Artigos Científicos - IG
URI Permanente para esta coleçãohttps://repositorio.ufpa.br/handle/2011/3239
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Item Acesso aberto (Open Access) Caracterização química e mineralógica de birnessita natural da Mina do Azul (Província Mineral de Carajás, Brasil) e seu análogo sintético (K-OL-1) obtido pelo método sol-gel(Universidade Federal do Pará, 2016-06) FIGUEIRA, Bruno Apolo Miranda; ANGÉLICA, Rômulo Simões; COSTA, Marcondes Lima da; MERCURY, José Manuel Rivas; SANTOS, Manoel Roberval Pimentel dos; POELLMANN, HerbertThis paper presents a comparative chemical and mineralogical study of birnessite (BIR-AZ) collected from Azul mine (Carajás Province, Brazil) and its synthetic analogous synthesized by sol-gel method. The products were characterized by X-ray diffraction, FT-Raman spectroscopy, thermal analysis (TG-DTA), scanning electron microscopy (SEM) and ICP-MS techniques. The results obtained confirm the presence of well-defined layer structures having monoclinic system, C2/m space group and the unit cell parameters are: BIR-AZ, a = 5.148 Å; b=2.843 Å, c=7.175 Å, and β = 100.75º; K-OL-SG, a = 5.150 Å; b = 2.846 Å, c = 7.214 Å, and β= 101.29º. The birnessite from Azul mine ores shows thermal stability up to 600 ºC, whereas its synthetic analogous, above 900 ºC. FT-Raman bands at 635, 570 and 410 cm-1 were identified and attributed to the Mn-O and K-O bond deformations in the birnessite structure. SEM images reveals that the manganese oxide mineral consist of platy packed particles of about 1 to 5 µm. By contrast, the morphology of the synthetic compound displays randomly arranged globules (<1 µm).Item Acesso aberto (Open Access) Sílica gel obtida de escória de alto forno: Marabá, Pará(Universidade Federal do Pará, 2015-09) REBELO, Monaliza Maia; NASCIMENTO, Lidiane Diniz do; CORRÊA, José Augusto MartinsSilica gel with similar properties to commercial silica was obtained from blast furnace slag (EAF) using digestion with hydrochloric acid. The EAF-silica was obtained and characterized by different techniques. The results showed that the EAF-silica obtained was amorphous, with 99.7% purity and specific area 282 m2/g. It presented high hydrophilic character (12.27%), with constitution water of ~ 6.18%, which was confirmed by mass loss in thermogravimetric analysis. The EAF-silica particles had micrometric sizes (< 1 µm) with aggregates, unimodal size distribution and D50 7.0 µm.Item Acesso aberto (Open Access) Síntese de zeólita do tipo faujasita: comparação entre caulim beneficiado e caulim flint(Universidade Federal do Pará, 2015-06) ROCHA JUNIOR, Carlos Augusto Ferreira da; ANGÉLICA, Rômulo Simões; NEVES, Roberto de FreitasThe main purpose of this work is the synthesis of faujasite zeolite using three different kinds of kaolin from the Amazon region, Brazil: two kaolin from the beneficiation process for paper coating and hard or flint kaolin, a non-processed kaoling from the mining site. Analysis of the reaction products of kaolin showed the formation of faujasite zeolite. Flint kaolin showed a lower potential with respect to zeolitization ratio Si/Al equal to 2, compared to processed kaolins, probably related to the iron present in the structure. New results show a complete change in the formation of faujasite, which turns to be the main mineralogical phase after iron removal.