Navegando por Assunto "Sanukitoides Rio Maria"

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Assinatura geoquímica de apatita de rochas sanukitoides do sudeste do cratón amazônico, Província Carajás.
(Universidade Federal do Pará, 2019-05-26) FONSECA, Camila Santos da; LAMARÃO, Claudio Nery; http://lattes.cnpq.br/6973820663339281
The Rio Maria Sanukitoid Suite, included in the Rio Maria Domain, southern portion of the Carajás Province, is composed of granodiorites and associated mafic and intermediary rocks. It has large exposures in the north of Redenção city, south of Rio Maria, east of Bannach and northeast of Xinguara, SE portion of the Amazonian Craton, being intrusive in greenstones of the Andorinhas Supergroup, Arco Verde Tonalite and Complex Caracol Tonalitic. Other granodioritic rocks correlated to the Rio Maria sanukitoids were described in the regions of Água Azul do Norte, Ourilândia do Norte, Serra do Inajá and Xingu region, all of them included in the Carajás Province. The Rio Maria Sanukitoids are metaluminous rocks, calcic-alkaline affinity and enriched with Mg, Cr and Ni in relation to other granodiorite rocks. They present primary epidote, zircon, allanite, titanite, apatite and magnetite as main accessory phases. U-Pb and Pb-Pb zircon dates defined crystallization ages of 2,87 Ga for these rocks. Apatite is a generally early mineral in the order of crystallization of granitoid rocks. Because of its properties, it can incorporate variable contents of REE and other trace elements, such as Na, K, Mn, F, Cl, Sr, Y, Pb, Ba, Th, U, V, and has been used as a good petrological and metallogenetic indicator of its host rock. The objective of this dissertation was the morphological and compositional study, by electron microprobe, of apatite crystals of granodioritic rocks from Rio Maria Sanukitoid Suite in Rio Maria, Ourilândia do Norte and Bannach regions, Rio Maria Domain, Carajás Province. For comparative purposes apatites of Leucogranodiorite with high Ba-Sr from Água Azul do Norte and of the Trondhjemite Mogno from Bannach region, both archaeans, have been studied. It was also compared to the apatites of the Seringa and Antônio Vicente paleoproterozoic type A granites, the first weakly oxidized and sterile, and the second, reduced and mineralized to Sn. The apatites of the Ourilândia do Norte sanukitoids have compositional zonations concentric to oscillatory more evident and complex, with well defined light-dark zones. On the other hand, the apatites of the Rio Maria and Bannach sanukitoids form more homogeneous crystals, with not evident or non-existent zones. The apatites of high Ba-Sr Leucogranodiorite and Mogno Trondhjemite are equally developed (> 150 μm), but with rare zoning restricted to the edges of some crystals. Inclusions of zircon are common only in apatites of Mogno Trondhjemite. In the Seringa granite, the apatites are comparatively smaller (<100 μm), subhedral to euhedral and with well defined zonations, while those of the Antônio Vicente granite are poorly developed (<30 μm), subrounded and free of compositional zonations. The main compositional variations among the apatite of the Rio Maria Domain, in addition to CaO, P2O5 and F, are in the highest content of LREE (La, Ce, Pr, Sm, Eu) found in the apatite of Ourilândia do Norte and Rio Maria in relation to those of Bannach, which show lower concentrations and sub-horizontal trend in the diagram (La + Ce + Pr + Sm) vs. (Gd + Yb + Y). This enrichment in REE is more evident in the diagram ΣREE + Y vs (La + Ce + Pr + Sm + Eu), where the studied apatite form an enrichment trend towards the Bannach - Rio Maria - Ourilândia do Norte sanukitoid. Based on this geochemical signature, similar and more enriched magmatic sources in LREE are suggested for the apatites of Ourilândia do Norte and Rio Maria. On the other hand, the apatites of Bannach sanukitoids presented higher and more variable concentrations of CaO, P2O5 and F and lower LREE, suggesting origin from a compositionally different and more LREE depleted magma. The apatites of the Mogno Trondhjemite and the leucogranodiorite high Ba-Sr are also more impoverished in LREE and tend to follow the apatite of the Bannach sanukitoides in the diagrams, but the apatite of the leucogranodiorites show greater enrichment in Sr. The Seringa granite has apatites more enriched in F and REE + Y when compared to the apatite of the archaean rocks, and they stand out in all the geochemical diagrams. This fact demonstrated that apatite compositions can also be used to record petrogenetic processes and to differentiate magmatic compositions that marked changes during the crustal evolution of a region, for example, distinguishing between Archaean and Paleoproterozoic granitoids, and are, therefore, useful in studies of provenance. Apatites of Antônio Vicente paleoproterozoic granite, mineralized in Sn, show high concentrations of F, Mn, Fe, Y and REE (except Eu), in comparison to other granitoids and can be used as a good metallogenetic indicator.
Acesso aberto (Open Access)
Morfologia e assinatura geoquímica de zircão da suíte sanukitoide Rio Maria, Província Carajás: implicações petrológicas
(Universidade Federal do Pará, 2016-11-29) COSTA, Hévila de Nazare Silva da; LAMARÃO, Claudio Nery; http://lattes.cnpq.br/6973820663339281
This research involved the morphological and compositional study of zircons from granodioritic rocks of Sanukitoide Rio Maria suite, Carajás Province. For this study were chosen five regions inserted in this Province, namely: Rio Maria and Bannach, type areas of the Rio Maria Sanukitoide rocks; Ourilândia do Norte, containing correlated granodioritic rocks to sanukitoids Rio Maria; São Felix do Xingu, where there are still poorly studied granodiorite rocks similar to sanukitoides, besides Trairão Granodiorite, situated in the Pau D'Arco region, belonging to the Guarantã suite and geochemically distinct from sanukitoide rocks. Zircon crystals were studied with the aid of secondary electron images (ES), cathodoluminescence (CL), semiquantitative analysis by spectroscopic energy dispersive (EDS) using a scanning electron microscope (SEM), aiming to define morphological features and characteristics geochemical signatures for zircons from each group of rock, compare the typological aspects between them and reaffirm the importance of zircon in petrological studies and SEM-CL-EDS methodology as a support tool for these purposes. The morphological study was conducted in zircons from two groups of rock. In the first one, made up of zircons from Rio Maria Sanukitoide Suite, were selected one hundred ten zircons and in the second one, represented by zircons of Trairão Granodiorite, twenty nine crystals. Zircons from the first group have euhedral shapes, subordinately subhedral, well defined standard zoning, well-developed and preserved cores, thin luminescent edges, suggesting compositional change at the end of crystallization, and rare to moderate presence of F-apatite inclusions. The zircons of Trairão Granodiorite showed euhedral the subhedral forms and well defined oscillatory zoning. The presence of F-apatite inclusions is recurring in this sample, both at the cores or at the edges of the crystals, truncating or taking place in parallel with the growth zones, suggesting simultaneous crystallization of both minerals. For the typological study were selected two groups of zircons. The first, made up of zircons of the Rio Maria sanukitoides, falls mostly within S18 type, with rare occurrences in P4 type. The second, represented by zircons of the Guarantã Granodiorite, correlates with S3 and S8 types. Semiquantitative ESD analysis performed in zircons from the five studied regions were compared and interpreted in specific geochemical diagrams. Zircons of Rio Maria and Ourilândia do Norte sanukitoides showed the lowest Nb contents (1.0-1.8%), followed by the zircons of Bannach and Xingu regions (1.8-2.5%) and Trairão Granodiorite (dominantly between 2.2 to 3.3%). Zircons from Rio Maria and Ourilândia do Norte sanukitoides showed higher Zr/Nb ratios, between 30 and 50, and zircons from Trairão Granodiorite the lower ratios, predominantly between 17 and 23. Zircons from Bannach and Xingu sanukitoides presented intermediate Zr/Nb ratios, between 23 and 32. The Sr versus Zr/Nb diagram shows a well defined negative trend, with zircons of Trairão Granodiorite more enriched in Sr (1.5 to 2.4%) and zircons from the Rio Maria and Ourilândia of Norte sanukitoides most depleted (0.6 to 1.6%), with partial overlap between them. Zircons from Bannach and Xingu sanukitoides showed intermediate Sr content (1.2 to 1.7%) and Zr/Nb (23 and 32) and plotted between the previous in the diagram. The study showed morphological, typological and compositional differences between the zircons of sanukitoides rocks of southeastern Para, and between these and the zircons of the Trairão Granodiorite. According to Pupin (1980) scheme, these differences allowed to frame the zircons of the sanukitoid rocks and the Trairão Granodiorite into two distinct groups, suggesting its crystallization occurred in different environments and temperatures.