or oil) and other combustible gases. Thus is revealed the complexity of physical and chemical processes that occur in the reactor by the use of energy and mass balance information and rates of chemical reaction of the recommendations and the physical transport processes. The computer model can predict the profile of the gas composition, temperature, primary and secondary tar along the longitudinal axis of the gasifier. Data results have been obtained from both models and after the phenomena behaviour was analyzed in comparison with the experimental data obtained by Santos (2011).