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Dissertações em Geologia e Geoquímica (Mestrado) - PPGG/IG

URI Permanente para esta coleçãohttps://repositorio.ufpa.br/handle/2011/2604

O Mestrado Acadêmico pertence ao Programa de Pós-Graduação em Geologia e Geoquímica (PPGG) do Instituto de Geociências (IG) da Universidade Federal do Pará (UFPA).

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Acesso aberto (Open Access)
Adsorção de cromato em materiais sintetizados a partir de rejeito de caulim do rio Capim
(Universidade Federal do Pará, 2008-05-13) MORAES, Milena Carvalho de; LEMOS, Vanda Porpino; http://lattes.cnpq.br/1829861620854008
Industrial and domestic waste cause serious problems for the environment. Industries treatment of kaolin have been deposited reject in large lakes of sedimentation and this has caused accidents as occurred in august/2007 and February/2008. The large volume of kaolin in the lakes sedimentation invaded lakes and rivers from Rio Capim, Para region. This fact resulted in the pollution of waters and death of fish. This problem can be minimized with the use of kaolin reject (KR) in the synthesis of new materials. In this work was used KR treated with organic acid (glycine at concentrations of 5%, 10% and 15% , being obtained the adsorbents: KR-gly-5, KRgly-10 and KL-gly-15, respectively) and mixture NaClO4:HClO4 (proportions 1:50 and 1:75, being obtained the adsorbents KR-NaClO4:HClO4-1:50 and KR- NaClO4:HClO4- 1:75, respectively) and KR as source of Si and Al in the synthesis of zeolites. The materials were characterized by chemical composition and XRD, FTIR, DTA-TG and SEM data. These materials were studied in adsorption process for CrO4 2- from aqueous solutions. The results obtained indicate that the CrO4 2- is adsorbed by kaolin reject and other materials from KR followed this order: KR-gly-10> KR-gly-5>KR-gly-15>KG> KR- NaClO4:HClO4- 1:75> zeolites.
Acesso aberto (Open Access)
Adsorção de molibdato em minerais de argila delaminados e amorfizados
(Universidade Federal do Pará, 2012-04-15) PEREIRA, Patricia Magalhães; LEMOS, Vanda Porpino; http://lattes.cnpq.br/1829861620854008
The search for efficient methodologies to control environmental pollution, as well as the development of technologies in the fields chemical, physical and biological have been widely discussed in order to produce efficient alternatives to improve the quality of life and control of chemical pollutants (organic or inorganic) that over the years are being dumped into the environment so as inconsequential by households and industries. Thus, it is important to know about the adsorptive behavior of metals in the soil, because high concentrations of metals produce adverse effects on the environment. Molybdenum is an essential element for biological functions of plants and animals, but in high concentrations in the body can lead to bone deformities, anemia, abnormal liver and lead to death.The possibility of interaction of organic-inorganic compounds (Humic Acid, Urea andH2SO4) in sediments "in nature” from the region of Acre, was investigated with the aim of evaluating the possibility of applying these materials in adsorption processes in molybdate aqueous solutions. The natural samples used in this study have a high content of clay minerals, mainly smectite, kaolinite and low content of primary minerals such as feldspar and quartz. All samples "in nature" were characterized by XRD, XRF, FTIR, SEM and pHH2O and pHKCl. The modification with inorganic acid concentrations (0.25, 0.5, 1 and 1.5mol.L-1), temperature and contact time are important parameters in the process of delamination of the clay minerals. As the use of organic compounds such as urea and humic acid were efficient in the amorphization. The study by XRD in the modified samples show a change in the structure when H2SO4 at the concentrations used, but this fact is only observed for 15Å peak, characteristic of smectite, all other peaks showed no significant change. The synthesis of organic compounds promoted the amorphization of the smectite peak reference. Thus, as the sediment naturally has clay (smectite, kaolinite), confirmed by XRD and the presence of iron, indicating a transition to the montmorillonite nontronite, and with isomorphous substitution of iron is expected to strong interaction between the adsorption molybdate fractions modified with respect to the natural. The introduction of H+ due to the modification process with sulfuric acid promoted the replacement of calcium ions in the structure confirmed by semi-quantitative analysis performed by EDS. SEM analysis indicated the presence in natural samples cluster morphology, this fact was not observed in the modified samples, which was observed delamination and amorphization. The equilibrium conditions in the adsorption process were investigated in which it is inserted, time of 2 h and the solution pH was measured before and after adsorption. The equilibrium datawere represented by theisotherm models Langmuir, Freundlich and Sips. The adsorption process had better performance in the concentrations for samples and S10H15 S10UH. The humic acid modified samples contained higher Qmáx =3.43, values regression fit to the model obtained indicate Freundlich efficient adsorption process, the modified samples effective adsorbed molybdate anion in comparison to natural sample.
Acesso aberto (Open Access)
Adsorção de nitrato em rejeito de caulim organofuncionalizado com uréia
(Universidade Federal do Pará, 2012-05-30) TAVARES, Laís Conceição; LEMOS, Vanda Porpino; http://lattes.cnpq.br/1829861620854008
Kaolin waste, generated in abundance by companies from Pará state, has caused to the environmental problems. In order to give input on the reuse of this waste was evaluated retention of nitrate ions on kaolin waste natural and modified with urea and studied the equilibrium of adsorption processes at solid-solution interfaces. The materials were characterized by X-ray diffraction and X-ray fluorescence (XRF and XRD, respectiely), IR spectroscopy (FTIR spectrum), scanning electron microscopy and estimated data of surface charge. Adsorption experiments of nitrate ions in the waste natural kaolin (CRJN) and modified with urea (CRJU) were performed without pH adjustment. H + concentrations were measured by direct potentiometry before and after the process of adsorption and equilibrium concentrations of nitrate were measured by ion chromatography. The results indicated: high purity kaolin waste; formation of kaolinite-urea complex confirmed by XRD reflection at 2  8,28o e d = 1.068 nm and the FTIR spectrum with the appearance of a broad band of low intensity, containing two discrete shoulder around 3500-3380 cm-1, corresponding to asymmetric and symmetric vibrations of the group-NH2 of urea-kaolinite, superimposed to the vibration of water. surface charges data, suggesting that the materials have a higher capacity to adsorb cations than anions, but depending on the concentration of H + and OH- on adsorbent, the hydroxyl surface can be protonated yielding positive charges that are reflected in the adsorption of anions, obtaining significant adsorbed nitrate, both in CRJN as CRJU (0,27-0,73 and from 0,18-0,70 3.5 mg g-1, respectively), the separation coefficient (RL) of from 0,28 to 0,828 change in free energy ΔG ° = -2,094 to + 0,445 kJ mol-1 for CRJN and ΔG° = -1,036 to + 1,32 kJ mol-1 for CRJN molecule. The data from RL indicated that the adsorption processes are less favorable in most points of the adsorption processes and based on the results of the free energy change (ΔG º) was showed low spontaneity to no spontaneity and adsorption processes are physical.
Acesso aberto (Open Access)
Adsorção de Pb por caulinita tratada com ácidos acético e cítrico
(Universidade Federal do Pará, 2005) SENA, Luciana Freitas de; LEMOS, Vanda Porpino; http://lattes.cnpq.br/1829861620854008
Acesso aberto (Open Access)
Adsorção simultânea de íons níquel, zinco e cobre em sedimentos argilosos da Formação Solimões no estado do Acre
(Universidade Federal do Pará, 2011-09-02) CARDOSO, Vivian Mariana Miranda; LEMOS, Vanda Porpino; http://lattes.cnpq.br/1829861620854008
Torrential rains in the Amazon region provide large leaching of micronutrients, which can be controlled from the adsorption reactions of micronutrients in clay minerals. Studies on the geochemical properties of sediment containing high concentrations of clay minerals in the adsorption reactions of micronutrients is a research topic of great importance considering the proven use of clay minerals with a wide range of applications in various processes and procedures adsorption, involving the remediation of sediment, purification of air and water. In order to make contributions on the physical and chemical properties of soils and applicability of the Solimões Formation from Acre State was carried out a study to simulate natural competitive adsorption of micronutrients cobre, níquel e zinco in different adsorbents sites present in these sediment and to evaluate the influence of the attributes mineralogical, chemical and physico-chemical from these adsorption processes. Preliminary data on the mineralogy of soil samples allowed to select four stations distributed among four named as H1RA, H6B, H23A H9F and located along the BR 364 and BR 317, as well as outcrops in the river Acre. Analyses of samples were performed by XRD (using the powder in the range 2θ=o 5-75 ; analysis of clay fraction in sheets oriented air-dried in an atmosphere of ethylene glycol o and heated at 550 ° C (2θ = 3 -35 ) analysis total chemical by ICP-OES; element analysis exchangeable and available to determine parameters of soil fertility. In adsorption experiments the equilibrium concentrations of cobre, níquel and zinco were determined by AAS. We used the models of Langmuir isotherm, Sips, Toth, Temkin Rendlich-Petersen and the fit of the experimental data of adsorption. The results indicated that the samples present as major minerals quartz and clay minerals of the smectite group, mica and kaolinite mineral and the 14th (H6B) preliminarily identified as interstratified mica-chlorite smectite-mica or chlorite-vermiculite. The other minerals identified in the samples were gypsum (H1RA), microcline (H6B and H9F) and albite (H9F). The average chemical composition is represented by 60.99% SiO2, 15.91% Al2O3, 5.84% of Fe2O3, 2.21% K2O, 0.34% of Na2O, 1.26% MgO, 0.86% CaO and 0.86% TiO2. The following ranges were obtained for the parameters of fertility: pHH2O = 5.24 to 8.36; pHKCl = 3.16 to 7.02; CTCefetiva = 3.37 to 25.42 cmol c / kg;% V (base saturation) = 83.08 to 97.63; saturation% Ca = 4.28 to 69.21; saturation% = 11.32 to 76.42 Mg, K saturation% = 2.32 to 17.32;. In the adsorption experiments were obtained the following ranges for the amount of each element adsorbed (mg / g) in soil samples selected: Cu) from 91.30 to 147.46 in H1RA, 47.25 to 83.93 in H6B , 67.13 to 137.36 in H9F; 73.01 to 141.35 in H23A, Ni) from 49.97 to 93.81 in H1RA; 42.51 to 113.44 in H6B; 62.52 to 134.86 in H9F; 54.13 to 172.58 in H23A, Zn) from 50.11 to 104.50 in H1RA, 44.31 to 64.12 in H6B; 60.21 to 89.91 in H9F; 73.84-135 , 60 in H23A. In these experiments was obtained the following values for the initial pH of the aqueous suspensions of samples in H1RA pHinicial=3.88 to 5.38; in pHinicial H6B = 2.71 to 3.27; H9F in pHinicial = 3.16 to 4, 24 and in pHinicial H23A = 2.61 to 3.29. The values of pH equilibrium were 4.38 to 5.2 in the H1RA sample, 2.71 to 3.16 in H6B; 3.24 to 4.2 in H9F; 2.51 to 3.14.in H23A. It was concluded that the sediment samples analyzed have suitable properties adsorptive for simultaneous retention of Cobre, níquel and zinco in water; the samples with montmorilonite (station H23A) and mineral 14A (H6B) present adsorption of metals transition at pH values between 2.5 and 3.1. The samples H1RA H9F with different groups of clay minerals (smectite, kaolinite and mica) the adsorption of transition metals occurs at pH values between 3.2 to 5.5. The ionic strength increases with decreasing pH . The best isotherm models to describe adsorption processes of Cobre, níquel and zinco in sediment samples were the Langmuir and Sips models. The values of ns Sips indicated that the majority of adsorption systems fall between the homogeneous heterogeneous systems. The equilibrium data and thermodynamic processes of simultaneous interaction between these ions and mineral adsorbents indicated that the processes are favorable, spontaneous and the type of adsorption is specific (chemical adsorption) with the formation of inner sphere complexes.
Acesso aberto (Open Access)
Afinidades geoquímicas entre sedimentos (solos) e vegetação (gramíneas e cultivares), além de cabelo de ribeirinhos, ao longo das praias de rios da bacia do Juruá, no estado do Acre e sua importância ambiental
(Universidade Federal do Pará, 2005-06-10) RÊGO, José de Arimatéia Rodrigues do; COSTA, Marcondes Lima da; http://lattes.cnpq.br/1639498384851302
The State of the Acre is located in the southwestern extremity of the Brazilian Amazonia, in an area of 153.149 km2, with a low population density (3,66 inhabitants/km2). The studied area comprehends the basin of the Juruá river between the Feijó and Cruzeiro do Sul cities, including Tarauacá and Rodrigues Alves. In the basin the main rivers are: Juruá, Tarauacá, Envira, Muru and Moa. The same carry in sediments great amounts by traction and suspension from siltic- argillaceous rocks of the Solimões Formation and deposite in beaches formed along the rivers. In drought periods the beaches (point bars) are displayed in its meanders and benefit the riparian that use them to leisure and to short cycle agriculture. The beaches sometimes are used to cultivs of maize (Zea-Mays) and beans (Vigna unguiculata (1) Walp). These beaches also present a vegetation succession of canarana grass (Costus spicatus) and orvalho grass (Brachiaria decumbes). This study evaluates the high fertility of the beaches sediments (soils) and the geochemistry affinity between their sediments and the crops besides riparian hair and the environmental importance of this cycle. So the main rivers that constitute the Juruá basin, enclosing Feijó, Tarauacá, Cruzeiro do Sul and Rodrigues Alves cities were related. Nine stations were established along the rivers and samples of beach sediments, canarana grass leaves, orvalho grass leaves and seeds and beans leaves had been leaves were collected. Besides this, measurement of phisical-chemical parameters of the rivers waters were caried out. Human hair samples were collected in the cities. The sediments samples were analyzed by X-ray difraction (XRD) for mineral determination, are by chemical ICP-MS for characterization (major and trace elements). In attempt to verify the content of Major and Trace Elements, like Ca, Fe, K, Na, Ba, Zn, Mo, Co, Cr, Cu, Pb, Hg, As and Se and their sediment — (solil) — crops transference were camet the chemical compositions analyses were carried out with regal water plus MS-ICP and neutron activation. The studied beaches sediments in the cultivated areas excet the beach of Moa river are essentially fine-grained, ranging from fine sand to silt. And are formed by in decressent order quartz, feldspars clay minerals (smectite, illte and kaolinite) and feldspars. Chemical are constitute binaimes by SiO, (68,0 98,9 % in weight), following by significaty lower values, of Fe>03 (0,13 to 4,37 %), MgO (0,02 to 1,03 %), KO (0,16 to 1,94 %), CaO (0,02 to 1,05 %) and Na,0 (0,02 to 1,03 %) and AlOs, are more concentrated in the sediments of Envira, Tarauacá and Juruá rivers. These values compened chemical with that one of the PAAS and, the Upper Crust, are slightly impoverished in Al, Fe, Mg, K, Ti as well as slightly in Ca and Na, diluted certainly for the high contents of SiO2. In general, the rivers waters of the Juruá basin are dark-colored, as white waters type, due to inorganic material in suspension (suspensates) in high concentration. The criterion of suspensates and phisical-chemical parameters (pH, DO, TDS, temperature, resistivity, electric conductivity and salinity) delimit three geographic zones (sub-basins): a) Envira-Tarauacá, b) Juruá and c) Moa rivers. The first one presents the highest values of all the analyze phisical-chemical parameters, except resistivity, and the area coincides with the more fertile land area State of the Acre. Among the studied vegetables the canarana grass leaves revealed are richerest in K, S, Ca, Mg, P than orvalho grass leaves. Canarana and orvalho grass present chemical similarity in relation to K, P, S, Mg and Ca elements. Only canarana grass, collected in the sediments of the Juruá river tends to become richer in Ca and S. The chemical elements transference sediment (soil)-vegetable presents an absorption for vegetal of the K>P>Ca>P. This order presents the major values for vegetables collected in the sediments of Envira river, emphisizing the importance of Envira river with greater transference potential of macronutrients and being a probable pointer of its superior fertility in relation to the other rivers of Juruá basin. In the sediment-crop-human chain the cycle of Hg shows that in the beach sediments of the Juruá, Envira and Tarauacá rivers the average concentration of Hg (27 ppb) in the sediments below the background range (50 ppb) and in the plants is in according to normal considered range (< 500 ppb) for plants that grow in soils with low contents of Hg; the average contents of Hg in hair in Tarauacá, Cruzeiro do Sul, Rodrigues Alves and Feijó rivers is about 3992 ppb. The lower concentration (average 1680 ppb) was found in Feijó and the higher (6240 ppb) in Cruzeiro do Sul, being normal values and slightly impact indicators, not observed in the region. The slightly anomalous values of Hg in hair is not related to the crops, as well as to the sediments. For hunam other sources of Hg disponibilization must be evaluated as fish or domestic or wild animals meats. The beaches and abrupt declivities (banks) of the white water rivers of the central and western regions of Acre (Juruá basin) are really fertile, adequated to short cycle agriculture and its nutrients and other elements are completely assimilated by vegetables and crops. For the present study the chemistry of the sediments and crops, as well as of human hair, shows that the region does not present geochemistry anomaly of any considerable antropogenic impact.
Acesso aberto (Open Access)
As águas subterrâneas de Belém e adjacências: influência da Formação Pirabas e parâmetros físico-químicos para medidas de qualidade
(Universidade Federal do Pará, 1996-04-08) SAUMA FILHO, Michel; LIMA, Waterloo Napoleão de; http://lattes.cnpq.br/1229104235556506
In the Metropolitan Region of Belém (PA) the water supply to the population comes from springs (physiographic area of Utinga) and from a network of positional tube wells, in general, in more remote urban areas or where pumping is precarious. This work evaluates the groundwater used in the Metropolitan Region of Belém, correlating data of physical, physical-chemical and chemical parameters, in an attempt to compose an understandable picture about the quality of these waters, and to verify the influence that they suffer from the geological units in which they are located. the aquifers that preserve them are located. To carry out the work, water samples were collected in two different seasonal periods: dry and rainy. After exhaustive consultation of the files of companies, institutions and researchers, 17 tubular wells were selected, 9 in Belém, 5 in Icoaraci, 2 in Mosqueiro and 1 in Ananindeua (Annex A). The most frequent turbidity indices were between 9 and 14 units (ppm of SiO2), but some wells showed higher values (33, 41 and 71 ppm of SiO2. Only in some cases, this turbidity can be immediately correlated with the silica content obtained by chemical analysis. The most frequent color measurements are in the range from zero to 7.5 U.C., with the zero index predominating. However, some wells showed a value above 100 U.C. and others, less frequent, with indices varying between 20 and 60 U.C. The pH and electrical conductivity were quite different parameters. Thus, the highest pH and electrical conductivity indices were verified in the aquifers of the Pirabas Formation. In these cases, the pH was around 6 .4 to 7.6 and conductivity between 231 and 362 µS/cm, with a discontinuity at 87.5 µS/cm, also attributed to a well associated with the aforementioned Formation. More acidic waters (pH below 6.38 and above of 4.01) are certainly attributed to the aquifers of the Barreiras and Post-Barreiras Group. The chemical constituents, notably the contents of Ca2+, Mg2+, Na+ and K+, are consistent with the interpretation of the numerical values of pH and electrical conductivity. Without exception, the concentrations of Ca2+ are higher than those of the other cations, establishing a decreasing order according to Ca2+> Mg2+> Na+>K+, with some inversion between Na+ and Mg2+. The highest concentrations of Ca2+ (soon followed by Mg2+) result from the dissolution of carbonates present in the Pirabas limestone. In fact, confirming this assertion, the concentrations of HCO-3 are also much higher than the concentrations of Cl- and SO2-4. It is to be expected, therefore, that the dissolution of Pirabas sediments produces higher concentrations of Ca2+ and HCO-3. The silica and iron contents also discriminate such waters. In general, higher silica contents correspond to greater depths, as would be expected, taking into account the action of chemical weathering on silicate minerals. As for iron, this constitutes a differentiating parameter of the waters of the Pirabas Formation, almost always at much lower levels than the corresponding values associated with the Barreiras and Post-Barreiras aquifers, with, however, exceptions, in which appreciable indices of iron related to Pirabas sediments. It should be noted that the Pirabas Formation appears in the Metropolitan Region of Belém almost always at depths greater than 100 m, although there are records of smaller depths, but these are apparently rarer situations, as is the case with well number 3. , on the University Campus, near the Guamá River, with a depth of 76 m, and the 94 m well of the Museu Paraense Emílio Goeldi, in the central area of the city (Annex A). The exhaustive consultation of the aforementioned archives of institutions, companies and researchers led to the realization that many tubular wells installed in the urban area use water associated with the Barreiras and Post-Barreiras aquifers, where the pH values are almost always, below 6 units, and electrical conductivity measurements rarely reach 100 µS/cm. Finally, it appears that there is a need for greater investments in order to increase the prospection and use of groundwater in the region, as these, in addition to dispensing with treatment prior to distribution, are still a source of resources, not dimensioned, but of great potential.
Acesso aberto (Open Access)
Alteração hidrotermal e potencial metalogenético do vulcanoplutonismo paleoproterozoico da região de São Félix do Xingu (PA), Província Mineral de Carajás
(Universidade Federal do Pará, 2015-08-27) CRUZ, Raquel Souza; VILLAS, Raimundo Netuno Nobre; http://lattes.cnpq.br/1406458719432983
The region of Sao Felix do Xingu, south-central Pará, exposes a volcano-plutonic system exceptionally well preserved and grouped in the Sobreiro and Santa Rosa formations, in which hydrothermal alteration and mineralization associated were recognized. The Sobreiro Formation consists of lava facies flow of andesitic, basaltic andesite, and dacitic composition, according to the proportions or absence of clinopyroxene and/or amphibole phenocrysts. Volcaniclastic facies is genetically associated and is represented by mafic crystals tuff, lapilli-tuff, and massive polymictic breccia. Santa Rosa Formation is fissure-contolled and composed of lava flow facies and associated volcaniclastic facies of felsic crystal tuffs, ignimbrites, lapilli-tuff, and massive polymictic breccia. Part of this system is interpreted as ash-flow caldera partially eroded and developed in several stages. Conventional petrography, X-ray diffraction (XRD), scanning electron microscopy (SEM), and infrared spectroscopy show hydrothermal alteration paragenesis occurring in these rocks. In general, the alteration minerals develop subeuhedral anhedral crystals and replace magmatic minerals. The types of hydrothermal alteration identified are incipient the pervasive and are distinguished propylitic, sericitic, intermediate argillic, and potassic, which overlap, and fracture-controlled silicification associated with hematite and carbonate. Propylitic alteration, prevalent in Sobreiro Formation, presents both pervasive and fracture-controlled styles. The paragenesis consists of epidote + chlorite + carbonate + quartz + sericite + clinozoisite ± albite ± hematite ± pyrite, which is overlapped by pervasive potassic alteration or fracture-controlled, mainly represented by potassic feldspar + biotite ± hematite. Locally, fracture is filling with prehnite-pumpellyite association that suggests geothermal low-grade metamorphism conditions. The sericitic alteration is marked by the occurrence of mainly sericite + quartz + carbonate ± epidote ± chlorite ± muscovite. It is manifested mainly in mafic crystal tuff. However, the overlap of these types of changes is evidenced by relics of propylitic chlorite alteration and textures of rocks, partially obliterated, in which there were only pseudomorphs of sericitized plagioclase. In the Santa Rosa Formation the sericitic alteration is pervasive and characterized by the occurrence of sericite + quartz + carbonate. Also presents fracture-controlled, which is represented by sericite + quartz. It is the main type of change identified in this unit by assigning the whitish rocks. SEM data show that, associated with the sericitic alteration occur lead phosphate, gold, rutile, and barite. The potassic alteration is more subordinate, generally associated with granitic porphyry and locally to rhyolites. Paragenesis is given by microcline + biotite + chlorite + carbonate + sericite ± albite ± magnetite. The intermediate argillic alteration was recognized in rhyolites and possibly corresponds to the final stages of hydrothermal alteration. It is characterized by the presence of montmorillonite + illite + chlorite + sericite ± kaolinite ± halloysite ± quartz ± hematite, which were identified by infrared spectroscopy and XRD. It gives whitish to whitish pink to the rocks. The hydrothermal alteration types were mainly controlled by temperature, fluid composition, and fluid/rock ratios. They are compatible with thermal anomalies related to magma, and possible temperature decrease due to mixing and neutralization with meteoric water, similar to that described in low- and intermediate-sulfidation mineralization. Gold identification and compatible accessories phases provide important information for prospective studies in the region, especially for potential intermediate- and low-sulfidation epithermal deposits of precious metals (gold and silver) in volcano-plutonic systems with related ash flow calderas, as well the Au(Cu) and Mo porphyry-type deposits.
Acesso aberto (Open Access)
Ambiente geológico e mineralizações associadas ao granito Serra Dourada (extremidade meridional) Goiás
(Universidade Federal do Pará, 1983-08-29) MACAMBIRA, Moacir José Buenano; VILLAS, Raimundo Netuno Nobre; http://lattes.cnpq.br/1406458719432983
The Serra Dourada granite belongs to a set of domic structures, generally mineralized in cassiterite, located in the center-east of Goiás, where rocks of the Uruaçu and Brasília folding belts and the Goiás median massif dominate. In order to contribute to the petrological, metallogenetic and stratigraphic knowledge of these granitic rocks, the southern tip of Serra Dourada was selected for this study. The methodology adopted was mapping at a 1:45,000 scale, petrographic, minerographic and geochronological studies, in addition to the determination of the contents of major elements in rocks and some minerals, and of trace elements in rocks. The granitic rocks of Serra Dourada were classified as syenogranites, presenting three varieties: amphibole-biotite granite, muscovite-biotite granite and biotite granite, the latter being dominant. The K-Rb graph indicates an advanced degree of fractionation for these rocks and suggests a trend that starts from granite to amphibole and ends in muscovite. In turn, the systematic variation of the contents and ratios of some trace elements reveals an intimate relationship between these varieties, meaning multiple intrusions that correspond to different degrees of partial fusion of the original material. In attempts at dating by the Rb-SR method, it was observed that the phenomena subsequent to the initial lodging in the crust introduced possible isotopic rejuvenations. However, these granitic rocks provided maximum conventional ages close to 2 b.a. The last magmatic phases of the Serra Dourada granite were the pegmatites which, in the core of the batholith, are zoned and contain aquamarine, while at the edge they bear tantalite-columbite, emerald, muscovite and monazite. Then, large amounts of hydrothermal solutions enriched in Sn and F reached both the granite and its host, changing them to greisens. Upon contacting the enclaves, the solutions precipitated cassiterite, magnetite, fluorite and sulfides. Veins with wolframite and rutile lodged in the nearest enclaves. At lower temperatures, these solutions generated kaolin when reaching the pegmatites of the contact range. Several types of enclaves have been identified in the granite: biotitite, soda-gneiss, xenoliths of schists and quartzites, and amphibolites. The soda-gneiss enclaves are trondhjemitic in nature and also have amphibole and biotite, biotite and biotite and muscovite varieties. The similarity of the assemblage and chemistry of some mineralogical phases suggests a consanguinity between soda-gneiss and granite, with the possibility that they are partially intact fragments of the rocks that gave rise, by anatexia, to the granitic material. On the other hand, the contents and anomalous ratios of some elements of soda-gneiss indicate reaction with magma, which is emphasized by the position of these rocks in the K-Rb graph. This reaction certainly affected the isotopic ratios, allowing only to suggest an Archean age. In turn, the biotites are possibly restricted. The sequence where the Serra Dourada granite was lodged is composed of intercalations of schists and quartzites from the Serra da Mesa Group. The typical mineralizations of acid magmatism, greissens, pegmatites and granitic sills in the metasediments, in addition to xenoliths from the enclosing rocks and pronounced foliation at the edges of the body, testify to the intrusive character of the granite in these metamorphites, whose late-syntectonic event is associated with the formation of the brachyanticlinium, which agrees with the regional structural pattern. Through the mineralogical assemblage of these rocks, conditions of low amphibolite facies were attested for its formation, where pressures above 4.5 Kb and temperatures around 550°C.
Acesso aberto (Open Access)
Análise da dinâmica da cobertura e uso do solo na bacia hidrográfica dos lagos Bolonha e Água Preta, Belém, Pará.
(Universidade Federal do Pará, 2024-12-20) BARROS, Jackison Mateus Lopes; SOUZA FILHO, Pedro Walfir Martins e; http://lattes.cnpq.br/3282736820907252; https://orcid.org/0000-0003-0252-808X
The increase in the urban population in the world has impacted river basins that supply water to cities, including the treatment and distribution of drinking water for domestic, industrial and commercial use. One example is the Bolonha and Água Preta Lakes Hydrographic Basin (BHLBA) in the Belém Metropolitan Region (RMB), the second largest urban agglomeration in the Brazilian Amazon, with 2.3 million inhabitants. One of the best ways to monitor the dynamics of river basins is through remote sensing techniques with orbital images, due to the quality of the spatio-temporal data. This work aims to analyze the changes in land cover and use in the last four decades in the BHLBA, through images from the Landsat satellite series from the years 1984, 1989, 1994, 1999, 2004, 2008, 2018, 2021 and 2023, using a geographic object-oriented image analysis (GEOBIA) methodology. Thus, the classes of lakes (L), urban area (AU), aquatic macrophytes (MA), arboreal vegetation (VA) and pasture (P) were evaluated. The overall accuracy of the images showed values around 90%, with the main error being allocation errors. Changes that occurred over the years were identified, such as the significant growth of macrophytes on the water surface of the Bolonha and Água Preta lakes, which decreased by approximately 3.7%. A 13.4% increase in arboreal vegetation in the BHLHA was also recorded, evidencing a forest recomposition. A 3.2% growth in urban areas around the BHLBA was also observed, which is worrying because human influence can put the health of the water supply sources of the RMB at risk. The GEOBIA methodology proved to be adequate for the study and we recommend that monitoring be continued due to the socio environmental importance of the area under study.
Acesso aberto (Open Access)
Uma análise de cluster via CiteSpace a propósito da espectrometria WDXRF para geocientistas (2001-2021)
(Universidade Federal do Pará, 2023-08-17) CASTANHO, Rebeca Soares; PAZ, Simone Patrícia Aranha da; http://lattes.cnpq.br/5376678084716817
The present bibliometric analysis addresses the use of Wavelength Dispersive X-Ray Fluorescence (WDXRF) spectrometry in geochemical analysis to evaluate scientific trends over a twenty-year period, from 2001 to 2021, using the academic and free bibliometric tool, CiteSpace. For this purpose, 941 international scientific articles involving WDXRF were collected from the Web of Science (WoS) platform using the search terms "wdxrf" or "wavelength dispersive x-ray fluorescence". The data analysis was divided into two parts: the first part aimed to understand and interpret the quantitative aspects of the scientific production related to the technique, while the second part involved a co-occurrence analysis of keywords from the retrieved works. Despite fluctuations, there has been a constant increase in the number of articles related to this spectrometry technique, with 2020 being the year with the highest productivity in the historical series (105 publications). The United States of America leads the country rankings (110 articles); however, the relatively homogeneous distribution of these studies reveals that WDXRF is a widely disseminated technique worldwide. Brazil ranks among the top ten most influential countries in this field, occupying the eighth position with 59 publications. The journal X-Ray Spectrometry, with 82 articles, stands out as the primary venue for the dissemination of research on this analytical technique. In total, 569 keywords were found, connected by 2002 co-occurrence links. The term "trace element" denotes a solidified but always relevant interest in the use of WDXRF for this level of chemical analysis. On the other hand, "nanoparticle" is the keyword with the highest citation explosion over the past two decades, particularly between 2015 and 2021, highlighting a more recent trend in the elemental characterization of nanostructured compounds. The CiteSpace program identified 13 thematic groups, with five being the most notable in the application of this instrumentation: nanomaterial characterization (cluster #0), trace-level heavy metal analysis (cluster #1), chemical speciation (cluster #2), analysis of particulate matter on filters (cluster #5), and provenance of historical ceramics (cluster #6). In summary, it can be concluded that the chemistry of geological materials does not constitute a narrowly defined body of studies concerning WDXRF. Instead, it represents a scientific frontier that expands through interdisciplinary approaches, providing new and integrated methodological approaches to geoscientific research for those who delve into this technique.
Acesso aberto (Open Access)
Análise de imagens Landsat ETM, Radarsat-1 e modelos numéricos de terreno para o mapeamento dos índices de sensibilidade ambiental ao derramamento de óleo na costa de manguezais do nordeste do Pará
(Universidade Federal do Pará, 2006) BOULHOSA, Messiana Beatriz Malato; SOUZA FILHO, Pedro Walfir Martins e; http://lattes.cnpq.br/3282736820907252
Accidents related to exploration and oil transport are a threat to coast zones araund the world. Oil spills are an ecological disaster that may cause irreparable damage to the environment affecting living beings that live in these coast zones and also the local economy. Characterizing coast environments is very complex because of the many limiting factors during the mapping process. When it comes to humid tropical environment, like in Pará northeast coast, it gets worse because this area is typically dominated by macro tide. First of all, the macro tide plain creates low areas where informations about the relief are, most of times, scarce and the plain metric representation is dominant. Secondly, the tide variations with its vertical and horizontal moving produces strong changes on the sediment coast environment limits. Thirdly, the geomorphological modifications in the coast areas are intense and fast. Towards this context, the objective of this master’s degree dissertation is to create a map of the coast environment and a rating map of the environmental sensitivity about the oil spills in a certain part of Pará state northeast coast. The methodology consisted on processing digital images from remote sensors in the range of optical (Landsat ETM +7) and microwave (RADARSAT–1 Wide-1) associated to data from the SRTM (shuttle radar topographic mission) digital model of elevation, and to the field data collected in SIG (geographical information system) environment, providing an integrated analysis of the spectral, geomorphological, altimetrical and sedimentological characteristics of the coastal environments in cartographic georeferenced bases. The most important results of this dissertation allowed: 1) The evaluation of the potential of the images Landsat ETM +7, RADARSAT-1 and of the multi sensors fusion products used for identifying the coastal environment and the Environment Sensitivity Rates (ISA) of oil spills in this areas 2) Recognizing and describing five main morphological unities and fourteen sub unities: Coastal Plateau, Tide Plain, Coastal Plain and Alluvial Plain 3) Identifying and classifying eight unities of Environmental Sensitivity Rates (ISA) for the Amazon coast zone which are: ISA 1B – support wall; ISA 3B – exposed scarps with declivity to the sand; ISA 9B – sand bank and plains of tidal vegetable mudflats; ISA 9C – hypersalt herbaceous fields, ISA 10A – salt and salobre herbaceous fields; ISA10C – Mangrove; ISA 10D – Lea; 5) creation of the Environmental Sensitivity Rates map to oil spill of the studied area. The using of remote sensors techniques and SIG proved to be an important tool for recognizing and analyzing coast environments and for generating maps to coast environments and to environmental sensitivity rates to oil spills in the northeast coast of Pará.
Acesso aberto (Open Access)
Análise integrada da paisagem para avaliação da vulnerabilidade à perda de solo das margens da Baía de Marajó, estado do Pará
(Universidade Federal do Pará, 2011-11-30) GUIMARÃES, Ulisses Silva; COHEN, Marcelo Cancela Lisboa; http://lattes.cnpq.br/8809787145146228
Marajó Bay is part of the Coastal Zone in the Amazon estuary, and it constitutes a form of "V" with intensive processes of erosion and progradation. The bay shores are the object of this study, from the west coast, represented by the west coast by Salvaterra and Soure municipalities, to the east coast of Mosqueiro Island. The purpose is to analyze the coastal environments adjacent to the Marajó Bay, with a systemic and integrated approach using thematic databases (geology, geomorphology, pedology, climatology and Use and Land Cover) and remote sensing images (Landsat TM 5 and MDE SRTM) to prepare maps syntheses of landscape units and vulnerability to loss of soil as a subsidy to coastal management. The main steps of this methodology are: i) atmospheric correction by dark-object subtraction, geometric correction by orthorectification, with supervised classification algorithm Spectral Angle Mapper (SAM) through training samples to map the Use and Land Cover; ii) compilation, adaptation and classification to improve data of morphology; iii) development of derivatives geomorphometric; and, iv) integration of the thematic basis for map algebra, with an overlap equation for synthesis of the landscape units maps and another equation for the preparation of the arithmetic average map of vulnerability to loss of soil. The Marajo Bay shores have mostly the unit of Fields with 17.61% of the study area (50,483.16 ha), maximum altimetry of 58 m, the topography is flat and smooth, the relief were overwhelmingly straight and planar. The integrated data indicate that the pedogenetic processes prevail in only 3.58% (10,231.38 ha) of the study area. The areas in balance between morphogenic and pedogenetic processes correspond to 3.75% (10,737.63 ha), while morphogenesis is prevalent in 42.40% (121,317.39 ha). The superiority of morphogenic units shows the hazard of coastal environments per surface mechanisms, how substrate desegregation and erosion by processes of runoff and mass displacement.
Acesso aberto (Open Access)
Análise palaeoambiental e caracterização dos Folhelhos Negros da Formação Barreirinha utilizando análises Multiproxy
(Universidade Federal do Pará, 2025-06-04) CARVALHO, Wivian Maria Rodrigues; BRITO, Ailton da Silva; http://lattes.cnpq.br/9873489431846769; HTTPS://ORCID.ORG/0000-0001-9224-5563; SOARES, Joelson Lima; http://lattes.cnpq.br/1345968080357131
The initial sedimentation phase of the Barreirinha Formation was associated with a rapid relative sea-level rise during a significant marine transgression event that flooded the Amazon Basin. These organic-rich shales outcrop along a narrow yet extensive belt located on the southern margin of the Amazon Basin. Few studies have specifically addressed the potential paleoenvironmental variations linked to the deposition of these shales. This is mainly due to the relative lithological uniformity of these rocks—composed predominantly of fine-grained sediments—and their economic relevance, which has directed most research toward the maturation of organic matter. To investigate the paleoenvironmental variations during the deposition of these fine sediments—focusing on sedimentary dynamics, the origin, and provenance of the organic matter—a multiproxy approach was applied, combining various quantitative, semi-quantitative, and qualitative techniques. The analyzed stratigraphic succession is mainly composed of gray to black shales, exhibiting facies variations related to coarse terrigenous input and episodes of bioturbation. These features suggest a deep, distal, anoxic marine depositional environment, with no evidence of carbonate sedimentation, typical of the Abacaxis Member of the Barreirinha Formation. Mineralogical cluster analyses indicate a dominance of kaolinite, characterizing the Kaolinite Facies, with subordinate quartz, sulfates, and sulfides in the lower portions. The base of the succession includes massive fine-grained sandstones with cross-bedding, correlated with the Ereré Formation, interpreted as deltaic to inner shelf deposits. The transition to laminated shales interbedded with sandstones and siltstones marks the onset of the Devonian (Frasnian) transgression, with substantial continental input evidenced by heavy minerals, pyritized plant remains, and tasmanites. The presence of dumpstones suggests glacial influence and ice-rafted debris deposition. Upper levels show more homogeneous shales, enriched in organic matter, lacking bioturbation and detrital minerals, indicating maximum anoxia during the peak of the transgressive event in the Amazon Basin. Diagenetically, the shales underwent compaction, fracturing, mineral substitution, oxidation, and intense pyritization, mainly as framboidal pyrite—typical of reducing marine environments. The mineralogy is dominated by kaolinite and quartz, with accessory minerals indicating alteration processes and possible Jurassic-Triassic igneous intrusions (Penatecaua magmatism), which contributed to increasing the thermal maturity of the kerogen. Rock-Eval pyrolysis and biomarker analyses reveal Type II-III kerogen with gas-generating potential, ranging from immature to post-mature depending on proximity to igneous intrusions. These findings reflect a transgressive system strongly influenced by environmental controls and regional thermal input.
Acesso aberto (Open Access)
Análise paleoambiental da Formação Pirabas no litoral do Maranhão, Brasil
(Universidade Federal do Pará, 2011-06-03) OLIVEIRA, Samantha Florinda Cecim Carvalho de; ROSSETTI, Dilce de Fátima; http://lattes.cnpq.br/0307721738107549
The Pirabas Formation is a geological unit known for its abundant fossil content, which includes a large number of invertebrate and vertebrate groups. This unit is exposed in the north and northeast coast of Brazil, in the States of Para, Maranhão and Piaui. The majority of the studies focusing the fossils of the Pirabas Formation emphasized initially, invertebrates. However, studies using ichthyoliths have been increasingly emphasized in the last years, which is due to their resistance to dissolution, transportation and deposition. Moreover, the small size favors their continuous recovery along different stratigraphic levels, allowing their use as an additional tool in paleoenvironmental interpretations. This work aimed to prospect ichthyoliths of the Pirabas Formation exposed along the coast of the State of Maranhão, as well as their identification and integration with facies analysis. This study area is part of the São Luís Basin, which is filled with a 4,000 m-thick sedimentary succession represented mainly by Cretaceous rocks, with a thin Cenozoic cover, the latter represented by the Pirabas and Barreiras Formations deposited mostly in the Miocene. The exposures studied occur along various cliffs between the towns of Alcantara and Guimarães. Miocene carbonates with ichthyoliths record in this location are occasional, occurring as thin layers up to 2 m thick, which are laterally and vertically intergraded with siliciclastic deposits. These strata occur as three stratigraphic units, with the second one documenting fossiliferous carbonates related to the Pirabas Formation. The cliffs studied include the ones in the localities of Canelateua, Mamuna Grande, Peru and Base. We analyzed 16 thin sections sampled from these localities, which resulted in description of four carbonate microfacies, and one of mudstone. The samples provided 30 ichthyoliths, which were photographed, identified and described under a scanning electron microscope. In addition to the ichthyoliths, the petrographic study recorded the presence of other fossils, including bryozoans, foraminifera, gastropods, bivalves, algae, and echinoids. The integration of paleontological data and microfacies is consistent with deposition in carbonate paleoenvironments predominantly with low energy, reducing conditions and subjected to the frequent introduction of siliciclastic grains. These characteristics, added to the low fossil frequency in most of the samples, corroborate previous interpretations that the deposition of these strata occurred in paralic, probably estuarine palaeoenvironments. However, the abundance of marine fossils in some samples, associated with the presence of ichthyological elements common in environments with normal salinity, shows periodic introduction of saline inflows. Therefore, we can conclude that the strata analyzed were deposited in association with an estuarine system, but representing more distal facies of this system, representative environments more exposed to marine influence.
Acesso aberto (Open Access)
Análises sequenciais para o ouro em solo do salobo 3A, Serra dos Carajás
(Universidade Federal do Pará, 1989-06-07) FRANCO, Maria Esmeralda Bravo Esteves Bouça; RAMOS, José Francisco da Fonseca; http://lattes.cnpq.br/8189651755374537
The Salobo 3A area. in Serra dos Carajás in the State of Pará belongs to an elongated range. according to the WNW-E SE direction. of Archean age, which borders the northern flank of the Carajás syncline. This area has been the subject of several studies, with the aim of prospecting and extracting copper ores and using their by-products. The aim of this work is to investigate the distribution of gold in soils in the area of the Salobo 3A copper sulphide deposit. Eighteen samples were collected in horizontal and vertical profiles next to gallery G1 and another sixteen from wells PA-O8 and PA-23. Soil gold concentrations were determined according to the sequential partial opening of Gatehouse et al. (1977), which was supplemented by organic extraction. due to the low concentrations of this metal in soils. The phases considered separately were iron and manganese oxides and hydroxides (amorphous and crystalline), organic matter and clay mineral silicates and quartz. A particle size fraction < 120 mesh was chosen. to avoid the presence of larger metallic gold particles. In addition to sequential analysis. another 5 grams of the same sample were etched with HF+HCl04 and another 5 grams with HF+HCl04 followed by etching with aqua regia (Au-total). All results were compared with those obtained by the instrumental neutron activation analysis and with DOCEGEO analyzes performed through the aqua regia aperture. The main objective of this work is to show the suitability of sequential analyzes for gold in soils and, through the results obtained for the studied phases, to deepen the knowledge about the behavior of gold in a supergenic environment. Of these, it is worth noting the good correlation between the gold concentration determined in the organic matter and the Au-total concentration in the soil (or even only with aqua regia, or with values obtained by INAA). The study of the amount of organic matter related to the gold adsorbed on it seems to be in agreement with the mechanisms of mobility and transport of gold in a supergenic environment known so far. From the analyzes carried out, it is concluded that, in general, little gold is found in the native state, if the concentrations obtained by the partial extractions are compared with the Au-total concentration of the samples. This element is preferentially found in silicates (clay minerals and quartz), in organic matter and in goethite (in smaller amounts).
Acesso aberto (Open Access)
Aplicação da modelagem hidrodinâmica na circulação do estuário do rio Maracanã (NE do Pará)
(Universidade Federal do Pará, 2017-10-16) BARBOSA, Leandro Patrick Ferreira; EL-ROBRINI, Maâmar; http://lattes.cnpq.br/5707365981163429
The coastline of NE Pará presents a configuration cut and a large number of estuarine systems, very active with amplitudes of tide between 5-7m.In this region, is inserted the estuary of the river Maracanã - estuary of coastal plain and the type and mixed - with a length of 101 Km from igarapé the tube to the island of Cumaru. The profile of this is typically meandrante, low slope that allows runoff, and allows a pattern of drainage with large amount of water in several directions and an order of flow of 103 to 104 m3 s-1.This estuary likely a result of the system of macro-tides (> 4m), the semi-diurnal nature, with winds of influence (average of 6 m / s) and the tidal currents (mean of 69.53 cm / s). The climate is the type Am (Tropical Wet), which is characterized by being warm and humid (Climate Equatorial Amazon), with temperature between 25 ° C and 28 ° C and rainfall of 2,500 mm / year to 3,000 mm / year, and two distinct periods, a dry (June to November) and another rainy season (December to May). The work was aimed at the implementation of the hydrodynamic modeling the movement of the estuary of the river Maracanã (NE Pará), using as a modeling tool (Program Design SisBAHIA - Base Hidrodinâmica Environmental System), based on interpretation of the data collected in the field and experimental studies conducted in the laboratory. The methodological procedures consisted of three basic steps: bibliographical survey, work of field and laboratory. In the field, were performed: (1) a survey of semi-ecobatimétrico detail, employing is a Ecossonda DGPS / PLOTTER / SONAR FURUNO GP-1850 F, which were made transects ecobatimétricos cross-sectional and longitudinal in the estuary during the flood tide, ( 2) measurement of currents, tidal, to obtain measures of intensity and direction of currents in a point (00 ° 45187 'S and 47 ° 26712' W), over a period of continuous sampling of 8 days (preamar e) (baixamar 04/02/07 to 11/02/07), covering sizígia. To this end, it was used a Correntógrafo Falmouth Scientific 2D-ACM, (3) the monitoring of the vertical tide was based Marégrafos Orphimedes Brand OTTHidrometrie, which recorded the water level at the same time, near the mouth and the inner part of the estuary, for a period of 8 days continuous every 20 minutes. In the laboratory: (1) the data processing environment ecobatimétricos in Excel for correction in relation to the level of tide. Still, the Surfer was used for scanning the data input for the hydrodynamic model of the Program Sisbahia, (2) time series of the level of current and tide were subjected to routine data processing environment developed in Excel (3) For flow was conducted an estimate based on simple and rational.The data were then processed for analysis: (1) In implementation of the model, were gathered all the data collected in the study area and these data were supplied to the model within a predefined area, (2) For calibration of the model Adjustments were made in an attempt to merger of the data collected in the field and model, (3) the validation of the model, which was the accuracy of the results of the computational model in relation to its purposes, and the natural system that it represents, in order to reproduce the actual phenomena. Then put up the model pra "run", that is, the model will generate scenarios of ebb tide, flooding, and squaring sizígia. With this, could itself describe the patterns of movement of estuarine river Maracanã and understand the aspects of their complex hydrodynamics. Thus, it is obtained, maps featuring patterns of current averages upright over a cycle of the tide sizígia and quadrature (half ebb tide, half flood tide, estofa of preamar and estofa of baixamar). It was observed that during the tides of sizígia, the speeds are higher if compared with the tides, squaring. The geometry of the estuary is responsible for restricting the penetration of coastal waters and help to raise the tide inside of it. The results generated by the model were not equal to those measured in the field, because of the complexity of the area and the amount of data acquired.
Acesso aberto (Open Access)
Aplicação de dados SRTM (Shuttle Radar Topography Mission) no estado do controle neotectônico da rede de drenagem e microbacias hidrográficas, na região de Urucu e Adjacências (AM)
(Universidade Federal do Pará, 2009-09-01) PINTO, Marcelo Lima; BORGES, Maurício da Silva; http://lattes.cnpq.br/1580207189205228
Geologic studies of the Neogene of the Amazon have shown significant evidence of recent tectonic processes, analysis, particularly from the structural control of the valleys and rivers. Given this context, the objective of this study referred to the research area of neotectonic Urucu and Surroundings (AM) through the structural analysis of drainage systems and topography from digital products, namely, images SRTM (Shuttle Radar Topography Mission). The understanding of the latest tectonic structure, the region of Urucu (AM), is fundamental in defining the current landscape geometry. Thus, this study was crucial for the recognition of reactivated structures (NE-SW, NNE-SSW, NW-SE) and neoformed (EW and ENE-WSW), which certainly influence the control of landscape drainage and relief during the Neogene to the present. The initial analysis of alignments of drainage and relief from SRTM images allowed the interpretation of two main sets of discontinuities. The first set includes the structures oriented EW and ENEWSW, which are associated guidelines NE-SW and NNE-SSW. The second set brings together the structures positioned to NW-SE and NNW and SSE. The first set relates to a structure with probable transcurrent movement, where NE-SW orientations represent "splays" who are willing to make up a structural sigmoidal-like duplexes directional. Structural assemblies oriented NNESSW seem to represent a second pulse within that directional movement / transpressive. The second set is represented by discontinuities NNW-SSE. These guide the geometry and impose asymmetries in the drainage network, which are compatible with the definition of "fronts" and reverse in relief. The landscape seen resembles those developed drives dip-slip "normal. A second pulse of drive geometry of normal fault oriented NW-SE limits floodplains and causes the dam's natural river system, providing displacement of fluvial channels. Latter pulse probably occurred during the Holocene. Also, based on geophysical data type field of Total Reduced IGRF (International Geomagnetic Reference Field) can be seen that there is a strong correlation between neotectonic structures and magnetic anomalies, indicating that the structures are associated with the newly formed structures EW and ENE-WSW and structures of reactivation of ancient structures are presented with directions NE-SW, NNE-SSW, NW-SE.
Acesso aberto (Open Access)
Aplicação de geoprocessamento na análise ambiental das bacias hidrográficas do Igarapé Juruti Grande e rio Aruã – Juruti – Pará
(Universidade Federal do Pará, 2007-03-26) TANCREDI, Nicola Saverio Holanda; BORGES, Maurício da Silva; http://lattes.cnpq.br/1580207189205228
The study area is located in the region of Juruti, enclosing the river Juruti Grande and Aruã watershed, with 4,560 km2. The region within equatorial humid climate has a mean annual precipitation of 2,223 mm, showing dense forest with great number of vegetal species. The pedology shows essentially yellows latossolos and in the Amazon river flooding plains, hydromorfic soils. This region is placed in Amazon Sedimentary Basin within superior part, a thick package of Cretaceous rocks, poor consolidated, of the Alter do Chão Formation, being recovered by Quaternary aluvial deposits, distinguished that of the Amazon river floodplain. The Juruti Grande and Aruã’s watershed present good conservation condition. However, the Juruti Project for explotation of bauxite is developed in the plateaus of these basins, by Alcoa Inc., passing this area for intense speculation, with great pressure on the environment, being necessary periodic monitoring by competent agencies for maintenance of the balanced ecosystem. Thus, the geoprocessing blunts as an efficient, fast alternative and low cost for this environmental monitoring, evidenced in these research. It were made use of methodologies to manage the natural capital of the inquiry area, developing geographic information systems (GIS), therefore has vital paper in the administration of the space information of the environment, easing the management by digital way of cartographic data and allowing them elaboration of prognostics and diagnostics of environmental problems, underlying the planning and the decision makes. In this way the application of GIS in the inquiry area have great value, once the region of Juruti passes and will pass, for great transformations in ecological and social-economic aspects, letting only more, a marginal region from Amazonia. In the GIS’s building for this area, accomplished the storage of the geometry and the attributes of georreferencing data, radar and satellites images, acquiring in the years of 1972, 1986, 1997, 2000, 2001 and 2005. The multitemporal boarding allowed access information of qualitative and quantitative evolution of the land use and alterations of the natural vegetal covering, making possible, modified analysis of biomas among the different compared years, understood as basic for initial evaluations of the ecology of the landscape, overall with respect to its land covers. The computational procedure made possible an initial evaluation of metric parameters (overall related the paisagistic diversity) of automatic manner, beyond the generation of digital thematic maps. The development and application of these technological methodologies (geoprocessing and remote sensing applied at images of radar and satellites), in the Juruti region, made possible the generation of diverse representative products, as the multitemporal land use maps, declivity correlation with the relief, drainage trends, and others. The thematic and land use classification maps of the area had presented the evolution of landcovers in the four years used as reference. The application of the kappa’s index for the quality of the thematic mapping evaluation pointed a result of 0,72, indicating a very good classification. The thematic maps and the respective comparative graphs had shown that the forest area presented 91.8% of the area in the year of 1986; 87.22% in 1997; 85.57% in 2001 and 74,92% in 2005. The antropics and secondary forests areas, had increased proportionally to the reduction of the area of forests. The correlation map of declivity within relief presented predominance of areas with low declivity, specially the fertile swamp areas and that almost plain reliefs. The regions that had presented ondulate to strong reliefs are mainly, in the central part of the watershed. The interpretation of main neotectonic structures with detailed drainage network analysis considered the straight line trends as drainage trends. It was detected NE-SW directions well narrow characterizing long belts in SE part of the area. Near Amazon river it has NNE-SSW belts.
Acesso aberto (Open Access)
Aspecto geoquímicos do material particulado da pluma estuarina do rio Amazonas: fatores que controlam as interações com as águas oceânicas
(Universidade Federal do Pará, 2000-02-10) PEREIRA, Simone Baía; EL-ROBRINI, Maâmar; http://lattes.cnpq.br/5707365981163429; https://orcid.org/0000-0001-7850-1217
The geochemical aspects addressed in this investigation are the determination of the chemical composition of the material in suspension in coastal waters under the influence of the mouth of the Amazon River, indicating the possible location of the source of suspended material, as well as the influences that it suffers along the continent transition -ocean. X-ray diffraction analysis indicated the predominance of kaolinite, illite and quartz clay minerals over the other identified inorganic components, observing the presence of chlorite, sometimes as a subordinate mineral in some samples, sometimes as a trace, and smectite in trace grades, which, like chlorite, is also present as a subordinate mineral. The centesimal mineralogical composition of the particulate material was estimated, associating the analytical results with X-ray diffraction data, using stoichiometric calculation, based on the scientific literature. The results obtained through the stoichiometric calculation confirm the tendency shown by the diffractograms. It is observed that the dominant clay minerals are kaolinite (maximum in 51.19%), associated with high levels of aluminum, distinguishing the dominance of this clay mineral in the sample in which this fact occurs, and illite (maximum in 42.43%) associated At high levels of potassium, when this clay mineral dominates the samples, the presence of iron and titanium colloids was also admitted. The content and nature of the organic matter associated with suspended sediments were evaluated, using elemental analysis for carbon, nitrogen and hydrogen, thermogram records and absorption spectra in the infrared region. In the sediments, organic compounds predominate (clay minerals, silica, iron colloids), with organic matter always having a content below 3.6%. Therefore, in interpreting the records of absorption spectra in the infrared region, the most intense bands are related to the dominant clay minerals in the material, that is, the illite and kaolinite mixture. Bands related to chemical bonds in clay minerals dominate in the infrared spectra. The clear and intense vibration band of the Si-O stretching, which extends from 1200 to 1000 cm-1, with its most significant developments around 1180 and 1034 cm-1, is well representative of structures of the illite and kaolinite types. And there is still a clear band, with weak folds around 950 to 915 cm-1, related to the Al-OH bond; bands around 790-800, 750-780, 640-690 cm-1; or in the range of 400 - 600 cm-1, the intense absorption bands recorded in the range of 4000 - 3400 cm-1, with their various developments, related to the bonds with hydroxyl, –OH, so common in clay minerals and an intense and average band recorded around 1640 cm-1 corresponding to the angular deformation of the HOH bond, a characteristic of constitutive water present in clay minerals. The infrared absorption spectra of humic and fulvic acids from different sources are similar but not identical. The (subtle) differences are the result of brief changes in their compositions. Perhaps the most interesting feature of the spectrum of humic acids is the appearance of intense and broad absorption bands related to the stretching vibrations of the C=O bond of several organic functional groups (carboxylic acids and their derivatives, aldehydes, ketones), in the range from 1709 to 1715 cm-1 and vibrations of aromatic compounds around 1600 to 1613 cm-1. The bands recorded around 1698 to 1701 cm-1 and around 1400 cm-1 indicate the presence of carboxyl and carbonyl groups. The most interesting aspects of the recorded spectra concern the appearance of clear (but weak) absorption bands in the range of 2959-2885 cm-1, attributed to methylene groups –CH2- of hydrocarbons; and the presence of a weak (but clear) band around 1385 cm-1 referring to the carboxyl and/or carbonyl groups. Leading to the conclusion that it is humic material present in organic matter from leaching and drainage of typical Amazonian soils, such as podzolic and latosolic. Elementary organic carbon contents range from 1.27% to 2.05%, while nitrogen contents range from 0.03% to 0.13%. These contents produce high C/N ratios (minimum 12.7% and maximum 68.3%) of material rich in cellulose decomposition products of vegetable origin. The integration of data from the chemical analysis of suspended matter with physical-chemical parameters of coastal waters and the variation in phosphorus levels (minimum of 0.06% to maximum of 0.71%, expressed in P2O5), associated with salinity variation (minimum of 24.31‰ and maximum of 39.19‰), used as limiting parameters, defined the existence of three characteristic zones of origin of suspended material: one predominantly terrigenous, one transitional and one predominantly oceanic biogenic.