Navegando por Assunto "Hidrotermalismo"

Agora exibindo 1 - 4 de 4

Acesso aberto (Open Access)
Caracterização mineralógica com espectroscopia de reflectância por infravermelho (SWIR): exemplo do Complexo máficocarbonatítico Santana, sul do Cráton Amazônico
(Universidade Federal do Pará, 2021-09-21) COSTA, Jhoseph Ricardo Costa e; FERNANDES, Carlos Marcello Dias; http://lattes.cnpq.br/0614680098407362; https://orcid.org/0000-0001-5799-2694
On the border of the Pará and Mato Grosso states, in the Amazonian Craton, municipality of Santana do Araguaia (PA), there is a volcano-plutonism named Santana mafic-carbonatitic complex. This set houses the Serra da Capivara phosphate deposit. A lower mafic-ultramafic member reveals plutono-volcanic lithofacies with pyroxenite, ijolite, apatitite, and alkaline basalt. Autoclastic lithofacies contains poorly selected deposits of massive polymictic breccia, lapilli-tuff, crystal tuff, and ash tuff. Volcanogenic epiclastics rocks cover these lithofacies. The upper carbonatite member contains plutonic lithofacies with coarse calcite-carbonatite (sövite). Fine carbonatite veins with pervasive carbonatic and apatitic alterations crosscut this lithotype. Minor thick apatitite occcurs associated to this member and represents the protore of the deposit. Effusive volcanic lithofacies reveals fine calcite-carbonatite (alvikite) with porphyritic, equigranular, or aphanitic textures. A poorly sorted lithofacies of crystals tuff, lapilli-tuff, and massive polymictic breccia completes this member. Stocks and syenitic dykes invade these lithofacies. Detailed mapping suggests that the complex is a volcanic caldera in which large zones of hydrothermal alterations occur with reddish, brownish red, and yellowish carbonatitic rocks. Petrographic observations reveal paragenesis of barite + fluorapatite + calcite + dolomite ± quartz ± rutile ± chalcopyrite ± pyrite ± monazite ± magnetite ± hematite. The application of short wave infrared spectroscopy (SWIR) revealed the chemical characteristics and their importance in the crystallinity of most of these hydrothermal minerals, such as radicals (OH- and CO3), H2O molecule, and cation-OH bonds such as Al-OH, Mg-OH, and Fe-OH. The main mineral phases identified were dolomite, calcite, serpentine, chlorite, muscovite with low, medium, and high aluminum, montmorillonite (Ca and Na), illite, nontronite (Na0.3Fe2((Si,Al)4O10) (OH)2·nH2O), and epidote. The data suggest a control by temperature, fluids composition, and fluid/rock ratio during the evolution of the Santana mafic-carbonatitic complex. This low-cost exploratory technique, which is applied in hand-held samples or drill holes on a large scale, is promising in characterization of volcano-plutonic centers in regions subjected to severe weathering conditions, as well as helping to develop models for prospecting mineral deposits of Rare Earth Elements (e.g. Nd, La) associated with alkaline-carbonatitic complexes. We can even combine this tool with artificial intelligence algorithms for more robust and faster results.
Acesso aberto (Open Access)
Greisens e Epi-sienitos potássicos associados ao granito água boa, Pitanga (AM): um estudo dos processos hidrotermais geradores de mineralizações estaníferas
(Universidade Federal do Pará, 2002-10-23) BORGES, Régis Munhoz Krás; DALL'AGNOL, Roberto; http://lattes.cnpq.br/2158196443144675
Three stanniferous greisen types were characterized in the western border of Água Boa pluton, Pitinga mine (AM), associated with the rapakivi granite facies: greisen 1 (Gsl), composed mainly by quartz, topaz, brown siderophyllite and sphalerite; greisen 2 (Gs2), composed essentially by quartz, phengite and chlorite; greisen 3 (Gs3), composed of quartz, fluorite and phengite, with minor green siderophyllite. Besides these rocks, a potassic episyenite (EpSK) was identified associated with the Gs2. In spite of the compositional and petrographic differences, all of these hydrothermal rocks derived from a same protholith, a hornblende biotite aikali feldspar granite to syenogranite. The Gsl shows an inner mineralogical zoning defined by topaz or siderophyllite predominance. Along drill cores, the siderophyllite-rich zone occurs near the contact with the greisenized grafite and the topaz-rich zone is situated far from the grafite contact. The brown siderophyllite displays moderated Al contents, and its compositional changes can be explained by Fe+2 substitution for A1+3 and Li in octahedral sites, with a coupled Al+3 substitution for Si+4 in tetrahedral sites. The mineralogical zones in the Gs2 are physicaliy separated in leveis with phengite or chlorite predominance. The mica of Gs2 is a phengite, whose chemical variation is due to substitution of viAl for Fe+2, coupled with Si+4 enrichment. The calculated Li contents in phengites are lesser than those estimated in siderophyllite. The green siderophyllite from Gs3 is VIAl richer and F poorer than Gs1 brown siderophyllite, and the phengite displays two compositional types: an early Fe+2-poor aluminous phengite and a later Fe+2- F-rich one whose chemical variation is similar to that of Gs2 phengite. The chlorite from the three greisen is a Fe-rich daphnite, and its compositional range is due to VIAl substitution for R+2 cations, coupled with Si+2 enrichment. The aluminous chlorite displays higher temperature formation than ferrous one, according to the geothermeter proposed in the literature. The Pitinga greisens were formed by different processes of interaction among three main fluids: (1) low salinity, F-rich, aquo-carbonic fluid, with initial temperatures between 400° -350°C, present during Gsl and Gs3 formation; (2) low salinity aqueous fluid, with a temperature around 300°C, which during a progressive salinity increasing process, originates a moderate to high salinity residual fluid, with temperatures between 200° - 100°C, present during the Gs2 formation and silicification stage of EpSK; (3) low salinity aqueous fluid, with temperatures between 200° - 150°C, which interplayed with the others two fluids in differents grades, contributing to the formation of ali the hydrothermal rocks. The first two fluids has seemingly an orthomagmatic origin while the latter has a surface characteristic (meteoric water?). Moreover, the data suggests that the fluid responsible by the initial stage of the episyenitization process was not registered in the studied samples. These fluids were trapped in pressure conditions around 1 Kbar, representing high crustal levels conditions, similar to that of the stanniferous granites from Pitinga. Both episyenitization and greisenization processes occurred without volume changes in the granitic protholith, and the density differences of the altered rocks were caused by the mass variations along the alteration processes. The greisenization process caused a extensive loss of Na2O and K2O, while SiO2 showed a immobile behaviour in Gsl but was parcially removed in Gs2. The Al2O3 was depleted during the Gs2 formation but added in Gsl. The Fe2O3 (Fe total), Sn, S, volatiles LOl and F were the responsible by the mass increase at greisenization. In the Gsl, the chemical changes in the fiuids were caused by F activity decrease and fO2 increase during cooling. These changes also originated the differentiation between the ZT, in the inner portions of the fratures/conducts, and the ZS, nearest to surrounding gravite. The Gs3 was formed in more oxidizing conditions by F-poorer fiuids than those trapped in the ZS. The dissolution cavities generated during the episyenitization process increased the permeability of the altered rocks, providing an increase of fluid/rock ratios in the EpSK and Gs2 sites. The interaction between aqueous fluid and EpSK feldspar, during the Gs2 formation, caused a continuous salinity increase. The ZF was formed in the early stages of this interaction, at higher temperatures, while the ZC was originated by the more cold and saline, residual fluid. The latter was also trapped in the quartz filling cavities in the EpSK during the later silicification stage. In this way, the greisens and the potassic episyenites were generated from interactions among, at least, three fluids of seemingly independent origin, from a same protholith, in shallow crust conditions. The fO2, F activity and salinity variations, during the hydrothermal system cooling, and the contrast in fluid/rock ratios caused by permeability differences, were very important factors to greisen differentiation. These factors controlled greatly the fluids compositional changes, and caused the cassiterite and sulphides precipitation in the greisens and the Sn- S-enrichment during later greisenization of EpSK.
Acesso aberto (Open Access)
Petrografia, alterações hidrotermais e eventos mineralizantes do Bloco Norte do depósito aurífero Volta Grande, Domínio Bacajá (PA), Cráton Amazônico
(Universidade Federal do Pará, 2021-09-22) SOUZA, Hugo Paiva Tavares de; VASQUEZ, Marcelo Lacerda; http://lattes.cnpq.br/4703483544858128; https://orcid.org/0000-0003-2729-9404; FERNANDES, Carlos Marcello Dias; http://lattes.cnpq.br/0614680098407362; https://orcid.org/0000-0001-5799-2694
The southeastern region of the Amazonian Craton has been the target of several mineral survey programs over the past few years, which have recently led to the identification of the world-class Volta Grande gold deposit, with reserves of ~3.8 Moz at 1.02 g/t, which provides an expectation of 17 years of operation. The deposit is in the municipality of Senador José Porfírio in Pará and is housed in Rhyacian granitoids (2.15 Ga) that occur associated with the volcano-sedimentary Siderian sequence (2.45 Ga) of the Três Palmeiras Group. These units are in the Bacajá Domain, which is formed by belts of high-grade para- and orthoderived rocks and greenstone belt of Archean to Siderian protoliths, reworked during the orogenesis of the Transamazonian Cycle (2.26–2.06 Ga). Granitoids and charnockites sectioned this set in Rhyacian. Part of the mineralization at the Volta Grande is housed in granitoids metamorphosed under medium to high-grade conditions. Local kinematic indicators suggest dip-slip movement in which the greenstone moves up relative to the intrusive rocks. Petrographic descriptions carried out in this work revealed: 1) gray to greenish mylonitic granodiorite, with intense deformation of the main minerals that make up them, such as quartz, biotite, and feldspars. The texture in this lithotype is mainly porphyroclastic. Main metamorphic foliation (S1) is defined by biotite and amphibole, as well as reveals concordant quartz veins and venules. The highest gold contents are distributed in upper amphibolite facies zones. In these, the ore occurs mainly as isolated grains in cm-sized quartz veins and venules associated with pervasive carbonatic alteration that was synchronous to dynamic metamorphism, as well as in a fracture-controlled style. Part of the gold is also associated with a low sulfides content disseminated in the veins and host rock; 2) The metamafic rocks comprise foliated fine- to medium-grained amphibolite and andesite with a dark grayish-green color and nematoblastic texture. Chlorite, calcite, sericite, and opaque minerals are the main secondary phases. These relationships are compatible with lode-type gold systems, usually developed in the transition between greenschist to amphibolite metamorphic facies. Lava flows and dykes of isotropic rhyodacite, rhyolite, and plutonic rocks such as quartz monzonite, granodiorite, monzodiorite, and minor microgranite cut the mineralizing event previously described. Plutonic rocks are medium- to coarse-grained, have a gray color with reddish and greenish portions throughout the profiles, inequigranular texture with quartz, feldspar, biotite, and amphibole. Apatite, zircon, calcite, epidote, and opaque minerals are primary accessories. In turn, volcanics have light gray, black or dark red colors, porphyritic to aphyric texture, and microlithic or felsophyric groundmass. They reveal phenocrysts of plagioclase, amphibole, potassic feldspar, and quartz. This volcano-plutonic system contains potassic, propylitic, intermediate argillic, and/or carbonate hydrothermal alterations in selective, pervasive, or fracture-controlled styles. In hydrothermalized zones, gold occurs as isolated grains disseminated or associated with sulfides, as well as in cm-sized quartz veins in a stockwork arrangement. These characteristics are like those of shallow intermediate- to lowsulfidation epithermal systems already identified in the Amazonian Craton. The Volta Grande data suggest a second overprinted mineralizing event, common in high-tonnage productive gold deposits in China, Finland, and other areas of the planet and represents a new exploration guide for the Bacajá Domain. Several mineralizing events are critical to the economic feasibility and longevity of world-class gold deposits. Thus, new geochemical, geochronological, microthermometric, and stable isotope data will be obtained to better define the genetic modeling of the Volta Grande gold deposit.
Acesso aberto (Open Access)
Petrografia, suscetibilidade magnética e química mineral dos metagabros de Águas Claras, Serra dos Carajás-Pará
(Universidade Federal do Pará, 1997-04-15) SOARES, José Erima Bezerra; DALL'AGNOL, Roberto; http://lattes.cnpq.br/2158196443144675