Programa de Pós-Graduação em Geologia e Geoquímica - PPGG/IG
URI Permanente desta comunidadehttps://repositorio.ufpa.br/handle/2011/2603
O Programa de Pós-Graduação em Geologia e Geoquímica (PPGG) do Instituto de Geociências (IG) da Universidade Federal do Pará (UFPA) surgiu em 1976 como uma necessidade de desmembramento do então já em pleno desenvolvimento Curso de Pós-Graduação em Ciências Geofísicas e Geológicas (CPGG), instalado ainda em 1973 nesta mesma Universidade. Foi o primeiro programa stricto sensu de Pós-Graduação (mestrado e doutorado) em Geociências em toda Amazônia Legal. Ao longo de sua existência, o PPGG tem pautado sua atuação na formação na qualificação de profissionais nos níveis de Mestrado e Doutorado, a base para formação de pesquisadores e profissionais de alto nível. Neste seu curto período de existência promoveu a formação de 499 mestres e 124 doutores, no total de 623 dissertações e teses.
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Item Acesso aberto (Open Access) Acúmulo e exportação de carbono, nitrogênio, fósforo e metais em canais de maré dos manguezais de Marapanim, Costa Norte Brasileira(Universidade Federal do Pará, 2020-12-18) MATOS, Christiene Rafaela Lucas de; SILVA, José Francisco Berrêdo Reis da; http://lattes.cnpq.br/1338038101910673; https://orcid.org/0000-0002-8590-2462; COHEN, Marcelo Cancela Lisboa; http://lattes.cnpq.br/8809787145146228In this study, we assessed the potential of intertidal mudflat sediments along mangrove forest to accumulate and export carbon, nutrients (N and P) and metals (Fe and Mn), in addition to examine the influence of the Amazonian seasonal rainfall patterns on the physicochemical conditions, diagenetic processes and exchange of nutrients and metals along the sediment-water interface (SWI) in intertidal mudflats fringed by pristine mangroves. The study was carried out in the Marapanim River estuarine system (northern Brazil), which is fringed by extensive areas of well-developed mangroves, part of the largest continuous and best preserved mangrove forest in the world, located approximately 200 km from west of the mouth of the Amazon River. The results of this work are presented in two articles. The first deals with the potential of stocks and accumulation of COT, NT and PT in intertidal mudflat sediments, in addition we investigate the potential sources of sedimentary organic matter (OM). The second assesses the influence of seasonal rainfall pattern on physicochemical properties, the diagenetic processes and the diffusive fluxes of nutrients at the SWI in the Marapanim mangrove creeks. During wet season the salinity values decreased as a consequence of the increase in rainfall, with a dilution-mixing zone in the top sediment (<15 cm). In the dilution-mixing zone, Fe (III) and Mn (IV) reduction are the dominant anaerobic respiratory processes in the sediments. The redox zonation of sediments oscillated in response to the rainfall patterns, with the highest concentrations of Fe2+ and Mn2+ in deeper sediment layers during the dry season. Under suboxic conditions, the mudflat sediments act as a source of Fe2+, Mn2+, NH4 +, and PO4 3- to the water column, and these fluxes were driven by rainfall. The results indicated that mangrove-fringed mudflats are quite effective in retaining carbon, nutrients and iron in sediment solid phases than exporting to the coastal waters, while can potentially be a significant contributor to the oceanic Mn cycle. The potential of these mangrove creeks to accumulate these elements is directly related to grain size, sources and susceptibility of OM degradation. In addition, temporal variability in pyrite formation revealed that the solid phase retention mechanisms are also susceptible to seasonal effects, with lower concentrations of chromium-reducible sulfur (CRS, mainly pyrite fraction) during the dry season. Therefore, we show that these seasonal variabilities implied substantial changes of physicochemical properties and the diagenetic processes, affecting the release of metals and nutrients from the SWI and their accumulation in the sediment.Item Acesso aberto (Open Access) Adequação de método para avaliação de risco de contaminação ambiental em áreas de estocagem de combustíveis(Universidade Federal do Pará, 2002-02-28) CHAVES, Cláudio Cezar Cunha de Vasconcelos; CORRÊA, José Augusto Martins; http://lattes.cnpq.br/6527800269860568Item Acesso aberto (Open Access) Afinidades petrológicas e geocronologia U-Pb em zircão de ortognaisses do Complexo Gnáissico-Migmatítico Água Azul, Terreno Sapucaia, Província Carajás.(Universidade Federal do Pará, 2024-10-09) PINTO, Eliziane de Souza; OLIVEIRA, Davis Carvalho de; http://lattes.cnpq.br/0294264745783506; https://orcid.org/0000-0001-7976-0472The Água Azul do Norte area is part of the geological context of the Carajás Province, precisely in the Sapucaia Terrain, according to the recent tectonic compartmentalization proposals presented by the Granitoid Petrology Research Group (GPPG/UFPA). This region is formed by a mesoarchean orthognathic basement with TTG affinity (Água Azul GneissicMigmatitic Complex; 2.93 Ga) associated with late Mesoarchean intrusions with sanukitoid signatures (Água Azul and Água Limpa Granodiorites; 2.88-2.87 Ga), high-Ba-Sr sodic (Nova Canadá Granodiorite; 2.89-2.87 Ga) and high-K calc-alkaline (Boa Sorte Granite; 2.89- 2.85 Ga) signatures. The review of geological and petrographic data indicated that the TTG crust of Água Azul do Norte is compositionally heterogeneous and records strong evidence of progressive metamorphism and migmatization. Therefore, this work reclassifies this TTG basement as being formed by orthogneisses, which occasionally present variations to tonalitic to quartz dioritic compositions that resemble fragments of a more primitive, intensely deformed and gneissified crust. These varieties show compositional banding in an E-W direction, often disturbed by shear bands and drag folds. Considering the classification of migmatites, they have an orthognathic paleosome and leucosomes rich in Qz+Pl±Bt parallel to the banding (stromatic metatexite) and frequentely outlined by mafic aggregates (melanosome rich in biotite and hornblende). They form four compositional varieties: i) hornblende±biotite tonalitic orthogneiss (HBTnl), ii) clinopyroxene-hornblende tonalitic orthogneiss (CHTnl), iii) epidote-biotite orthogneiss quartz diorite (EBQzD) and iv) hornblende-biotite orthogneiss quartz diorite (HBQzD). They present a large proportion of mafic minerals (M'> 15%), especially biotite and hornblende, which can occur slightly stretched along the foliation plane. Plagioclase and secondary quartz are abundant and occur in the matrix or, in the case of plagioclase, as phenocrysts, while alkali-feldspar and primary quartz are practically insignificant. Whole rock geochemical analysis indicated that samples MED-120A (EBQzD) and MEP-53B (HBQzD) present moderately magnesian character, medium-K calcium-alkaline signature, relative depletion in K2O, MgO, Ba, Ni and Cr and enrichment in Na2O, Al2O3, TiO2, Fe2O3 and Zr, reflecting a certain affinity with traditional tonalite-trondhjemitic associations. The presence of many zircon crystals with igneous features preserved in these samples marks the crystallization age of the protolith at 3.06 Ga, suggesting that they are crustal fragments approximately 100 Ma older than the underlying crust (Água Azul Orthognathic Complex). MED-144 (HBTnl) exhibited a strongly magnesian character, high-K calcium-alkaline signature, high K2O/Na2O ratio and enrichment in MgO, Ba, Ni and Cr, very similar to the composition observed in sanukitoids. The U-Pb data obtained for this sample indicated a crystallization age of 2.92 Ga, similar to that observed in sanukitoids described in the Ourilândia do Norte region (Arraias Granodiorite). The other samples showed significant contents of compatible elements (e.g. Fe, Mg, Ni, Cr) and moderate contents of incompatible elements (e.g. K, Rb, Ba, Sr, Zr, Ti) and revealed an intermediate behavior between TTGs and granitoids enriched in Mg, as well as a strong affinity with the São Carlos Orthogneiss (2.93 Ga) described in the same terrain. Concordant U-Pb ages obtained for samples MED-95A (HBTnl) and EDC-28B (CHTnl) indicated acrystallization at 2.95-2.93 Ga contemporaneous with the emplacement of the Água Azul TTGs and the São Carlos Orthogneiss. The textural behavior of the quartz and mafic minerals indicates dynamic recrystallization mechanisms at intermediate to high temperatures (~500-650ºC), while the morphology observed in the migmatites (stromatic metatexitic and leucosomes with hydrated minerals) suggests that there was a low amount of melt produced and fluids participation in the partial melting process. Combined with the mineral paragenesis (Pl+Qz+Bt±Hbl±Ep), these factors point to a granitic protolith metamorphosed under amphibolite facies conditions, with the migmatization being strongly contemporaneous with the deformation and peak of the regional metamorphism described in the Carajás region (2.89 Ga; MED-95A).Item Acesso aberto (Open Access) Alteração supergênica dos basaltos do Porto Franco-Grajaú-MA(Universidade Federal do Pará, 1985-10-04) VAQUERA VARGAS, Antônio; OLIVEIRA, Nilson Pinto deItem Acesso aberto (Open Access) Alterações hidrotermais associadas às rochas máfico-carbonatíticas do depósito de fosfato Serra da Capivara, região de Vila Mandi (PA), extremo sul do Cráton Amazônico.(Universidade Federal do Pará, 2019-07-14) VIEIRA, Danilo Amaral Strauss; FERNANDES, Carlos Marcello Dias; http://lattes.cnpq.br/9442875601862372Near the border of the states of Pará and Mato Grosso, in the Amazonian Craton, about 90 km west of the Vila Mandi district, Santana do Araguaia (PA) city, there is an unprecedented volcano–plutonism named Santana mafic-carbonatitic Complex. It is formed by a lower maficultramafic member with plutono–volcanic and other volcaniclastic lithofacies; besides an upper carbonatitic member with plutonic, effusive, and volcaniclastic lithofacies originated in a volcanic caldera environment with large areas of hydrothermal alterations and genetically related circular structures. The severe Amazon weathering partially affected this cluster, producing the Serra da Capivara Phosphate deposit supergenically. Although speculative, the Santana mafic-carbonatitic Complex is Paleoproterozoic in age, because it invades the Paleoproterozoic volcano-plutonic sequences Cinco Estrelas and Vila Mandi formations (1980–1880 Ma) and it is capped by sedimentary rocks from the same Era. The lower maficultramafic member has lithofacies with slabs of pyroxenite, and minor isolated metric blocks of ijolite and apatitite. They are medium-grained ceylonite-bearing (MgAl2O4) pyroxenites with augite (~ 90% vol.), magnesio-riebeckite, and olivine crystals replaced by clay minerals (saponite). The ijolite is composed of clinopyroxene and nepheline phenocrysts immersed in a fine-grained groundmass with nepheline, calcite, and interstitial magnetite. Apatitite blocks are composed of medium-grained apatite grains (~ 98% vol.) and calcite. The volcanic rocks of this lithofacies comprise isolated metric blocks of alkali basalt and rare associated outcrops of finegrained apatitite. This basalt rock presents plagioclase-rich groundmass and acicular augite phenocrysts as essential mineralogy. Aphyric samples have primary spherules filled with calcite and quartz, besides interstitial pyrite, iron oxides, apatite, barite, rutile, celestine, and monazite. This textural feature suggests silicate and carbonatitic melts immiscibility process. An explosive to autoclastic mafic volcaniclastic lithofacies encompasses poor sorting deposits of massive polymictic breccia, lapilli-tuff, crystal-rich tuff, and ash tuff. The autoclastic rocks reveal volcaniclastic texture comprising centimetric angular clasts sourced from autofragmentation of the mafic-plutonic plutono–volcanic lithofacies. Epiclastic sedimentary volcanogenic deposits usually cover all previous lithofacies. The upper carbonatitic member reveals coarse-grained carbonatite (sövite) lithofacies comprising reddish-yellow sövite (calcite carbonatite) composed of subhedral to euhedral calcite (85–90% vol.), with variations to magnesium-ferriferous calcite and dolomite. Primary accessories are magnetite, hematite, potassic feldspar, and pyrite. These lithotypes show hydrothermalized medium- to fine-grained carbonatite veins. Rare coarse-grained apatitite bodies occur associated with this lithofacies, which represents part of the proto-ore. An effusive carbonatite (alvikite) lithofacies reveals finegrained calcite-rich (80–85% vol.) to porphyritic alvikite, besides hematite, magnetite, potassic feldspar, and pyrite. Fragment-rich explosive carbonatitic volcaniclastic lithofacies encompassing poor sorting and texturally variable massive crystal-rich tuff, lapilli-tuff, and massive polymictic breccia formed by angular clasts sourced from host rocks and the complex. Syenitic stocks and dikes invade these rocks. The main hydrothermal magmatic alteration of the complex is represented by hydrothermalized carbonatitic rocks of reddish, brownish, and yellowish colors. The mineral paragenesis found was barite + fluorapatite + dolomite ± quartz ± rutile ± chalcopyrite ± pyrite ± monazite ± magnetite ± hematite. This alteration occurs in three distinctive ways; 1) in the deeper zones, where the minerals found were barite, fluorine apatite, and dolomite in pervasive to fracture-controlled alteration associated with deep fine carbonatites. 2) In the sövite, of weak interstitial form with mineralogy similar to the deep alterations. 3) in the alvikite with intense interstitial changes and formation of hydrothermal quartz associated with barite, fluorapatite, dolomite, monazite, celestine, and rutile. The mineral assemblage of the deeper alterations suggests initially sulphate-rich, magnesium, phosphorus, and CO2 fluids with possible transitional source between the late magmatic and the hydrothermal stages. In transition to more superficial phases of the volcanism, there was an assimilation of SiO2 from the country rocks evidenced by the formation of fine interstitial quartz crystals in alvikite. The interpreted environment of volcanic caldera occurs in the interception of regional NE-SW and NW-SE faults with up to 40 km of extension and that served as deep conduit of the precursor magma of the complex. The root of the system is represented by maficultramafic rocks and plutonic carbonatites. The pre-caldera phase involved intense degasification and hydrothermal activities as a function of magmatic evolution, and ascending by lithic faults and placing on the surface of large volume of carbonate lava (alvikites) that built the extinct volcanic building. The collapse of this structure and the topographic landslide coincided with explosive volcanism and formation of the volcanoclastic lithotypes, representing the intra-caldera filling. The late syenites may represent the post-caldera phase and sealing of these structures. The hydrothermal paragenesis identified in the Santana maficcarbonatitic Complex shows important metallogenetic potential for rare earth elements and phosphate and represents a prospective guide on Proterozoic terrains of the Amazonian Craton, like other areas of the planet.Item Acesso aberto (Open Access) Alvo Borrachudo, Serra dos Carajás (PA): rochas ígneas ricas em magnetita e apatita com mineralizações de sulfetos associada(Universidade Federal do Pará, 1996-05-25) FARIAS, Edielma dos Santos; VILLAS, Raimundo Netuno Nobre; http://lattes.cnpq.br/1406458719432983Item Acesso aberto (Open Access) Ambiente deposicional, composição mineralógica e estudo isotópico Pb-Pb das zonas sulfetadas do Alvo São Martim, Cinturão Araguaia, sul do Pará(Universidade Federal do Pará, 2004-07-07) LIMA, Aderson David Pires de; VILLAS, Raimundo Netuno Nobre; http://lattes.cnpq.br/1406458719432983Item Acesso aberto (Open Access) A ametista de Pau d' Arco e Alto Bonito no Pará e a do Alto Uruguai no Rio Grande do Sul(Universidade Federal do Pará, 1998-03-23) CASSINI, Carlos Tadeu; COSTA, Marcondes Lima da; http://lattes.cnpq.br/1639498384851302Item Acesso aberto (Open Access) Análise do padrão espectro-temporal de ambientes costeiros com imagens Landsat, Ilha de Marajó/PA.(Universidade Federal do Pará, 2010-10-06) CARDOSO, Gustavo Freitas; SOUZA JUNIOR, Carlos Moreira de; http://lattes.cnpq.br/2090802631407077; SOUZA FILHO, Pedro Walfir Martins e; http://lattes.cnpq.br/3282736820907252Knowledge of spatial and temporal distribution and monitoring of its dynamic evolution are the most important factors for the study and management of wetlands. The aim of this study was to characterize, to map, to compare the spectral response of coastal wetlands, as well as detect the changes on the eastern shore of Marajo, State of Pará, using images from TM Landsat-5 reflectance. To this end, the images were geometrically and radiometrically corrected. Were collected in the reference image (2008), at least 20 polygonal samples (5x5 pixels) for each type of land cover. The analysis of variance (ANOVA), Tukey HSD Test and an index of spectral separability of pairs of regions of interest (ROIs) were calculated. The mapping was generated from the supervised classification Spectral Angle Mapper, and validating data, outlined by the Confusion Matrix. Thus were recognized the following units: MAN - mangrove, MAD - degraded mangrove, PRD – beaches and dunes, VSI – initial secondary vegetation, VSA - advanced secondary vegetation, ACS – water with sediment, ASS - water without sediment, OCH - human occupation and CAM – marshes. The result of ANOVA showed that there are significant differences between the average reflectance in all classes and at least one pair of means, for all bands (1-5 and 7) image. The Tukey HSD test found that the smallest difference between two means of bands 1 and 2 occurs in pair VSAMAN, the band 3, VSI-MAN, the band 4, OCH-MAN, the band 5, OCH-PRD, and band 7, ASS-ACS. The function of spectral separability of pairs of ROIs highlighted a low value for the pair of classes OCH-CAM. The calculation accuracy of the mapping showed acceptable values. Was also applied the technique of spectral mixture model to determine the fractions – green vegetation, water and/or shade, soil and vegetation not photosynthetically active – in reflectance images in years from 1988, 1994, 1998, 2004, 2006 and 2008. The detection of changes over the years was done with the help of the tri-linear diagram of Thompson, used to analyze the evolution of Mangrove environments, Salt Marshes with a predominance of soils, Grassland Salt Marshes, Beaches and Dunes, Wet Sediment, Water with Sediment and Water without Sediment. The results showed that 80% of the samples from mangrove environment, maintained their spectral characteristics, ie, the environment has not changed over time, and that 15% of possible paths indicated a gradual change for the formation of mangrove until 2008. Of the total number of pixels analyzed for this environment, 93% corresponded to the actual mangrove, confirming a relative stability of this environment in the study area. Salt Marshes showed an unusual condition in the analysis of the image of the reference year (2008), with spectral response similar to the soil characteristics, this is not checked in years gone by. In recent years, there was a predominance of Grassland Salt Marshes. As for the environment Beaches and Dunes revealed a considerable increase of its surface (66.7%) in the 20-year period (1988-2008). Overall, the results suggest that the study area has undergone the process of progradation of sediments along the shoreline and stabilization in the increase of surface Mangrove since 2006. For the Salt Marshes detect the variations in the abundance values among the three fractions (Green Vegetation, Shade/Water, Non-photosynthetically Active Vegetation and Soil) generated by the spectral mixture model, mainly due to seasonal climate in the region. The method of change detection applied fostered the development of a model spectral dispersion diagram for coastal wetlands. This model should assist in future research about the monitoring of the impacts of the humid coastal environments from the increase in sea level, the location and spectral characterization, and change detection.Item Acesso aberto (Open Access) Análise espaço-temporal dos manguezais degradados de Bragança, com base em imagens de satélite e modelos de elevação digital(Universidade Federal do Pará, 2022-02-22) MOLANO CÁRDENAS, Sergio Mauricio; COHEN, Marcelo Cancela Lisboa; http://lattes.cnpq.br/8809787145146228The Bragança Peninsula occurs at the northern littoral of Brazil, in the state of Pará. It is characterized by the largest continuous mangrove belt in the world. The construction of the PA- 458 road in the ‘70s changed the hydrodynamics of the peninsula, causing the degradation of a considerable portion of the mangroves in the central region of the peninsula. Recently, degraded areas are being colonized by mangrove trees, mainly by the Avicennia germinans specie. This study intends to identify changes in the degraded areas of the tidal flats in topographically higher sectors during the last 35 years. To reach that objective, we used the following techniques: a) manual mapping of the degraded areas with mid spatial resolution satellite imagery; b) object-based classification of the degraded areas and mangrove species, using high spatial resolution satellite imagery; c) photogrammetry of drone imagery; d) digital elevation models; and e) topographic validation with theodolite and GNSS GPS “Antenna Catalyst”. From 1986 to 2019, there was a reduction in the degraded areas of 247.96 ha according to the mid-resolution “dataset” quantification. However, high-resolution data showed a reduction in the degraded areas of 211.65 ha between 2003 and 2019. The degraded areas quantification presents fluctuations in the regeneration trend; it is related to significant climatic phenomena such as “El Niño” and “La Niña”, accompanied by periods of drought and high rainfall, respectively. Overall accuracy and Kappa index values for the high-resolution data generally exhibited values above 0.9. Producers’ and users’ accuracy and Kappa per class values showed the difficulties separating mangrove species due to the lack of radiometric resolution of the analyzed images. The digital terrain model representing the tidal flat showed two topographically differentiated regions in the degraded areas, separated by the PA-458 road, which are mainly influenced by the Caeté’s and Taperaçú’s characteristics. This same difference was found in the vegetation height model, where the largest trees are located toward the SE side of the road, reaching 25 m, while at the NW side of the road, the tree heights oscillated mainly between 5 and 15 m. The sea-level rise specifically controls regeneration rates. This relocated the intertidal zone to topographically higher areas, increasing tidal flushing processes, essential for the mangrove forests development.Item Acesso aberto (Open Access) Análise faciológica das formações Poti e Piauí (carbonífero da Bacia do Parnaíba) na Região de Floriano-PI(Universidade Federal do Pará, 2000-07-20) RIBEIRO, Cleive Maria Monteiro; GÓES, Ana Maria; http://lattes.cnpq.br/2220793632946285Item Acesso aberto (Open Access) Análise faciológica e aspectos estruturais da formação Águas Claras, região central da Serra dos Carajás-PA(Universidade Federal do Pará, 1995-01-31) NOGUEIRA, Afonso César Rodrigues; TRUCKENBRODT, Werner Hermann Walter; http://lattes.cnpq.br/5463384509941553Item Acesso aberto (Open Access) Análise integrada da morfologia e sedimentologia do baixo curso do rio Xingu(Universidade Federal do Pará, 2019-01-28) SILVA, Ariane Maria Marques da; ASP NETO, Nils Edvin; http://lattes.cnpq.br/7113886150130994The Xingu River is an important tributary of the Amazon River, contributing with 5% of its total water discharge. Nevertheless, it does not contribute substantially with sediment load. The lower reaches of the Xingu River correspond to a Ria, as a result of the Holocene sea-level rise. It is also classified as a tidal river, where tides reach over 1 m at its confluence with the Amazon River. This study evaluated the morphology and sedimentology of the area, correlating it with hydrodynamics, aiming to understand the still ongoing infilling process of the Xingu Ria. The study area encompasses a stretch of about 180 km, from the Xingu-Amazon river confluence upward to the narrowing of the channel, near the city of Vitória do Xingu. During the maximum sediment discharge of the Amazon River (i.e., feb/2016) 109 bottom sediment samples were collected, whereas 11 of the sampling sites were re-sampled during the minimum water discharge period of both rivers (i.e., nov/2016). During the maximum water discharge period of the Amazon River (i.e., jun/2018), additional water level measurements were undertaken simultaneously in several locations along the Xingu River, as it was also performed during the other campaigns. The morphology was evaluated on the basis of the bathymetric surveys of the Brazilian Navy (CLSAOR/DHN), including about 20,000 points. The results showed that the infilling process of the ria lake has taken place from both ‘ends’ of the area- from the Xingu River itself, forming a prominent bay-head delta, as well as from the Xingu-Amazon River confluence, where tides have transported Amazon River sediments upstream into the Xingu Ria. Furthermore, there is a central portion of the ria lake with large cross-sectional areas, reached only by relatively small amounts of sediments, being a quiescent environment within muddy sedimentation. In a transversal perspective, sands seem to prevail along the margins, where local wave action seem to result in bluff erosion. Longitudinally, sands are substantially more frequent at the bay-head delta area, and at the confluence area, where cross-sections are clearly narrower. Results also suggest that the sediment input from the Amazon River into the Xingu ria has reduced over time, whereas the combination of cross-section area variation and the Xingu River water discharge itself reduce the sediment flux from the Amazon River into the Xingu River.Item Acesso aberto (Open Access) Análise morfoestratigráfica do estuário do Rio Marapanim - NE do Pará(Universidade Federal do Pará, 1998-12-20) SILVA, Cléa Araújo da; EL-ROBRINI, Maâmar; http://lattes.cnpq.br/5707365981163429The estuary of Marapanim River is developed on tertiary-quaternary sediments of Barreiras and Pós-Barreiras Formation. It is inserted on "Littoral of Rias" of Pará northeast, which from High Pleistocene was submitted to marine transgression that drowned coastal paleolines and, in the maximum of Holocene Transgression, reached the coastal plateau. This portion of coast is strongly influenced by dynamic macrotides (5,3m) and salt wedge with mear salinity of 8%0 (high tide — Marudazinho) and 3%0 (low tide — Marapanim). So that, on outer funnel (Marudá) the salinity is 35°/00, representing no influente of mouth river discharge. Geomorphology of the area is subdivided in three morphologic domains: (1) Coastal Plain, constituted by strand plain, paleodune, coastal dune, salt marsh, tidal flat (sand flat and mangrove swamp), recurved spit, lake and palco tidal creek; (2) Estuarine Plain, constituted by estuarine channel (subdivided in estuarine funnel segment, sinuous meandering segment, cuspidate meandering segment and upstream channel), tidal creek and floodplain (salt marsh and fresh water marsh) and; (3) Alluvial Plain constituted by meandering channel (chute cutoff), channel deposits (channel lag deposits), overbank deposits (natural levee, crevasse-splay deposits and floodplain) and channel-fill deposits. Fourteen morphostratigraphic units was identified: floodplain, levee, chute cutoff, fresh water marsh, mudflat, channel bar, point bar, strand plain, paleodune, coastal dune, recurved spit, sand flat and salt marsh. Six stratigraphic facies are also present: point bar sand and mud, marine sands, estuarine sand and mud, estuarine muds, fluvial sands and motled sand. Stratigraphical analysis permitted recognize stratigraphic sequences: Basal Marine Transgressive (Si) with fluvial, salt marsh and shoreface environments; Marine Regressive (S2) with fluvial, fresh water marsh, tidal flat, salt marsh and strand plain environments and; Recent Marine Transgressive (S3) with estuarine (channel bar and point bar) and littoral environments (recurved spit, strand plain and coastal dune). Geological evolution of the estuary of Marapanim River is associated with sea levei oscillations that occurred during progradation and regressive cycles on Later Holocene, which in the maximum of the Holocenic Transgression eroded the highland (coastal plateau). In stillstand sea levei conditions occurred marine regressive and mud flat progradation over marine sand deposits. In present time, sand sheets are deposited over mud ilat providing partia! filling in the mouth of estuary by sand bars.Item Acesso aberto (Open Access) Análise tafonômica da ostracofauna do testemunho 1AS-5-AM: contribuição para a interpretação paleoambiental dos depósitos neógenos da Formação Solimões, AM, Brasil.(Universidade Federal do Pará, 2019-11-01) SANTOS, Katiane Silva dos; RAMOS, Maria Inês Feijó; http://lattes.cnpq.br/4546620118003936The Solimões Formation corresponds to the miocenic sedimentation from the Solimões Basin; it is constituted, essentially by mudstone, siltstone and fine sandstone, poorly consolidated, interspersed by lignite and carbonate levels, whose deposition took place in a fluvial and fluvio-lacustrine environment. Among the invertebrates from Solimões Formation the ostracode stand out for their abundance and diversity. Initially, the studies on those microcruteacea focused mainly on taxonomy. Subsequently, contributions on the bioestigraphy field suggest Early Miocene - Late Miocene age for this unit; while geochemical and paleontological analysis point to predominantly freshwater environmental conditions, with sporadic marine influence. However, taphonomic studies with emphasis on ostracode from Solimões Formation have not yet been performed. Taphonomic analysis of fossil concentrations can provide important data on paleoenvironmental hydrodynamics, sediments geochemistry, sedimentation rates and diagenetic processes. This paper deals with the biostratinomy and fossildiagenesis of ostracodes from Solimões Formation, as well as the mineralogical composition and sedimentological aspects of lithotypes. The material analyzed comes from thecore 1AS-5-AM, drilled in the village Cachoeira, near the Itacuaí river, Amazonas State. According to lithological characteristics, types of preservation and occurrence of ostracodes it was possible to individualize three intervals along the analyzed core. The interval I (284.50-119.30 meters) corresponds to the lower portion of the core. In this, the ostracofauna is poorly preserved, occurring only few juveniles (A-2, A-3 stages) and adults, with strong dissolution process. The lithology of this interval comprises solid, dark greenish gray to black mudstone, with rich organic matter content. The Interval II (116.70-107.10 meters) presents a higher occurrence of ostracodes in excellent preservation state and several ontogenetic stages, higher occurrence of closed carapaces and low degree of dissolution (occurs partially and punctually), suggesting a rapid burial event and little influence of methanogenesis on the lower organic matter content of the samples. The lithology of these layers are the same from interval I, however the organic matter content is fewer. Interval III (106.90-41.00 meters) has a moderate preservation stage, where the highest dissolution rate is associated to oxidation of monosulfides and iron sulfides that occurs adherent to the specimens surface, which were exposed by bioturbating organisms of sediments. The predominance of juvenile ostracodes in this interval indicates high mortality in ontogeny probably due to environmental stress. The lithology of this interval is made up of light to medium solid greenish gray, locally siltitic and lignite. Bioturbations (Skolitos) were recorded only at this interval. Organic matter content varies from low to moderate. Related to the color change of the ostracodes, opaque white valves were recorded in interval I more frequently; in II predominate black, dark gray, white and in smaller quantity, amber and hyaline colored valves; while in the III predominate reddish brown specimens, followed by light gray and opaque white. The taphonomic analysis of the ostracodes allowed to verify carapaces/valves with original chemical composition preserved, however, contaminated by chemical elements from the siliciclastic sediments and thin mineral layers adhered to its surface. The following types of preservation were identified: 1) ostracode valves and carapaces covered by thin mineral layers of iron monosulfide, iron phosphate, iron and thallium sulfide; 2) preserved in iron oxides; 3) recrystallized; and 4) pyritized molds. Preservation types identified predominantly reflect conditions of early (thin mineral layers mineralization and mold formation), and late (recrystallization, oxide formation) diagenesis. Fossildiagenetic alterations correspond to mineral filling of carapaces by pyrite, dissolution, color change and recrystallization. The first is related to iron phosphate present in sediments and rapid burial events. The dissolution resulted from the oxidation of the thin mineral layers adherent in the valves and the organic matter content; while carapaces/valves with alterations to reddish brown, dark gray, black and amber reflect the deposition of thin mineral layer on the specimens surface, opaque white valves result from partial dissolution. The punctual recrystallization of few valves reflects the mineral stability of the low magnesian calcite, the main constituent of ostracod carapace. The biostratinomic alterations identified are equivalent to fragmentation, disarticulation (from death, ecdysis and transport of ostracodes), bioerosion (due to chitinolytic bacteria) and transport. In interval I juvenile allochthonous ostracodes suggest postmortem transport. In interval II the predominance of native fauna shows low energy environment. Allochthonous and autochthonous (predominant) ostracodes of interval III reflect energy variation in scenery near the coastal lake zone. Based on the types of preservation and lithological characteristics, the environment was interpreted as lacustrine, with low to moderate energy. The absence of evaporitic minerals and dispersed pyrite in sediments attest to the low salinity of the environment.Item Acesso aberto (Open Access) Análise tafonômica de Eremotherim laurillardi (Lund, 1842) dos depósitos pleistocenos, município de Itaituba, Pará(Universidade Federal do Pará, 2008-08-18) FERREIRA, Denys José Xavier; RAMOS, Maria Inês Feijó; http://lattes.cnpq.br/4546620118003936The present work deals with the taphonomic study of Eremotherium laurillardi (Lund, 1842), a ground sloth found within a Pleistocene depositional site in Itaituba town, State of Pará. The samples comprise approximately eight hundred skeletal fragments and complete pieces of this specie deposited in the Paleontological Collection of Museu Paraense Emílio Goeldi. Taphonomy is the post mortem history of fossils, the study of processes that influence preservation of potential fossils. It consists of two major aspects: biostratinomy, the study of processes affecting organism remains prior to burial and fossil diagenesis affecting potential fossils after burial. The biostratinomic study showed that the skeletal remains had a loose packing and were poorly sorted, indicating deposition in situ. Moreover, the biostratinomic study revealed that the taxonomic composition of the skeletal fragments is monotypical and monospecific related to catastrophic death (non-selective) by abrupt burial which occurred before necrolysis. Traces of abrasion and reworking during transport of the skeletal remains are insignificant and/or non-existent. Bioerosion facies have not been identified too. The non-preservation of soft parts shows that the necrolysis occurred in an aerobic environment. However, the partial presence of pyrite in the foramina and channels of ribs and teeth analyzed point to localized reducing micro environment. The skeletal remains show their morphological structures, both external and internal, well preserved suggesting that they were not exposed to the exogenous cycle, due to the quick burial. The fossildiagenetic study, conducted on samples of ribs, teeth and vertebrae, using both optical and scanning electron microscopy, revealed that both the bone and dental structures, known as Havers` channels and dentinal tubules, respectively, remained well – preserved. Additionally EDS Analysis (Energy Dispersive Spectroscopy) carried out on these components showed a nearly unaltered chemical composition relating to Ca, P, Mg, K and Na contents.Item Acesso aberto (Open Access) Aplicação de resíduos da mineração de bauxita na síntese de geopolímeros(Universidade Federal do Pará, 2022-04-08) BARRETO, Igor Alexandre Rocha; COSTA, Marcondes Lima da; http://lattes.cnpq.br/1639498384851302; https://orcid.org/0000-0002-0134-0432The process of extraction and beneficiation of bauxite deposits in the bauxite province of Paragominas/Rondon do Pará can generate large amounts of waste, mainly in two stages of the process: mining and processing. In the mining stage of the deposits, the “residue” comes from the removal of a thick layer of clay material (known as Belterra Clay). On the other hand, the “residue” from the beneficiation process is generated after the crushing, grinding and washing stages, which give rise to a large amount of clay material dispersed in a large amount of water. For the present study, it selected Belterra clay from the bauxite deposits of Rondon do Pará, a sample of Bauxite Washing Clay from the Hydro company and a sample of kaolin benefited from Imerys Company. The samples and geopolymers were characterized by X-ray Diffraction (XRD), X-ray Fluorescence (FRX), Gravimetric Thermal Analysis (TG), Differential Exploratory Calorimeter (DSC), Optical Emission Spectrometry with Coupled Plasma (ICP-OES) and Laser Particle Analyzer (APL). Geopolymers were synthesized from Belterra clay, microsilica and NaOH according to the Box-Benkhen design. Synthesis of geopolymers from Belterra clay and beneficiated kaolin was also carried out (a comparative study) using KOH and microsilica. Finally, geopolymers were synthesized from Bauxite washing clay with NaOH and microsilica according to the Doehlert design. In the study with only Belterra clay, the highest resistance result was 47.78MPa and the lowest result was 7.05MPa. In the comparative study between Belterra Clay and beneficiated kaolin, the best results of compressive strength were obtained with the beneficiated kaolin. The compressive strength results of the geopolymers synthesized from the Washing Clay ranged from 8.99 to 41.89MPa. These results demonstrate the positive potential of both samples for the synthesis of geopolymers that can be used as possible “Eco-friendly” substitutes for traditional materials, mainly ceramics and cement.Item Acesso aberto (Open Access) Arcabouço estrutural e geocronologia dos granitóides da região de Várzea Alegre: implicações para a evolução crustal da Província Borborema(Universidade Federal do Pará, 2024-07-25) SOUSA, Luis Kennedy Andrade de; DOMINGOS, Fabio Henrique Garcia; http://lattes.cnpq.br/3975188208099791; https://orcid.org/0000-0002-2447-3465; GALARZA TORO, Marco Antonio; http://lattes.cnpq.br/8979250766799749; https://orcid.org/0000-0002-7271-4737In the Borborema Province, in northeastern Brazil, several granitic batholiths and plutons are found, which are records of subduction and collision episodes related to the Brasiliano Orogeny. Within this large orogenic system, the emplacement mechanisms of many granites are closely related to the development of deep-seated shear zones, one of which is the Patos Shear Zone, which in its western segment is composed of slices of rocks such as granites, gneisses, metapelites, quartzites, and amphibolites that form an imbricated system. In this context, the present work was carried out with the aim of bringing new geochronological and microstructural data to add to the understanding of the nature of the processes that formed and modified the undifferentiated granitoids in the Várzea Alegre region (CE). The granites are classified as Biotite Monzogranite and Garnet Monzogranite, they present phaneritic and porphyritic textures, in some places, their mineralogical composition is mainly composed of plagioclase, K-feldspar, and quartz, in addition to biotite, muscovite, and garnet. The granitoids are composed of elongated bodies concordant with the host rocks. The deformation imposed on the granitic bodies developed ductile structures with NE-SW orientation and kinematic criteria indicate that the deformation occurred predominantly dextral. Microstructural features, observed mainly in rocks near the edges of the granitic bodies, show that quartz crystals exhibit microstructures such as sutured to lobate contacts, undulating extinction, ribbons, and the chessboard pattern, indicative of recrystallization by grain boundary migration (GBM), compatible with temperatures of 500ºC. Biotite crystals that define the mylonitic foliation characterize a spaced foliation that separates microlite domains formed by aggregates of quartz and plagioclase, with asymmetric lenticular geometry in the granites, similar to the foliation impressed on the gneisses of the Granjeiro Complex. Based on EBSD data, the granites exhibit a grain size distribution with a concentration of crystals <100 μm. From the pole figures, the quartz OPC shows that the dominant system was rhombohedral to prismatic, indicating a medium to high deformation temperature, in a context of progressive non-coaxial deformation. However, from the interpretation of the misorientation angle, it is shown that during the deformation history of the granites, these bodies underwent lower temperature deformation. U-Pb geochronological data on zircon provided crystallization ages of 573 to 576 Ma for this granitic magmatism. The Hf-TDM C model ages of these granitoids ranged from 2.84 to 3.30 Ga and the ƐHf(t) values from -21.9 to -29.6 suggesting a strong incorporation of mesoarchean crustal source. Similar Sm-Nd data in whole rock show that these granitoids have Nd-TDM model ages between 2.14 and 3.33 Ga and ƐNd(t) values between -20.02 and -31.79, suggesting a strong contribution from meso paleoarchean and paleoproterozoic crust (orosirian to riacian) to the formation of the granitic magma that originated the granites in the Várzea Alegre region (CE). These granitic bodies are classified as Itaporanga type and sin-transcurrent, as they have similar ages and structural features to other sin-transcurrent granitic bodies in the Borborema Province. These granites were generated from magmatism associated with the change in the predominant deformation in the Borborema Province, which was the result of the final stages of the Brasiliano Orogeny within the context of simple deformation, with the development of large shear zones.Item Acesso aberto (Open Access) Argamassas históricas de Belém do Pará.(Universidade Federal do Pará, 2019-09-16) LOUREIRO, Alexandre Máximo Silva; ANGÉLICA, Rômulo Simões; http://lattes.cnpq.br/7501959623721607The city of Belém, northern Brazil, known as the metropolis of the Amazon, was established on the banks of the Guajará Bay on January 12, 1616, with the denomination of Nossa Senhora de Belém do Grão-Pará, capital of the Grão-Pará province, now the state of Pará. Currently, Belém still has layers of lime mortar on its colonial and imperial buildings, which protect the secular structures and provide evidence of how this material was produced early in its history. Over the years, the deteriorating aspects identified in lime mortars, which damage both aesthetics and functionality, are related to the humidity, saline efflorescence, biological colonization, and/or anthropic actions. Once deteriorated, mortars require maintenance, consolidation, or replacement, which are difficult procedures that can lead to the use of inappropriate materials. Therefore, a good collect and characterization strategies of the original material is necessary for the restoration of historical monuments, because in studies focused on restoration science, the intervention strategy needs to include the use of building materials compatible with the original materials. Thus, the main objective of this doctoral thesis is to determine the characteristics and properties of historical mortars in Belém do Pará from the 18th and 19th centuries, as well as to propose a restoration mortars compatible with the historic mortars, which using industrial waste from Amazon Region. Therefore, this thesis was structured in three independent and complementary thematic articles, which addresses the topic of the historical mortars of Belém do Pará, since their characterization until the proposal of restoration mortars: 1) Investigation of the historical mortar of Belém do Pará, Northern Brazil; 2) How to estimate the binder: aggregate ratio from aerial lime-based historical mortars for restoration? and; 3) The use of industrial waste of the Amazon region in lime-metakaolin restoration mortars: compatibility assessment. Thus, the physical, chemical and mineralogical characteristics were determined, as well as the physical and mechanical properties of the historical material and the restoration material. The results of the historical mortars characterization pointing their main components, their functions and raw materials, besides indicating the analytical techniques used for binder: aggregate ratio quantification, which obtained good accuracy and reliability in your results. Moreover, the results show a wide range of characteristics and properties obtained through restoration mortars, which can serve as a benchmark for other studies or even for practical applications in historic masonry. Therefore, it was possible to identify the restoration mortars most compatible with the historical mortars of Belém do Pará, Northern Brazil.Item Acesso aberto (Open Access) Argilominerais da Formação Codó (Aptiano Superior) – Bacia de Grajaú: implicações ambientais e climáticas.(Universidade Federal do Pará, 2004-06) GONÇALVES, Daniele Freitas; ROSSETTI, Dilce de Fátima; http://lattes.cnpq.br/0307721738107549The Codó Formation is exposed in the adjacency of the town of Codó (MA) and consists of a dominantly closed and hypersaline lacustrine setting. It is characterized by sucessions that are arranged into shoaling upward cycles averaging 1 m thick. The cycles are constituted upward by central lake deposits (i.e., evaporite and bituminous black shale), transitional lake deposits (i.e., laminated argillite, lime-mudstone, peloidal packstone and meso-crystalline carbonate) and marginal lake deposits (i.e., massive pelite, gipsarenite and calcarenite with fenestrae and features of palaeokarst, pisoidal packstone to grainstone, rhythmite and nodular chert). This work applied X-ray diffraction and microscopic (including scanning electron microscopy) analyses to investigate argillaceous rocks of the Codó Formation. The goals included the characterization of the clay mineral assemblage, definition of its nature and evaluation of its application as a paleoclimatic and paleoenvironmental indicator. The facies studied in this work included: black shale, laminated argillite, lime-mudstone, massive pelite and rhytmite of carbonate and shale. These facies showed a clay mineral assemblage composed of smectite and, subordinately, illite kaolinite and interstratified illite-smectite. The smectite is, in general, detrital in nature, being characterized by crenulated flakes with parallel or chaotic arrangements. The smectite, when pure, exhibit high cristallinity and/or interstratification and has been classified as dioctaedric montmorillonite. Authigenic smectite can be locally found and is arranged in crystals averaging 2μm that show a honeycomb morphology, usually drapping ostracode shells in rhythmites. Kaolinite occurs as pseudohexagonal and equidimensional crystals averaging 1μm in diameter that replaces the smectite, and as booklets (averaging 8μm) that fill vugs. Its occurrence is substantially increased in marginal lake deposits, more specifically in the massive pelite facies. Illite occurs as hair-like crystals in transitional lake deposits as replacement of smectite. It is possible that part of the illite is detrital; in this case, it is characterized by a morphology in flakes that can hardly be differentiated from detrital smectites. The distribution of clay minerals throughout the studied profiles shows an upward decrease in both the amount and the crystallinity and/or interstratification of smectite. This tendency was also observed in some individual shoaling-upward cycles. Thus, central and transitional lacustrine deposits, located at the base of the sucessions, exhibit relatively increased amounts of smectite relative to kaolinite and illite, while the transitional and marginal deposits at the top show an inverse behavior. The dominance of detrital smectite and the large occurrence of evaporites in the study area confirm a warm and semi-arid climate during the late Aptian in the Grajaú Basin. The variability of clay minerals along the profiles correlates well with shoaling upward cycles, helping to better define them. The genesis of the authigenic clay minerals (i.e., kaolinite and illite) has been credited to pedogenic processes. The coexistence of kaolinite and illite is related to alternations between wet and dry periods.