Geoquímica das águas do médio e baixo rio Madeira e seus principais tributários - Amazonas - Brasil

Abstract

The aim of this paper was study the water of the Madeira River and its tributaries, between the city of Humaitá and its confluence in the Amazon River. There were analyzed: pH, conductivity, turbidity, major ions, trace elements and strontium isotopes during the dry and wet seasons and also, in the transition from the wet to the dry season, throughout 2009 and 2010. The white waters from the Madeira River are bicarbonated, calcic, with pH between 5 and 6 and the ions concentrations are higher than those of the tributaries. The waters of the tributaries are black, are more acidic and are chemically heterogeneous; those from the left margin are chemically similar to the waters of Madeira River, while those from the right margin are enriched in dissolved SiO2. The concentrations of cations, Cl- and NO3- are higher during the wet season due to the contribution of soils, vegetation and the rainwater composition (Cl-), while HCO3-, SO42-, Al, Br e P are concentrated in the dry season, and their higher contents may be related to the bedrock. The higher concentrations of SiO2 and rare earth elements in both dry and wet season are related to vegetation, soil and rocks. The interaction of these factors causes the chemical heterogeneity of the water. However, the chemical similarities between the water tributaries of the left margin and the water of the Madeira River, are probably, consequence of the Andean rocks be the sources of the Cenozoic sedimentary rocks percolated by these tributaries while the chemistry water of the tributaries of the right margin are in accordance with the tectonic stability, the intense weathering and the low erosion rate of the Amazon craton.