Teses em Geologia e Geoquímica (Doutorado) - PPGG/IG
URI Permanente para esta coleçãohttps://repositorio.ufpa.br/handle/2011/6341
O Doutorado Acadêmico pertence ao Programa de Pós-Graduação em Geologia e Geoquímica (PPGG) do Instituto de Geociências (IG) da Universidade Federal do Pará (UFPA).
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Tese Acesso aberto (Open Access) Aproveitamento do rejeito de caulim na produção de alumina para cerâmica e sílica de baixa granulometria(Universidade Federal do Pará, 2000-11-29) FLORES, Silvia Maria Pereira; NEVES, Roberto de Freitas; http://lattes.cnpq.br/9559386620588673The Amazon region detains 10% of the world reserves of kaolim. Since the seventy's, two great amazonic beds of kaolim are explored, producing kaolim for paper cover. In the beneficiation process, it's generated an elevated volume of polluted industrial residue which is deposited in extensivas and onerous lagoons of sedimentation. Because of the residue is very voluminous, these lagoons become an environmental problem of great proportions, due the extensivas deforested areas used for their constructions ( Barata, 1998). In this work, are suggested altematives of economic utilization of this residue, which is constituted, mainly, by a suspension of the claymineral kaolinite, for the production of pozolane, aluminium sulphate, the synthesis of the ammonium alum and alumina for ceramics utilization. The methodology constitutes in the drying and the calcination of the residue, followed by the extraction of the AI retained by the acid lixiviation H2SO4 ) followed by the ammonium alum crystallisation, for the reaction with the concentrated NH4OH, by means of pH control, and later calcination at 1200°C, getting a-Al2O3, with no sodium and Iow granulometry. From the aluminas obtained, are made bodies of proof smashed and sintered at 1600°C, to the determination of the ceramics properties, which are compared to one of the commercial alumina. After the acid lixiviation for the AI extraction, results as an insoluble material, an amorphous silica, for which it is suggested, as an additional contribution, an economic application, using it as artificial pozolane in building portland cement, making mechanics tests for the evaluation of its performance. The material that were used and synthesized were characterized throught the use of the X ray diffraction, eletronic scanning microscopy, the infra-red spectroscopy, thermogravimetry, differential thermic analisys, particle size analysis, specific area BET, porosity, chemical analisys throught umid means and throught X ray fluorescence.Tese Acesso aberto (Open Access) Transformações térmicas e propriedades cerâmicas de resíduos de caulins das regiões do rio Capim e do rio Jari – Brasil(Universidade Federal do Pará, 2006-03-23) MARTELI, Marlice Cruz; ANGÉLICA, Rômulo Simões; http://lattes.cnpq.br/7501959623721607; NEVES, Roberto de Freitas; http://lattes.cnpq.br/9559386620588673Mullite, Al6Si2O13, is a relatively rare mineral in nature, formed under exceptional conditions of high temperature and pressure, which can be used to synthesize this mineral. Mullite presents excellent mechanical resistance at high and normal temperatures; low thermal expansion coefficient; good chemical and thermal stability. Such characteristics explain the importance of mullite in traditional and advanced ceramics. This research proposes the development of a process to synthesize mullite using the wastes from kaolin processing industries located in the rio Jari (Monte Dourado-PA) and rio Capim (Ipixuna-PA) districts. Preliminary studies are made on the synthesized materials for application as base materials for grog and silicon-aluminum refractory bricks. The steps are: (a) mineralogical and chemical characterization, verifying the differences between the materials; (b) processing through calcinations of the wastes at increasing levels of temperature with 100 oC increments, ranging from 600 to 1500 oC, during 3 hours at each level, so mineralogical changes can be observed and; (c) the study of temperature and impurities effects through X-ray powder diffraction, scanning electron microscopy, green bodies cleavage, thin layer and polished section; and of ceramics properties, through green bodies retraction (shrinking). The results of this work indicate that detrites from kaolin industries at rio Jari and rio Capim are constituted mainly by kaolinite. The PR samples showed a higher level of structural order than the CR samples. The increase in calcination temperature favored agglomeration in both samples. A higher content of Fe in the CR samples influenced mullite formation, activation energy, and linear shrinking in sintering. Also, through to the results of the refractarity essays, both industrial waste samples showed that they can be used as starting materials for refractories and grog.