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Teses em Geologia e Geoquímica (Doutorado) - PPGG/IG

URI Permanente para esta coleçãohttps://repositorio.ufpa.br/handle/2011/6341

O Doutorado Acadêmico pertence ao Programa de Pós-Graduação em Geologia e Geoquímica (PPGG) do Instituto de Geociências (IG) da Universidade Federal do Pará (UFPA).

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Acesso aberto (Open Access)
Análise crítica das metodologias gerais de mapeamento geotécnico visando formulação de diretrizes para a cartografia geotécnica no trópico úmido e aplicação na região metropolitana de Belém escala 1:50.000
(Universidade Federal do Pará, 2001-11-09) COSTA, Tony Carlos Dias da; ABREU, Francisco de Assis Matos de; http://lattes.cnpq.br/9626349043103626; GANDOLFI, Nilson; http://lattes.cnpq.br/2605833412394930
This thesis brings within its scope the critical analysis of the main national and international methodologies of geotechnical cartography (IAEG, Australian, French, EESC-USP, IPT, IG-UFRJ and IG-SP), as well as the classification of a set of rules for the elaboration of geotechnical maps and charts in the Brazilian Humid Tropics. It also presents geotechnical mapping at the scale of 1:50 000, of the Metropolitan Region of Belém, in the State of Pará, comprising the municipalities of Belém, Ananindeua and Marituba. The methodology is based on the above-mentioned cartographic (conventions/ rules), and is presented in the form of eleven cartographic items: a documentary map of the Metropolitan Region of Belém, at a scale of 1:50 000; a documentary map of the central area of Belém, at a scale of 1:10 000; a gradient map; a geological map; a map of unconsolidated materials; a soil use map; a map of institutional areas and conservation units; a map of floodplain and mainland areas; a map of zones of permanent protection of water bodies; a chart of the preferential areas for the exploration of natural construction materials; and a chart of the preferential areas for the installation of sanitary landfills.
Acesso aberto (Open Access)
Análise da dinâmica das áreas de manguezal no litoral Norte do Brasil a partir de dados multisensores e hidrossedimentológicos
(Universidade Federal do Pará, 2016-12-16) NASCIMENTO JUNIOR, Wilson da Rocha; SOUZA FILHO, Pedro Walfir Martins e; http://lattes.cnpq.br/3282736820907252
The objective of this research is to analyze the dynamics of the mangrove areas in the north coast of Brazil from images of remote orbital sensors and hydrosedimentological data (flow and suspened sediment concentration). We tried to understand the existence of causality between the expansion or retraction of the mangroves with the suspened solid discharge calculated from the data of flow and suspened sediment concentration. The mangroves were mapped, using the object oriented classification technique, in the years 1975, 1996 and 2008 based on data from microwave sensors (RADAM / GEMS, JERS-1, ALOS / PALSAR). The data of fluviometric stations and sediments of the National Water Agency were used to calculate the solid discharge in suspension in the rivers Araguari, Gurupi, Pindaré, Grajaú and Mearim seeking to relate the addition and erosion in the areas of mangrove with the sedimentary load of the rivers that drain On the coast. The flow variations reflect the precipitation in the sub-basins of the analyzed rivers and presented a strong and moderate correlation with the temperature anomalies on the surface of the Pacific Ocean evidencing a relation of the El Niño and La Niña phenomena with the precipitation regimes in the Amazon. The variations of suspended sediment concentration were not related to the fluviometric variation suggesting that the annual mean oscillations are reflections of other phenomena (coverage and land use). The results show that the drainage areas of the sub-basins most impacted by the anthropic action contribute with a higher sediment load to rivers that have a higher concentration of native forest. Native vegetation contributes to containment of soil erosion and exposed soil and pasture areas are more vulnerable to soil erosion. The Gurupi, Pindaré, Grajaú and Mearim Rivers presented solid suspended load higher than or equal to the Araguari River. Analyzing the mangroves in the estuaries we noticed the addition of mangroves along the estuaries of the Gurupi and Mearim rivers (Baia de São Marcos) and the reduction of mangrove areas in the Araguari estuary. The Amazon coastal zone is subject to natural processes of great magnitude, but atrophic activities influence the natural dynamics of the region by implementing unsustainable economic practices.
Acesso aberto (Open Access)
Análise evolutiva da paisagem da serra Tepequém - Roraima e o impacto da atividade antrópica
(Universidade Federal do Pará, 2008-01-23) BESERRA NETA, Luiza Câmara; BORGES, Maurício da Silva; http://lattes.cnpq.br/1580207189205228; 1580207189205228; COSTA, Marcondes Lima da; http://lattes.cnpq.br/1639498384851302; 1639498384851302
The north area of Roraima State presents great diversity of geomorphologic featuresformed by dissected plateaus, limited by intermountain plain and relief with a plateau morphology that it is individualized in the extensive plain areas, e.g., of the mountain Tepequém. Since 1930s this was a site of intense activity of diamond extraction what printed changes in the landscape. The main objective of this study is to understand the dynamics evolution of the landscape of the mountain Tepequém under diamond extraction activity and the reason of its erosion susceptibility, being natural or anthropic. To reach these objectives, a description of profiles of soils and saprolitic rock, as well as lateritic profiles were accomplished. Samples of soils, altered rocks, laterites and coal were collected. Besides, width, depth, extension and directional alignment of the channels of the gullies measurements were carried out. The collected materials were submitted to the following analyses: grain size, by humid way; minerals identification by X-ray diffraction and SEM techniques; total chemistry analysis (major elements) by ICP-MS and content of organic matter, humidity and density of the soil measurements. Coal samples were submitted to radiocarbon analyses by AMS (Accelerator Mass Spectrometry). Appling the interpretation of optical images (Landsat-5/TM and Cbers-2/CCD) and the cartographic base, maps of structural alignment, relief (altimetry and declivity), drainage and vegetation covering were also elaborated. The mountain Tepequém stand out among the landscape dominated by relief of hills, residual hills and plane-slightly wavy surfaces because of its rectangular-rhombic format and outline of steep scarps elaborated on sedimentary rocks of Paleoproterozoic. The drainage system of the area delineates parallel, angle-rectangular and faults standards. The relief and drainage morphology of the mountain Tepequém and its around area define a subordination to the structural arrangement E-W, NE-SW and NW-SE directions represented by normal and strike-slip faults. In the mountain Tepequém, the geomorphologic compartments are established by 575 to 670 m high plain intra-valleys surfaces bordered by less than 774m high hills and residual hills and edge slopes less than 1100m high. The bush grassy savanna dominates this landscape and recovers the edge scarps and extends along the regional plain. The ciliary forest covers small stains along the Cabo Sobral and Paiva rivers. This scenery was quite modified because of diamond extraction activity. However, with the decline of this activity, the ciliary forest recovers spontaneously, as the optical images of the last 22 years shows (1984, 1995 and 2006). Intra-valleys plains were developed on sandy soils constituted by medium and fine grain size sandy domains, sub-angles to sub-rounded poorly selected, with low cohesion and small quantity of organic matter. These soils are developed on saprolitic derived of sandstones and siltstones. Locally stone lines and colluvial are observed, usually on the saprolitic. Immature laterites are found in the center-north hills of the mountain Tepequém. Quartz, muscovite in sub-milimetric plates and kaolinite partially involving the grains of quartz are predominant in soils constitution, while the lateritic profiles are constituted by gibbsite, goethite and hematite, besides quartz and kaolinite. Laterite and quartz fragments constitute the stone lines. High concentrations of SiO2 confirm the essentially quartz-character of the soils, while the values of Al2O3, K2O, MgO, Fe2O3 and TiO2 are more expressive in the saprolitic zones, confirming the kaolinite, muscovite and hematite domain, derived of claystones and siltstones. The radiocarbon ages in coal obtained for the superficial materials (colluvial and stone lines) show that these materials were formed at least 3.822 years BP. The intermountain plains reveal in its landscape erosive features in the piping formations, dolines and gullies, developed in the lands with sandy to silt materials domain. The channels of gullies are mainly aligned in the directions NE-SW and NW-SE corresponding to the directions of fractures and faults that section the Tepequém Formation. The seemingly stabilized gullies are partially covered by ferns that grow on the side and bottom surfaces of the channel. The evolution of the landscape of the mountain of Tepequém specially the formation of its general internal structure involves the tectonic still in Proterozoic. The inherited morphology reflects in the steep scarps around as well as in the top such a great synclinorium. The evolution of the landscape of the mountain of Tepequém during Cenozoic is marked by formation of small hills, some of these protected by lateritic crusts suggesting registration of a humid and hot paleoclimate in Pleistocene, which can admit the installation of the drainage net. The erosive process of the fluvial courses allies with the high gradient favored the transport of part of the sediments to W-SW direction, contributing in the formation of the intermountain plains. The current scenery is marked by the erosive retaking favored by the sandy non-cohesive nature of the soils, ally to a paleorelief inclined to the valleys and strongly fractured and failed that causes a strong shallow surface stormflow propitiating the piping formations, dolines and then the gullies. Thus, the diamond extraction activity can contribute in the intensification of the gullies but, however, it was not the decisive factor. Therefore, the evolution of the landscape of the mountain Tepequém in Proterozoic and in Cenozoic until the present is due to the interaction of multiple processes involving the tectonic history, the weathering changes and the several erosion cycles, as well as the restricted sedimentation and the small anthropic contribution.
Acesso aberto (Open Access)
Aplicação da composição isotópica de multielementos no monitoramento ambiental de área circunvizinha à barragem de rejeito: o caso da mina de cobre da Serra do Sossego, Canaã dos Carajás – PA
(Universidade Federal do Pará, 2017-06-09) OLIVEIRA, Simone Pereira de; MOURA, Candido Augusto Veloso; http://lattes.cnpq.br/1035254156384979
Tailings dams from ore mining activities are relevant compartment for environmental monitoring because the dam can present undesirable forms of water outlets such as infiltration. The present thesis proposed multielement isotope study in order to evaluate the use of the isotopic composition of oxygen, hydrogen, strontium and lead as a tool for the environmental monitoring of groundwater vulnerable to the tailings dam. This research was conducted in the area of the Serra of Sossego copper mine and, in addition to the isotope study, the hydrochemical characterization of groundwater and surface water was caried out. Besides, the direct reading of the isotopic composition of lead (without chemical treatment of the water sample) was applied for the first time, using multicollector inductively coupled plasma mass spectrometry, in the laboratory Para-Iso. The hydrochemical characterization of groundwater in the Serra do Sossego mine area showed that it is moderately acid (pH ~ 6). Only the AP15 and PS32 wells, under the influence of the drainage of the mixed pile (ore waste + sterile), presented high electrical conductivity (599 μS / cm2 and 694 μS / cm2) and the higher sulfate content (1.82 to 6.57 Meq/L). In general, iron (29.7 mg/L), manganese (69.7 mg/L) and copper (24.9 mg/L) present the highest metal content in the groundwter. In terms of the isotope studies, the groundwater of PS17, PS04, AP15 and PS32 wells and the water of the Dam present the least radiogenic lead isotopic composition. The water sampled in the AP15 and PS32 wells would be representative of the lead isotope signature of groundwater in the mine area (206Pb/207Pb = 1.1481 to 1.1663) and, probably, is indicative of the lead isotope composition of the meteroric water. The lead isotope composition of the groundwater of the wells PS04 (206Pb/207Pb = 1.1784-1.1850) and PS17 (206Pb/207Pb = 1.2100 to 1.2160) may indicate a small contribution of the rocks of the region (206Pb/207Pb > 1.6807). In turn, the lead isotope signature of water of the Dam (206Pb/207Pb = 1.2279) suggests, as expected, a slightly more pronounced contribution of the ore and the rocks. On the other hand, the lead isotopes of the water sampled in the wells MNA23 and PS06 show a more radiogenic signature (206Pb/207Pb = 1.6741 to 1.9196), which is similar to those of the chalcopyrite and the diabase of the Sequeirinho open pit, revealing a more significant contribution of the ore and rocks. As the lead isotope composition of water from the dam is different from that of the groundwater, it can be used for the environmental monitoring of the influence of the water from the dam in groundwater in the Serra of Sossego mine area. In those wells with less radiogenic lead isotope signature, a possible contribution of the water from the dam would result in a more radiogenic lead isotope composition in the groundwater. Conversely, in those wells with more radiogenic lead isotope signature, a contribution of the water dam for the groundwater would decrease the values of the measured lead isotope ratios. On the other hand, the application of the sulfur isotopes for environmental monitoring presented some limitation in the study area, due to the lack of contrast of the sulfur isotope composition among the sulfides of the Sossego deposit (δ 34S ~ 2-7 ‰), the water from the dam (δ 34S ~ 2 ‰), and the drainage of the mixed pile (δ 34S ~ 2‰). This prevents the recognition of a possible contribution of the tailings dam to groundwater. Mixing models using the 87Sr/86Sr ratio as a function of the strontium concentration and δ 18O values, also showed some limitations, since there is no contrast between the values of the 87Sr/86Sr ratio of the water from the dam (0. 7458 to 0.7539) and the rocks of the mine area (granite ~ 0.7474). Such similarity, in principle, would not allow identifying the contribution of the water from the dam. However, since groundwater generally exhibits less radiogenic values of the 87Sr/86Sr ratio (0.7161 to 0.7283) and well below the dam values, the strontium isotopic composition can be used for environmental monitoring of groundwater. Hydrogen and oxygen isotope data revealed that, in the rainy season, the groundwater presented values of δ 18O and δ D varying from -2.74 to -7.17‰ and from -15.6 to -46.0‰, respectively. In turn, an enrichment of 18O and D, with values of δ 18O between -1.67 and -7.29 ‰ and of δ D between -0.23 and -46.1 ‰, is observed in the dry season. Hydrogen and oxygen isotope composition of the water from the dam (δ 18O from 1.24 to 2.79 ‰ and δ D from 1.40 to 7.0 ‰) is very different from those of the groundwater and of the drainage of the pile. A mixing model performed with oxygen and hydrogen isotopes showed that these elements are the ones that best respond as indicators of the contribution of the waters from the dam to groundwater. The application of this model revealed no influence of the water from the dam on the groundwater during the period of this study. The results obtained in this multielement isotopic study suggest that the environmental monitoring of the groundwater of the Serra do Sossego mine to investigate the possible contribution of the water from the dam, can be done more efficiently with the oxygen and hydrogen isotopes. The isotopic compositions of lead and strontium can also be used for monitoring the groundwater, but this has to be done more systematically due to the small contrast between the isotopic composition of these elements in the dam water and in the groundwater. Finally, the isotopic composition of sulfur is the one that would contribute least to the environmental monitoring of the groundwater of the study area.
Acesso aberto (Open Access)
Arcabouço estrutural e geocronologia dos granitóides da região de Várzea Alegre: implicações para a evolução crustal da Província Borborema
(Universidade Federal do Pará, 2024-07-25) SOUSA, Luis Kennedy Andrade de; DOMINGOS, Fabio Henrique Garcia; http://lattes.cnpq.br/3975188208099791; https://orcid.org/0000-0002-2447-3465; GALARZA TORO, Marco Antonio; http://lattes.cnpq.br/8979250766799749; https://orcid.org/0000-0002-7271-4737
In the Borborema Province, in northeastern Brazil, several granitic batholiths and plutons are found, which are records of subduction and collision episodes related to the Brasiliano Orogeny. Within this large orogenic system, the emplacement mechanisms of many granites are closely related to the development of deep-seated shear zones, one of which is the Patos Shear Zone, which in its western segment is composed of slices of rocks such as granites, gneisses, metapelites, quartzites, and amphibolites that form an imbricated system. In this context, the present work was carried out with the aim of bringing new geochronological and microstructural data to add to the understanding of the nature of the processes that formed and modified the undifferentiated granitoids in the Várzea Alegre region (CE). The granites are classified as Biotite Monzogranite and Garnet Monzogranite, they present phaneritic and porphyritic textures, in some places, their mineralogical composition is mainly composed of plagioclase, K-feldspar, and quartz, in addition to biotite, muscovite, and garnet. The granitoids are composed of elongated bodies concordant with the host rocks. The deformation imposed on the granitic bodies developed ductile structures with NE-SW orientation and kinematic criteria indicate that the deformation occurred predominantly dextral. Microstructural features, observed mainly in rocks near the edges of the granitic bodies, show that quartz crystals exhibit microstructures such as sutured to lobate contacts, undulating extinction, ribbons, and the chessboard pattern, indicative of recrystallization by grain boundary migration (GBM), compatible with temperatures of 500ºC. Biotite crystals that define the mylonitic foliation characterize a spaced foliation that separates microlite domains formed by aggregates of quartz and plagioclase, with asymmetric lenticular geometry in the granites, similar to the foliation impressed on the gneisses of the Granjeiro Complex. Based on EBSD data, the granites exhibit a grain size distribution with a concentration of crystals <100 μm. From the pole figures, the quartz OPC shows that the dominant system was rhombohedral to prismatic, indicating a medium to high deformation temperature, in a context of progressive non-coaxial deformation. However, from the interpretation of the misorientation angle, it is shown that during the deformation history of the granites, these bodies underwent lower temperature deformation. U-Pb geochronological data on zircon provided crystallization ages of 573 to 576 Ma for this granitic magmatism. The Hf-TDM C model ages of these granitoids ranged from 2.84 to 3.30 Ga and the ƐHf(t) values from -21.9 to -29.6 suggesting a strong incorporation of mesoarchean crustal source. Similar Sm-Nd data in whole rock show that these granitoids have Nd-TDM model ages between 2.14 and 3.33 Ga and ƐNd(t) values between -20.02 and -31.79, suggesting a strong contribution from meso paleoarchean and paleoproterozoic crust (orosirian to riacian) to the formation of the granitic magma that originated the granites in the Várzea Alegre region (CE). These granitic bodies are classified as Itaporanga type and sin-transcurrent, as they have similar ages and structural features to other sin-transcurrent granitic bodies in the Borborema Province. These granites were generated from magmatism associated with the change in the predominant deformation in the Borborema Province, which was the result of the final stages of the Brasiliano Orogeny within the context of simple deformation, with the development of large shear zones.
Acesso aberto (Open Access)
Argamassas históricas de Belém do Pará.
(Universidade Federal do Pará, 2019-09-16) LOUREIRO, Alexandre Máximo Silva; ANGÉLICA, Rômulo Simões; http://lattes.cnpq.br/7501959623721607
The city of Belém, northern Brazil, known as the metropolis of the Amazon, was established on the banks of the Guajará Bay on January 12, 1616, with the denomination of Nossa Senhora de Belém do Grão-Pará, capital of the Grão-Pará province, now the state of Pará. Currently, Belém still has layers of lime mortar on its colonial and imperial buildings, which protect the secular structures and provide evidence of how this material was produced early in its history. Over the years, the deteriorating aspects identified in lime mortars, which damage both aesthetics and functionality, are related to the humidity, saline efflorescence, biological colonization, and/or anthropic actions. Once deteriorated, mortars require maintenance, consolidation, or replacement, which are difficult procedures that can lead to the use of inappropriate materials. Therefore, a good collect and characterization strategies of the original material is necessary for the restoration of historical monuments, because in studies focused on restoration science, the intervention strategy needs to include the use of building materials compatible with the original materials. Thus, the main objective of this doctoral thesis is to determine the characteristics and properties of historical mortars in Belém do Pará from the 18th and 19th centuries, as well as to propose a restoration mortars compatible with the historic mortars, which using industrial waste from Amazon Region. Therefore, this thesis was structured in three independent and complementary thematic articles, which addresses the topic of the historical mortars of Belém do Pará, since their characterization until the proposal of restoration mortars: 1) Investigation of the historical mortar of Belém do Pará, Northern Brazil; 2) How to estimate the binder: aggregate ratio from aerial lime-based historical mortars for restoration? and; 3) The use of industrial waste of the Amazon region in lime-metakaolin restoration mortars: compatibility assessment. Thus, the physical, chemical and mineralogical characteristics were determined, as well as the physical and mechanical properties of the historical material and the restoration material. The results of the historical mortars characterization pointing their main components, their functions and raw materials, besides indicating the analytical techniques used for binder: aggregate ratio quantification, which obtained good accuracy and reliability in your results. Moreover, the results show a wide range of characteristics and properties obtained through restoration mortars, which can serve as a benchmark for other studies or even for practical applications in historic masonry. Therefore, it was possible to identify the restoration mortars most compatible with the historical mortars of Belém do Pará, Northern Brazil.
Acesso aberto (Open Access)
Aspecto tectôno-sedimentares do fanerozóico do nordeste do estado do Pará e noroeste do Maranhão, Brasil
(Universidade Federal do Pará, 1992-09-16) IGREJA, Hailton Luiz Siqueira da; FARIA JUNIOR, Luis Ercílio do Carmo; http://lattes.cnpq.br/2860327600518536
A synthesis of the tectono-sedimentary evolution of the Phanerozoic at Northeastern Pará and Northwestern Maranhão is discussed with enphasis to the Bragança-Viseu and São Luis basins. This research is based on field observations, gravity (Bouguer Anomalies), magnetic, seismic, and borehole data interpretations. Five sedimentary sequences are defined: 1) Piriá-Camiranga (Cambrian-Ordovician to Silurian), 2) Lower Itapecuru (Lower Cretaceous), 3) Upper Itapecuru (Upper Cretaceous), 4) Pirabas-Barreiras (Oligocene-Mioceneto Pliocene) and 5) Pará (Quaternarg). The regional basement is an igneous-metamorphic assemblage which outcrops in two windows. The sedimentary and structural features of the Piriá-Camiranga sequence are consistent with a tectono-sedimentary model of coastal environment with fluvio-glacial influence related to a tilted blocks system induced by strike-slip motion. This sequence represents an evolutive stage coincident to the Eo-Hercynian paroxysm (Paleozoic) which ended with the closure of the Atlantic I (first geotectonic cycle of the Gondwana). The Lower and Upper Itapecuru, as well as the Pirabas-Barreiras and Pará sequences, are related to the Equatorial Atlantic opening during the Mesozoic and Cenozoic times. They are analysed by severa), authors which reached the interpretations refered to as Models of: Fracture Zones; Anti-clockwise rotation of Africa; Intumescence and fracturing; Clockwise rotation of the South America Nate; and Wrench Tectonics. These models were experimented for the studied area. The time and environments of the sedimentary processes are related to the rift and pos-rift phases of the equatorial coastal basins, but these models were not adequate to explain the structural features. A new model is proposed to explain the origin and development of the basins taking into account a regional NE-SW extension axis and formation of the Bragança-Viseu and São Luís basins with similar polarities. The tectono-sedimentary map for the Phanerozoic of the Northeastern Pará / Northwestern Maranhão enhances the compatibility of the depositional and tectonics systems with two periods of oceanic opening of the Northern Gondwana border.
Acesso aberto (Open Access)
Aspectos litoestruturais e mineralizações Salobo 3A (Serra dos Carajás-PA)
(Universidade Federal do Pará, 1996-10-29) SIQUEIRA, José Batista; COSTA, João Batista Sena; http://lattes.cnpq.br/0141806217745286
The Salobo district is located at the Carajás Province in the Cinzento strike-slip system, and is formed of supracrustal rocks of the Salobo Group and gneisses of Xingu Complex, which were assembled by several generations of shear zones. The Salobo Group includes magnetite-fayalite schist, biotite-almandine-magnetite-fayalite-grϋnerite schist, biotite schist, anfibol schist, chlorite schist, banded iron formation and quartzite. The Xingu Complex includes banded tonalitic gneisses, trondhjemitc and granodiritic gneisses, partialy migmatized. The older shear zones correspond to ductile thrusts to which the generalized imbrication of the lithological units and the tectonic layering, defined by strips and lenses of supracrustais rocks alternated with gneisse is due. Their movements is synchronous to that of the Itacaiúnas belt; minerals transformations under thermal conditions of amphibolite facies, as well as important modifications in the stratigraphic relationships of several lithological units, are related to therm. The second generation of shear zones formed the transtensive Salobo-Mirim duplex. They are sinistral strike-slip shear zones, linked by normal shear zones along which minerals transformations of greenschist facies occurred. The development of the duplex was controled by the former tectonic layering, and its assymetric shape was influenced mainly by the presence of a basement gneiss megalense. The third generation of shear zones is of transcurrent type, with NW-SE and NNW-SSE trends, which modified the Salobo-Mirim duplex geometry, and are interpreted as X features linked to the sinistral moviments. The shear zones of the west corner of the area represent the propagation of a horse tail structure at the west end of the Carajás fault; in these case, they could be oblique thrust. The Salobo 3A deposit is situated in the central part of a normal oblique shear zone, which belongs to a release bend along the main strike-slip shear zone of the Salobo-Mirim duplex. The copper and gold mineralizations are hosted in extension structures, as single and composite pull-apart structures, transtensive sigmoide stringers, tension gashes, pressure shadows and star strucutures in the cross-cutting zones of descontinuities. The Salobo 3 A deposit is an example of concentracion/reconcentracion of cooper and gold mineralizations in s transtensive shear zone due to deformational, hydrothermal and metamorphic processes.
Acesso aberto (Open Access)
Avaliação e aplicação de dados de sensores remotos no estudo de ambientes costeiros tropicais úmidos, Bragança, norte do Brasil
(Universidade Federal do Pará, 2000-11-17) SOUZA FILHO, Pedro Walfir Martins e; EL-ROBRINI, Maâmar; http://lattes.cnpq.br/5707365981163429
The study site is situated in the Cretaceous Bragança-Viseu coastal basin. The holocenic evolution of this area is marked by muddy progradation over a submerging coast, where is developed one of the most mangrove system of the world, with almost 6,000 km2. This research has showed that orbital remote sensing data can provide excellent geologic and coastal land use information. The SAR RADARSAT-1 imageries represent a powerful tool to understand the coastal processes in the wet tropical environments, mainly in the mangrove coasts. This fact is related to microwave radiation can be interpreted for Amazon coastal zone mapping and monitoring, because SAR image constitutes in the unique source of data with all-weather remote sensing capability, in response to difficulty to get optical images in the Amazon, due to all-time cloud cover. Landsat TM imageries are excellent data sources to integration with RADARSAT-1. They present a good performance in coastal environments discrimination. The remote sensing data integration allow a synoptic view of the area and provide geobotanic (relation between coastal environment and vegetation) and multitemporal information. In addition to integrated data, geographic information system (GIS) combines different data sets and simultaneously interprets the spatial and temporal relationship between various coastal environments. This way, GIS allows for a more comprehensive, accurate and easier interpretation of a geomorphologic mapping under an organizational philosophy to control data towards use the information to coastal zone management. The application of remote sensing data in the tropical coastal studies was used in different approaches. In relation to spatial and temporal variability of the shoreline, this study has revealed that during the Holocene, the coastal plain is marked by a muddy progradation. However, from the analysis of the remote sensing images were possible investigate the shoreline variability under long (1972-1998) and short (1985-1988, 1988-1990, 1990-1991) term, which is characterized by shoreline retreat, probably due to climatic changes, such as El-Niño and La-Niña events. These climatic events control the rainfall along the coastal zone, where severe erosional period (1985- 1988) are coupled with high precipitation rate (> 4,000 mm/yr.). From the point of view of the spatial analysis of the coastal changes, the mangroves constitutes one of the most environments to be analyzed by remote sensing images, as in the electro-optical spectrum due to their high reflectance in the infrared, as in the microwave due to their rough surface responsible for high backscattering. Therefore, mangroves have showed to be an excellent geologic indicator to detect and to quantify short and long-term morphological coastal changes. To conclude, remote sensing data integration, GIS and auxiliary fieldwork data present a fundamental role to the integrated coastal zone management, environmental risk assessment, local characterization of the study sites, base maps upgrading and information dissemination for public consultation, which are all significant factors in this decision-making process.
Acesso aberto (Open Access)
Braquiópodes devonianos da Bacia do Amazonas: novos dados taxonômicos, paleobiográficos e relações com as mudanças ambientais
(Universidade Federal do Pará, 2024-10-01) CORRÊA, Luiz Felipe Aquino; RAMOS, Maria Inês Feijó; http://lattes.cnpq.br/4546620118003936; https://orcid.org/0000-0003-0276-0575
The Devonian marked a significant phase in the evolutionary history of the Brachiopoda. During this period, the Phylum achieved its peak diversity (Emsian) and suffered one of its most significant declines (Frasnian–Famennian), ranking second only to the mass extinction event Permo-Triassic. Among the Brazilian sedimentary basins, the Amazonas Basin has the greater diversity of Devonian brachiopod genera, distributed among the following formations: Manacapuru (Lochkovian), Maecuru (early Eifelian), Ererê (Late Eifelian), and Barreirinha (early Frasnian). Studies of Devonian brachiopods from the Amazonas Basin began in the late 19th century with identifications of material collected during the Morgan Expeditions (1870–1871) and the Imperial Geological Commission of Brazil (1876). These expeditions focused primarily on the Maecuru and Ererê formations. The brachiopod fauna of the Manacapuru Formation (Lochkovian) was unknown until 2015, when during paleontological salvage at the Belo Monte hydroelectric plant in Vitória do Xingu, Pará, Brazil, a significant number of Rhynchonelliformes and Linguliformes samples were recovered. This work aims to carry out the taxonomic identification of brachiopods from the Manacapuru Formation, in addition to analyzing and discussing the possible factors that influenced the diversity of brachiopod genera among the sedimentary units of the Amazonas Basin (Mancapuru, Maecuru, Ererê, and Barreirinha formations). The taxonomic study of brachiopods from the upper part of the Manacapuru Formation (Lochkovian) has allowed, to date, the identification of two genera, Orbiculoidea d'Órbigny, 1847 and Schellwienella Thomas, 1910. Among the materials, Orbiculoidea has the greater diversity, totaling five species: Orbiculoidea baini Sharpe, 1856, Orbiculoidea bodenbenderi Clarke, 1913 and Orbiculoidea excentrica Lange, 1943 in addition to two new species: Orbiculoidea xinguensis Corrêa & Ramos, 2021 and Orbiculoidea katzeri Corrêa & Ramos, 2021. The species O. baini, O. bodenbenderi, and O. excentrica were recorded for the first time in the Manacapuru Formation and Northern Brazil, and they are also the oldest records (Lochkovian) from South America. The presence of Orbiculoidea in the region can be explained by two reasons: the proximity of the Amazonas Basin, located in the northwest of Gondwana during the Lower Devonian, with the paleocontinent Laurussia (where most occurrences of Orbiculoidea are recorded during the Silurian), favored the specific exchange between these two geographic regions; and the global rise in sea level during this period, which flooded much of northwest Gondwana, resulting in the presence of shallow seas in the Amazonas Basin, represented by marine sediments in the upper part of the Manacapuru Formation. These conditions favored the colonization of inarticulate brachiopods during the Early Devonian in northern Brazil. Furthermore, the new species Schellwienella amazonensis Corrêa et al. 2024, of the Pulsiidae Family Cooper and Grant, 1974, is proposed, this being the first record of the genus in the Amazonas Basin. Schellwienella amazonensis n. sp. and Schellwienella marcidula Amsden, 1958 from the Bois d’Arc Formation (Lochkovian), USA, are the oldest records of the genus. In the Devonian, Schellwienella occurred in all stages (Lochkovian, Pragian, Emsian, Eifelian, Givetian, Frasnian, and Famennian), mainly in the marine siliciclastic environments of Gondwana, transiting between temperate and polar latitudes. In the Carboniferous, its stratigraphic distribution was restricted to the Tournaisian-Visean interval, with a preference for warm water environments and carbonate platforms typical of low latitudes. We identified three distinct stages when analyzing the variation in Devonian brachiopod diversity in the Amazonas Basin. In stage 1, the peak of brachiopod diversity occurred in the early Eifelian (Maecuru Formation), when the Amazonas Basin was between subtropical latitudes 30°S and 60°S, under shallow and cold marine conditions, justified by the absence of carbonates, evaporites, and reefs in the region. In stage 2, the first decline in diversity occurred, recorded in the Ererê Formation (late Eifelian), attributed to a warmer climate and deeper waters than in the Maecuru Formation. Stage 3 occurred during the Frasnian when there was a second decline in brachiopod diversity in the Amazonas Basin (Barreirinha Formation). A major global transgression happened at the end of the Devonian. During this period, the Amazonas Basin experienced the deepest marine conditions in its history. Brachiopods of the Barreirinha Formation occur in black shale layers (offshore), attributed to a dysoxic to the anoxic environment of high stress, which explains the low diversity of brachiopods in this unit.
Acesso aberto (Open Access)
O Cambriano no Sudeste do Cráton Amazônico: paleoambiente, proveniência e implicações evolutivas para o Gondwana Oeste
(Universidade Federal do Pará, 2018-06-15) SANTOS, Hudson Pereira; NOGUEIRA, Afonso César Rodrigues; http://lattes.cnpq.br/8867836268820998
Transgressive events recorded in many cratonic regions marked the Cambrian period, hypothetically related to the glacioeustasy and/or the progressive opening of the Iapetus ocean (~600 Ma). Such events influenced the paleoceanography of this period, including the progressive biota evolution – the ‘Cambrian Revolution’. Although the Gondwana Supercontinent margins, entirely amalgamated in the Lower Cambrian (540 Ma), were flooded, the inner part of this supercontinent was emergent, probably triggered by postcollisional epirogenic uplifts. Epeiric seas covered subsiding areas with projections towards the interior of the Western Gondwana, developing shallow platforms that covered ancient colisional suture zones. In the southeastern Amazon Craton, the recurrence of platform environments dates from Upper Cryogenian (~635 Ma) until the Cambrian with the installation of glacial deposits, overlaid by carbonatic and siliciclastic successions. Despite the previous insertion in the context of a foreland type basin related to the evolution of North Paraguai Belt (650-640 Ma), these deposits have been included in an inverted intracratonic basin in the Ordovician. The bottommost deposits of the Cambrian sequences, here presented, are comprised dominantly by siliciclastic rocks. These consist in the Upper and Lower members of the Raizama Formation and the base of Lower Member of the Sepotuba Formation, Alto Paraguai Group, exposed in the central and northeast portions of the inverted intracratonic basin, Mato Grosso state. Two depositional sequences (DS1 and DS2) characterize the Cambrian successions of the base of Alto Paraguai Group. The DS1 presents as a sequence boundary (SB1) an erosional hiatus previously interpreted in the southwestern basin. This stratigraphic surface becomes a correlative conformity towards the central and northern portions, where this covers the Araras carbonates and Cryogenian glacial deposits from Puga diamictites. The SB1 represents an erosional or non-depositional period of approximately 80 Ma developed over the carbonates of the Lower Ediacaran Araras Group, related to the epeirogenic uplifts of the basin. A second thermal subsidence phase would have led to the installation of a siliciclastic platform during the Cambrian, characterized by DS1 composed by two facies associations denominated FA1 and FA2. FA1 consists of subarkoses, quartz-wackes and pelites dominated by wave and storm processes, inserted in the offshoretransition, lower-middle shoreface and upper shoreface zones. The presence of infaunal vertical trace fossils belonging to the Skolithos Ichnofacies (Skolithos linearis; Diplocraterion parallelum; and Arenicolites isp.) at the base of the lower-middle shoreface deposits indicated a Lower Cambrian age, or younger, to the Raizama Formation, previously considered as Ediacaran. The FA2 comprehends subarkoses, quartzarenites, sublitarenites, quartz-wackes and sandstone/pelite rhythmites interpreted as complex tidal plain deposits, unconformably overlaid (SB2) by braided fluvial channel deposits of (FA3), which belong to the DS2. The DS1 would have been deposited during lowstand to transgressive system tract, organized in progradational parasequences. This stacking pattern is not compatible with the traditional stratigraphy sequence for TST, which is attributed to a slow subsidence rate concomitantly to a high sediment supply indicated by the Skolithos Ichnofacies. Subsequently, a less expressive drop in the sea level promoted a progradation of distal braided deposits (FA3) over the DS1, related to the lowstand system tract (LST) characterized by an abrupt change of the tidal heterolitic deposits to medium and coarse-grained quartzarenites from fluvial deposits. Paleoflow data oriented preferentially to NE and SE obtained in coastal beds from FA2 and FA3 allied to the Paleo- to Mesoproterozoic U-Pb detrital zircon ages have indicated provenance exclusively from SW and NW sources from Amazon Craton. Besides that, the detrital quartz grains analysis of sandstones of the bottommost Cambrian deposits indicate mainly igneous and metamorphic sources. Previous works indicated that the fluvial deposits of DS2 were succeeded by a transgressive system tract, marking this as the last transgressive event that influenced the Cambrian deposits of the intracratonic basin. Slowly, the ocean connection was interrupted as a consequence of the closing of Iapetus Ocean (~500 Ma) as a result of basin uplift. In this way, Cambrian epeiric seas were confined and consequently started the lacustrine phase of the basin in the Ordoviacian, represented by the Diamatino Formation deposits. Posteriorly, the intracratonic basin of the southeast Amazon Craton would have been inverted by the transtensional tectonics which propitiated the implantation of post-Cambrian intracontinental basins of the Western Gondwana.
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O Camp nas bacias dos Solimões, Amazonas, Parnaíba e Parecis, Norte do Brasil: implicações geotectônicas e deposicionais para o jurássico do Gondwana Ocidental.
(Universidade Federal do Pará, 2024-08-23) REZENDE, Gabriel Leal; NOGUEIRA, Afonso César Rodrigues; http://lattes.cnpq.br/8867836268820998
Geological studies in conjunction with applications of geophysical techniques are being widely used to highlight and characterize CAMP gravimetric anomalies throughout Northern Brazil, including the Solimões, Parecis, Amazonas and Parnaíba basins. Interpretations of a residual gravimetric anomaly from these basins were used to expand the understanding of the distribution of CAMP throughout the subsurface. This study was carried out through qualitative and quantitative interpretations of gravimetric data, supported by surface geological information, mainly stratigraphic data based on outcrops. From direct gravimetric modeling, based on available crustal gravitational structure models to separate a residual gravity signal from observed gravity data, realistically detailed geological and tectonic features were interpreted, providing useful information for a geophysical interpretation of geological sources. With the residual gravity anomaly, a map of the elastic thickness (Te) of the basins was obtained, using a new procedure, presumably allowing some gaps presented in the current literature on the CAMP to be filled. For each Te value, the residual gravimetric signal was calculated, considering the surfaces described by topography and Moho for a regional model with standard density and discretized into prisms. The cross-correlation between the observed gravity signal and calculated gravity signal made it possible to obtain a map of the elastic thickness of the studied areas. The highest correlation value is directly related to the best value of elastic thickness and Moho depth associated with crustal deformation. Our study used a combination of these techniques to presumably define the possible extent of Jurassic magmatism, the basin rheology of igneous body intrusion and history of thermal subsidence that largely controlled depositional control during and after the CAMP. The presence of low gravity values is closely related to the less dense lithological units of the upper crust, while the high gravity values are related to high-density rocks correlated to the continental tholeiitic flood basalts of the CAMP. The use of residual gravity anomaly based on crustal modeling combined with previous geological data was effective in identifying the CAMP record in these Amazonian sedimentary basins. Furthermore, some gravimetric signatures correlate well with the main structural discontinuities, particularly with the Monte Alegre Dome and Xambioá, Serra Formosa and Vilhena arches, respectively, in the Amazon, Parnaíba and Parecis basins. This interpretation provides a reasonable explanation for understanding structural lineaments without exclusively tectonic connotations, assuming a new interpretation for the gravitational field related to intracrustal density contrast or residual gravity field for these basins. Eastern Gondwana was gradually uplifted by subvolcanic bodies of the Penatecaua magmatism in the Amazon and Solimões basins. In contrast, extrusive volcanism characterizes Mosquito magmatism in the Parnaíba basin interspersed with intertrap sediments. Information obtained from the elastic thickness map, Moho depth and residual gravity signal indicate a thinner crust in the Parnaíba basin favoring the magmatic eruption induced by a hot spot installed on the western edge of the basin. On the other hand, in basins with denser and thicker crust, magma accumulates mainly as sills, providing greater resistance to rupture due to the swelling of the CAMP. The Parnaíba Basin experienced three magmatic pulses at intervals of approximately 1 Myr, alternating with the development of aeolian-fluvial-lacustrine systems (intertrap sediments) during non-magmatic periods, indicating short intervals of magmatic resump-tion and cooling in the CAMP, contrasting with the longer and continuous magmatism in the Amazon and Solimões basins, which lack intertrap deposits. These results are important for a new disposition of the tectonomagmatic, structural and stratigraphic history for these basins, since from a new context or geological evolution for the area it will allow a better understanding of the studied basins in lava-sediment interaction, preserved from the Jurassic and related to the CAMP events, which preceded the main continental rupture in northwestern Pangea.
Acesso aberto (Open Access)
A capa carbonática marinoana do Sul do Cráton Amazônico: multiproxies aplicados na reconstituição paleoceanográfica e geobiológica do início do Ediacarano.
(Universidade Federal do Pará, 2024-08-30) SANTOS, Renan Fernandes dos; SANSJOFRE, Pierre; NOGUEIRA, Afonso César Rodrigues; http://lattes.cnpq.br/8867836268820998
The post-Marinoan glaciation (~650-635 Ma) was the most severe event from the late Cryogenian period of the planet. The snowball Earth conditions induced a climate anomaly, triggering major changes in the paleoenvironmental and ocean chemistry recorded in the carbonate cap sequences. The dramatic effects on the global sea level were caused by glacial-isostatic adjustment (GIA) and ice gravity on the coastal zones associated with the ocean thermal expansion under greenhouse conditions. The fast input of meltwaters contributed to a stable density ocean stratification formed by hypersaline deep waters and meltwater surface layers. The ocean destratification occurred in a timescale ranging from tens of thousands to thousands of years. The Puga cap carbonate (~635 Ma), the basal deposits of the Araras-Alto Paraguai basin from the southern Amazon Craton, is revisited in the classical sections from the Tangará da Serra and Mirassol d'Oeste, Mato Grosso State. This succession is one of the best records for evaluating the supersaturation events under GIA and transgression conditions that controlled the accommodation space in the southern Amazon Craton. Sedimentological and stratigraphic data were integrated with new paleoceanographic, and paleo-redox data combined with diagenetic, crystallographic, geochemical (primarily rare earth elements and trace metals), and isotopic (whole rock 87Sr/86Sr, εNd(t), δ 13C, δ 18 O, Sm/Nd) results providing further insights to understand the post-Marinoan conditions. The Puga cap carbonate sequence spans approximately 90 meters, with the first 10 meters composed of glaciomarine deposits, diamictites, and dropstones from the Puga Formation. The basal contact with diamictites is plastically deformed, indicating rapid carbonate precipitation. The cap dolostone consists of stratiform doloboundstones with gypsum pseudomorphs and domal doloboundstones with tubestone, which were deposited in a shallow platform with intense microbial activity. Peloidal dolomudstone/dolopackstone with laminations parallel to bedding planes and peloidal dolograinstones/dolomudstone with quasi-planar laminations and low-angle truncation were formed in a wave-influenced shallow platform. The cap limestone conformably overlies the cap dolostone deposits, marked by dolomitic marlstone with calcite crystal fans (aragonite pseudomorphs) interbedded with mega-rippled limestone. The facies association of the cap limestone indicates moderately deep-water conditions dominated by waves and storms transitioning to a deep platform supersaturated with CaCO3. The main diagenetic process is dolomitization during syn-depositional and shallow burial stages. Rare earth element + yttrium patterns have been analyzed in these deposits. Low Y/Ho ratios (<36) in the cap dolostone suggest a mixture of meltwater and seawater, while the base records superchondritic Y/Ho values up to 70 and high Eu/Eu* values up to 3, indicating upwelling of hypersaline seawater with hydrothermal fluid interaction, suggesting dolomite precipitation during ocean destratification. The radiogenic isotopic compositions of Nd, combined with other proxies such as δ 13C and 87Sr/86Sr, indicate the influence of continental and marine contributions. The Nd isotopic system, less susceptible to diagenetic exchanges, revealed distinct signatures of water masses and enhanced weathering of the Amazon Craton during deglaciation. This process is indicated by geochemical trends (e.g., Y/Ho) and 87Sr/86Sr, εNd(t), δ 13C values. 87Sr/86Sr data in the cap dolostone range from 0.7264 to 0.7084, higher than pre- and postglacial seawater values. More radiogenic 87Sr/86Sr values associated with less radiogenic εNd(t) values, similar to those found in diamictites, reinforce coastal weathering contribution to meltwaters. This multiproxies approach is a reconciliation with the previous rapid cap carbonate precipitation model following the short-term timescale for ocean destratification. Redox-sensitive trace metal data, U, Mo, V, Ni, Cu, P, and δ13C isotopes, indicated paleo-redox states and paleoproductivity during the post-glacial transgression. The cap dolostone precipitated under oxygenated conditions with extensive microbial community contributions, transitioning to predominantly dysoxic conditions with wave action in the last deposition phase. The abrupt sea-level rise altered the biogeochemical cycle, indicating a direct relationship between oxygen production and rapid microbial community colonization. The rapid sea-level rise and continental weathering reduced seawater Mg/Ca ratios with substantial Ca2+ input, also demonstrated by εNd(t) values, causing the change of dolomitic platform to CaCO3 -supersaturated seas in the Amazon Craton margin. Additionally, low siliciclastic content in the cap dolostone is consistent with the siliciclastic starvation model, and the abrupt increase caused the decline of microbial communities coincident with the predominance of dysoxic conditions and longterm transgression. During specific Cryogenian-Ediacaran deglaciation scenarios, anomalous sedimentary and geochemical processes generated one of the most complex paleoenvironmental disturbances in the biogeochemical cycle. They strongly influenced the rapid primary productivity, directly impacting microbial life. The analysis of Precambrian scenarios in the Amazon Craton unraveling the extreme climates sheds critical light on extremophile life proliferation and has strong implications for understanding other planetary surfaces.
Acesso aberto (Open Access)
O cenozoico superior do centro-oeste da Bacia do Amazonas: paleobotânica do embasamento cretáceo e evolução do Rio Amazonas
(Universidade Federal do Pará, 2018-11-08) BEZERRA, Isaac Salém Alves Azevedo; NOGUEIRA, Afonso César Rodrigues; http://lattes.cnpq.br/8867836268820998
At the end of the Neogene and during the Quaternary, the development of the Amazon River caused significant paleoenvironmental and geomorphological changes that generated current ladscape at Amazonia. Previous models elaborated on a continental scale were based on data obtained from a drill core carried out on the Atlantic continental shelf, distant 200 km of the Amazon River mouth, suggesting the establishment of this drainage with Andean provenance from the Middle to Upper Miocene. In contrast, studies based on outcrops in the western and central portions of the Amazon have indicated younger ages for this ecosystem, from Pliocene to Quaternary. The sedimentological-stratigraphic study of the fluvial terraces of the Amazon River, exposed in the center-west portion of the Amazon Basin, assisted by luminescence geochronology, allowed to sequence the sedimentation events and discuss the paleoenvironmental and paleogeographic since Late Neogene. The studied Neogene- Quaternary deposits overlies Cretaceous rocks whose sedimentological and paleobotanical study revealed the preservation of impressions and counter-impressions of leaves and other macro-plant remains in pelites interpreted as flood plain and abandoned channel deposits of meandering rivers. The first record of angiosperms in this unit with possible affinities to the families Moraceae, Fagaceae, Malvaceae, Sapindaceae and Anarcadiaceae with appearance from Late Cretaceous, and the family Euphorbiaceae with record starting in the Mid- Cretaceous confirm the Cretaceous age for these rocks. The terraces of the Amazon River informally subdivided into lower and upper units are composed of sand, gravel and clay, organized in finning upward cycles representative of channel filling and overbank deposits. The lower unit was interpreted as a record of the proto-Amazonas, with migration to the east and deposition around 2 Ma. During this stage, the alluvial plain was restricted, preferentially following weakness zones coincident with fractures in the Paleozoic and Cretaceous basement. The climatic oscillations during the Quaternary and the increase of the volume of orographic rains in the headwaters region of the fluvial systems, in the eastern flank of the Andean ridge modified the hydrological regime, amplifying the escarpment erosion. The gradual expansion of the alluvial plain formed a large area of 120 km around 1 Ma to 140 ka, recorded by the upper unit deposits. At this stage, the eastern portion of the Amazon Basin topographically higher restricted the Pleistocene sedimentation in minimum accommodation space. The lower unit deposits are correlate in part to the Miocene-Pliocene deposits of the Amazon Basin, while the upper units are correlate with the Pleistocene deposits of the Solimões and Amazon basins. The dynamics of the construction of the Amazon River valley during the end of the Neogene and Quaternary was influenced by neotectonics (106 yr) and climatic oscillations (104-105 yr). The landscape of the central-eastern portion of the Amazon dominated no Pleistoceno by terra firme in elevated areas was governed by the dynamics of expansion and contraction of the alluvial plain. At the end of the Quaternary, the várzea formed by floodplains within the alluvial plain, which used to occupy a wide area, became increasingly restricted by the continuous processes of fluvial incision during the glacial maximum (18 to 22 ka). The continuous lateral migration of the meandering channel to the north led to the confinement of the channel by the fluvial scarps developed in the Cretaceous basement, which culminated in the current landscape in the Center-East of the Amazon. Testing the reliability and accuracy of some Pleistocene and older OSL ages for Amazon River deposits revealed that are much more minimum ages than buried ages for pre- Quaternary deposits.
Acesso aberto (Open Access)
Cristaloquímica de esmectitas dioctaédricas em bentonitas brasileiras
(Universidade Federal do Pará, 2025-07-01) VEGA PORRAS, David Enrique; PAZ, Simone Patrícia Aranha da; http://lattes.cnpq.br/5376678084716817; https://orcid.org/0000-0002-5880-7638
Bentonites are mineral inputs of great industrial interest due to the physicochemical properties of clay minerals from the smectite group. These properties, resulting from the complex crystal chemistry and small particle size of smectites, include various layer charge, swelling capacity, and cation exchange capacity. In Brazil, the main bentonite deposits are located in the municipality of Boa Vista, Paraíba, which accounts for >70% of the country’s production. However, the progressive depletion of these varieties has motivated the search for new deposits. Among them, the Formosa deposit, in the state of Maranhão, stands out. Although both the Boa Vista and, to a lesser extent, the Formosa bentonites have been extensively studied in their <2 μm or coarser fractions, the crystal chemistry of their smectites has not yet been fully elucidated. This is due not only to the typical chemical and structural complexity of smectites, but also to the difficulty of obtaining pure smectite phases and the interference of accessory minerals. In this context, this thesis presents a detailed study of the crystal chemistry of smectite from the Formosa deposit, comparing it with three commercial varieties from Boa Vista: Bofe, Chocolate, and Verde Lodo. The <2 μm, 0.1-2 μm, and <0.1 μm fractions were analyzed, with the latter being the main focus of the study. The analyses included XRD (Rietveld method), FTIR, TEM-EDS, SEM, XRF, AAS, TG, and Mössbauer spectroscopy. These smectites, previously described as montmorillonites, also exhibit significant tetrahedral layer charge. In fact, the four samples show a tetrahedral charge of approximately 0.15 per half unit cell, sufficient to induce swelling after the Hofmann-Klemen treatment. The octahedral symmetry of all four samples was trans-vacant, influenced by both the Fe content and the tetrahedral charge. The structural and chemical similarities between the Formosa and Boa Vista smectites, along with similar smectite content in the <2 μm and <0.1 μm fractions – as quantified by the Rietveld method – demonstrated that the Formosa deposit is a potential alternative to the Boa Vista bentonites.
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Detecção de mudança e sedimentação no estuário do Rio Coreaú
(Universidade Federal do Pará, 2014-09-02) RODRIGUES, Suzan Waleska Pequeno; SOUZA FILHO, Pedro Walfir Martins e; http://lattes.cnpq.br/3282736820907252
The use of new techniques to study the evolution and filling incised valleys has provided, over the years, important results was to understand how the coastal evolution of the Brazilian coastal zone. In this context, this thesis aimed to study the evolution of the estuary Coreaú River, located in the state of Ceará, in different time scales, is "Possible" (months, years), "Engineering" (years, decades) and "Geology" (hundreds, centuries, millennio), proposed by Cowell et al (2003), with the goal to assess whether changes /alterations over the years were significant or not in the estuary. As a result, we obtained the first goal, using remote sensing techniques from image sensor TM, ETM+ and OLI of Landsat 5, 7 and 8 and sensor LISS-3 of satellite ResourceSat-1 from 1985 to 2013, a change minimal in relation to morphological changes along the estuary in the last 28 years (between Possible scales and Engineering), there was an increase in this period of 0.236 km2 (3%) of the area, not bringing significant changes to the estuary. Regarding sedimentation rate, corresponding to the second goal, from the collection of nine witnesses, up to 1m deep and using radionuclídeo 210 Pb along the estuary, we obtained a rate that ranged from 0,33 cm/year 1 cm/year (between scales Geological and Engineering) near the mouth of the estuary, and with a quick sedimentation perceived on the east bank of the river, where there are younger sediments toward the west margin. Regarding the fulfillment, third and final goal from the sampling of testimonials to 18 m depth, using the sampler Rammkernsonden (RKS), profiles and stratigraphic sections that helped understand filling the valley section of the estuary of the Coreaú river were generated and that it is a fluvialmarine estuary, filling the valleys formed in group Barriers in the last 10.000 years before present. These analyzes and results serve as a basis for comparison with other estuaries, either fluvial, fluvio-marine or marine, to better understand what the possible events that dominated sedimentation along the coast of Brazil at diferent scales.
Acesso aberto (Open Access)
Dinâmica de nutrientes e da matéria orgânica no manguezal do Igarapé Nunca Mais - Ilha de São Luís (MA)
(Universidade Federal do Pará, 2002-11-22) MELO, Odilon Teixeira de; LIMA, Waterloo Napoleão de; http://lattes.cnpq.br/1229104235556506
It is well known that the State of Maranhão has more than fourty percent of the Brazilian mangroves covering an área with almost 4800km2 and along of 640km of coastline. These mangrove swamps border a number of tidal channels, bays, gulfs, and others estuarine systems, where the macro-tidal system gives a singular condition to this environment, that it is different from the others Brazilian áreas. The exportation of macro-particles from the mangroves to the coastal waters is well known. However, there is a discussion if the mangroves import or export micro-particles and dissolved nutrients to the coastal areas. Few studies have been developed in this subject due to the methodological complexities of the flow calculations. The choice of the pilot-area for this study is the igarapé Nunca Mais, a tidal channel surrounded by an area of 1.22km2 of mangrove ecosystem, situated in the Northeastern portion of the São Luís Island. This choice is due bay the fact that in this area occurs exchanges with the coastal waters from the Maranhão Gulf take place. This tidal channel is the main transport pathway between the mangrove and the coastal waters. During the spring tides this mangrove is completly flooded. The main aim of this study was to evaluate the role of a mangrove region — Maranhão Gulf — in a macro-tidal area in exchanging of materials with the coastal waters. The characterization and quantification of the dissolved inorganic nutrients and the organic matter were the main focuses of this study. For this purpose were utilized flows calculations from "Eulerian" method. During the period of 13 months (from April 2000 to April 2001), in the neap and spring fluxes of the dissolved inorganic nutrients (ammonium, nitrite, nitrate, phosphate, and silicate) and those of the organic matter (organic carbon, organic nitrogen, and organic phosphorus) were determined along 52 tidal cycles. For the characterization of organic matter were used elemental ratio C/N, isotopes 13C and 15N ratio, and by the identification of dissolved humic substances as tracers for organic matter sources. The differences on day clear and orvernight show average values from 0960 for the pH and salinity, positive values of 5, 6, 8 and 11%, respectively, for nitrate, phosphate, ammonium, and silicate, and negative values for the oxygen (-10%), and for the dissolved and particulate organic matter (-1% to -6%). The dissolved nutrients and organic matter varies such as tidal ranges showing maximum values in the low tile, indicating flow from intersticial water of the mangrove for the tidal channel. Particulate organic matter values show variations relationships with current velocity showing resuspension and sediment transport. This fact confirms that the biological processes, such as nutrient consumption and organic matter deposition, in the tidal channel, and the tidal dynamics were relevants in the lief variations. The results obtained in this study show a seasonal variation with minium values in the dry season, except for the silicate, and maximum values in the rainy season, showing the raro precipitation influence in the transport from mangrove for the coastal waters. In addition, in the dry period, occurs maximum consumption of nutrient by phytoplancton, as well as, observed on primary production. It was evidencied also lower values in the concentration of particulate organic matter during this dry season due the lower fluxes values from the mangrove. The net exportation of inorganic nutrients and the organic matter in the mangroves of the São Luís Island (Maranhão State, Brazil), in the tidal channel Igarapé Nunca Mais, is evidencied in this study by interpretation of the flows calculations and the values from C/N. rations, elemental and isotopic. The isotopes of C and N used here as tracers lead to the identification of the primary sources of the organic matter in the tidal channel, i.e., the originated from mangroves, the coastal waters, and the resulting from allochthonous production. During the rainy period there are dominance of the organic matter (dissolved and particulate) transported from the mangrove, while in the dry period the marine and autochthonous sources are more considerables. The photosynthesis of the phytoplancton, in the tidal channel, justifies the autochthonous production. The net exportation of the dissolved organic matter for the coastal waters is slightly superior to the particulate organic matter (DOM, 14mM-2.day-1; POM, 20mM.m.-2.day-1). Perhaps this difference is due a fast sedimentation in the intermediary zune of the tidal channel that have the biggest profundity; this fact leads a minor quantity of particulates exported for coastal waters. It infers that this organic matter is constititued, dominantly, by humic substances because they are more refractory to the bacterial activity and consequently they can be transported by tidal currents for the adjacent coastal waters. Of course, the tidal amplitude ranges and pluviometric precipitation are relevant factors in these exportation processes. By this exposition, this study confirms the important role of mangrove for the fertilization of the coastal waters of Maranhão Gulf.
Acesso aberto (Open Access)
Estudo isotópico do depósito aurífero Volta Grande, domínio Bacajá, sudeste do cráton amazônico
(Universidade Federal do Pará, 2024-03-22) PIMENTEL, Helmut Sousa; VASQUEZ, Marcelo Lacerda; http://lattes.cnpq.br/4703483544858128; https://orcid.org/0000-0003-2729-9404; MACAMBIRA, Moacir José Buenano; http://lattes.cnpq.br/8489178778254136
The area of the Volta Grande of the Xingu River is crucial for the geological understanding of the Siderian and Riacian periods in the Bacajá Domain, Maroni-Itacaiúnas Province, Amazonian Craton, which hosts significant gold mineralizations. The Bacajá Domain is composed of tectonic associations with NW-SE orientation that contain reworked Archean and Siderian fragments, mainly during the Riacian, with significant crustal growth during the Transamazonian Cycle (2.26 to 2.06 Ga). The objective of this thesis is to investigate the tectonic environment and discuss the crustal evolution in accretionary and continental collision settings. The study relied on field surveys, geological-geophysical mapping, petrography, geochemistry, geochronology, and isotopic geochemistry, employing U-Pb and Lu-Hf methods in zircon via SHRIMP and LA-ICP-MS, U-Pb in titanite via LA-ICP-MS and Sm-Nd on whole rock via TIMS. The geological-geophysical integration reveals the NW-SE trending Bacajá Shear Zone with well-defined edges and foliated terrains of high magnetic susceptibilities, plastically deforming the lithotypes within. Petrographic analyses identified metavolcanosedimentary rocks of the Três Palmeiras sequence, the Intrusive Oca Suite (composed of granodiorite, quartz monzodiorite, quartz monzonite, monzodiorite, and diorite), as well as granodiorite, monzogranite, and sienogranite of the Bacajaí Complex and the Arapari Intrusive Suite. The zoned hydrothermal orogenic gold mineralization occurs at the contact between the Três Palmeiras Group and the Intrusive Oca Suite. The geochemistry of mafic volcanic rocks from the lower Itatá Formation of the Três Palmeiras Group indicates evolved tholeiitic character in a mid-oceanic ridge and juvenile island arc setting, while the volcanic rocks of the upper Bacajá Formation are related to calc-alkaline volcanic arcs in active compressional continental margins. Three groups of granitoids representing different phases of magmatic and tectonic evolution in the Bacajá Domain during the Riacian were distinguished, with ages spanning around 110 M.y.: granitoids from the Intrusive Oca Suite at 2.20-2.17 Ga, syenogranite with biotite from the Bacajaí Complex at 2.17 Ga, and biotite-bearing monzogranite from the Arapari Intrusive Suite at 2.09 Ga. The Intrusive Oca Suite comprises intermediate to acid, calcic to alkali-calcic, ultramafic to medium-mafic, metaluminous to peraluminous rocks formed in a cordilleran granitic setting related to volcanic arcs. The REE of Intrusive Oca Suite granitoids exhibit strong magmatic fractionation, reflected in high (La/Lu)N ratios, enrichment in Rb, Th, and K, and depletion in Ba, Nb, P, and Ti, sourced from mafic rocks with varying K contents. The Bacajaí Complex consists of calcic to alkali-calcic, medium-mafic, and peraluminous quartz monzonite, granite, and granodiorite, sourced from x mafic rocks with low-K and high-K components and some input from metasediments. The rocks of the Arapari Intrusive Suite are medium-mafic, calcium-alkali to alkali-calcic, and metaluminous, sourced from mafic rocks with high-K content. The syn- to late-collisional granitoids (Bacajaí Complex and Arapari Intrusive Suite) are enriched in LILE and LREE, exhibiting negative anomalies in Ni, P, and Ti, and depletion in HFSE, typical of orogenic granites in volcanic arcs. In terms of isotopes, the Três Palmeiras sequence has Nd-TDM values ranging from 2.35 to 2.58 Ga, with εNd(t) varying from -0.41 to +3.20. The Intrusive Oca Suite includes rocks with Nd-TDM between 2.24 and 3.06 Ga and εNd(t) ranging from -5.99 to +2.44. U-Pb zircon crystallization ages for this suite are 2203 ± 23 Ma, with Hf-TDM C values between 2.4 and 2.8 Ga and εHf(2.20Ga) ranging from -0.45 to +5.24 for the Ouro Verde body; 2173 ± 7 Ma with Hf-TDM C ranging between 2.3 and 2.6 Ga, and ɛHf(2.17Ga) between +2.04 and +7.65, added to a U-Pb age of 2171 ± 17 Ma in titanite, for the Central body, and 2171 ± 13 Ma, with Hf-TDM C values between 2.4 and 3.4 Ga and εHf(2.17Ga) ranging from -10.32 to +4.34 for the Buma body, indicating distinct crustal generations between the Mesoarchean and Siderian/Riacian. The Bacajaí Complex has a crystallization age of 2165 ± 10 Ma, Hf-TDM C values between 2.5 and 2.8 Ga, and εHf(2.16Ga) ranging from -0.35 to +3.04, with mantelic sources from the Neoarchean. The Arapari Intrusive Suite has a crystallization age of 2094 ± 13 Ma, Nd-TDM at 2.38 Ga, εNd(2.09Ga) at -1.15, Hf-TDM C values between 2.6 and 2.8 Ga, and εHf(2.09Ga) varying from -2.77 to +1.59, indicating a mixture of mantle and crustal sources generated from the Neoarchean to the Siderian. The geological evolution of the study region is marked by various events. In the Siderian, volcanic-sedimentary sequences with tholeiitic basalts and island arc andesites were followed by the emplacement of diorites to granites around 2.20 to 2.09 Ga and collision, originating continental arcs. The most advanced and late stage of the Transamazonian orogeny in the Volta Grande region is represented by the emplacement of peraluminous granitoids from the Arapari Intrusive Suite, closing the complex geological bevolution of the region. The analyses in this study highlight the proposed similarity based on petrographic, geochronological, and isotopic similarities between the Volta Grande region and the Lourenço and Carecuru domains, located in the state of Amapá, in the northeastern portion of the Maroni-Itacaiúnas Province.
Acesso aberto (Open Access)
Evolução crustal do setor Sul da Província Borborema: Domínio Macururé, sistema Orogênico Sergipano, nordeste do Brasil
(Universidade Federal do Pará, 2023-09-29) PEREIRA, Fábio dos Santos; ROSA, Maria de Lourdes da Silva; http://lattes.cnpq.br/9814085660417748; https://orcid.org/0000-0002-5099-829X; LAFON, Jean Michel; http://lattes.cnpq.br/4507815620234645; https://orcid.org/0000-0003-0854-3053
The Sergipano Orogenic System (SOS), located in the southern Borborema Province, is part of a large Brasiliano/Pan-African orogen structured during the Gondwana supercontinent assembly, which spread out to central Africa up to Cameroon. Six domains compose the SOS, namely Estancia, Vaza Barris, Macurure, Maranco, Poco Redondo, and Caninde. The Macurure Domain stretches 350 km from the Sergipe coast to Macurure City, Bahia state. It consists of a succession of quartzites overlaying by a thick package of phyllites, schists, metarhytmites, and metagraywacke, with intercalations of amphibolite and calc-silicate rocks. The rocks were metamorphosed under greenschist-amphibolite facies and intruded by numerous late Cryogenian-Ediacaran granites and mafic plutons. In this work, new geochemical, U-Pb geochronological (zircon and titanite), and isotopic (whole-rock Rb-Sr, Sm-Nd, and Pb-Pb and in situ zircon Lu-Hf) results from the main units composing the Macurure Domain allowed to refine the local stratigraphy and improve the comprehension about sources and processes involved in the generation of the magmatic rocks. U-Pb isotope analyses on detrital zircon from quartzites yielded two main peaks in the ranges of 1980-1950 Ma and 1000-910 Ma, consistent with the Rhyacian Orogeny (2.2-1.9 Ga) e Cariris Velhos event (1.0-0.9 Ga). Paleoproterozoic dates overlap those observed in the Provincia Borborema basement, represented in the study area by the Jirau do Ponciano Dome and Arapiraca Complex. Negative to slightly positive εHf(t) values between -15.6 and +0.5 and Hf-TDMC model ages from 2.5 to 3.5 Ga characterize this population, suggesting extensive reworking of the Archean crust during the Rhyacian-Orosirian periods. Early Neoproteozoic zircon grains display sub- to superchondritic Hf isotope composition (-12.3 to +7.7) and Hf-TDMC model ages from 2.5 to 1.3 Ga, implying the addition of juvenile material and reworking of preexistent crusts during the Cariris Velhos event. Less abundant Mesoproterozoic (1120-1040 Ma) and late Neoproterozoic (880-740 Ma) zircon populations suggest that the sediment deposition took place before the Brasiliano Orogeny. The groups of magmatic rocks were individualized based on field, petrographic, and geochemical features. (i) The oldest plutonic rocks in the area are diorites and gabbros, with minor cumulate hornblendites. They generally show evidence of solid-state deformation and well-developed tectonic foliation, defined by the plagioclase, hornblende, and biotite orientations. These features point to emplacement in a pre- to early-collisional stage between 643 and 628 Ma. Geochemical data reveal a magnesian nature and affinities with the high-K calc-alkaline and shoshonite magmatic series. REE and multielement spectra exhibit enrichment in light REE and large ion lithophile elements, with deep troughs at Ti-Nb-Ta, typically interpreted as a subduction setting signature. Whole-rock isotope data indicate an evolved signature with subchondritic Nd (εNd(t) = -2.0 a -5.2) e radiogenic Sr (87Sr/86Sr(t) = 0.708-0.710), and Pb (206Pb/204Pb = 18.50-19.18; 207Pb/204Pb = 15.69-15.77; 208Pb/204Pb = 38.54-40.04), indicating derivation from an enriched mantle source. High 87Sr/86Sr(t) and Rb/Sr ratios, together with low Sr/Th and Ba/Rb ratios, suggest that the enrichment episode occurred in response to the introduction of sedimentary components in the mantle via subduction processes, leading to the formation of phlogopite as the main metasomatic phase. Hf-TDMC model ages between 2.47 and 2.09 Ga suggest that the enrichment of the lithospheric mantle beneath the southern Borborema Province occurred during the accretionary events of the Rhyacian Orogeny. Incorporating sediments by the mantle peridotites may have led to increasing Rb/Sr, (U-Th)/Pb coupled with decreasing Sm/Nd and Lu/Hf ratios, which resulted in the time-integrated crustal signature observed in the mafic rocks. (ii) Biotite- and muscovite-bearing leucocratic granodiorites, monzogranites, and syenogranites outcrop as stocks and sheets. They show magmatic foliation marked by the orientation of micas and surmicaceous enclaves, parallel to the schistosity of country rocks, indicating synchronous emplacement to the collisional event between 630 and 624 Ma. Leucogranites are metaluminous to strongly peraluminous, high-K calc-alkaline, and magnesian to ferroan. εNd(t) values and Nd-TDM model ages overlap those of their host5 rocks, suggesting derivation from mostly sedimentary protholiths. (iii) The younger group consists of monzonites, quartz-monzonites, granodiorites, and granites, with crystallization ages from 625 to 603 Ma. They are predominantly isotropic and truncate the regional foliation of the country rocks, indicating a late emplacement relative to the collisional event. The metaluminous and magnesian signatures, with high-K calc-alkaline and shoshonite filiations, resemble the composition of experimental liquids obtained by partial melting of basalt protoliths moderately enriched in incompatible elements. Lu-Hf isotope data provided subchondritic εHf(t) values between -8.3 and 4.0 with Hf-TDMC model ages from 1.77 to 2.03, indicating the reworking of ancient continental crust, possibly related to the Cariris Velhos event. The geochemical and isotopic data of this study, together with those available in the literature allows us to infer that the Neoproterozoic geodynamic evolution of the SOS along the western Gondwana margin can be explained by a lithospheric extension of the Borborema Province basement, followed by basin inversion, and continental collision.
Acesso aberto (Open Access)
Evolução geológica da porção centro-sul do Escudo Guianas com base no estudo geoquímico, geocronológico (evaporação de Pb e U-Pb ID-TIMS em zircão) e isótopo (Nd-Pb) dos granitóides paleoproterozóicos do sudeste de Roraima, Brasil
(Universidade Federal do Pará, 2006-11-17) ALMEIDA, Marcelo Esteves; MACAMBIRA, Moacir José Buenano; http://lattes.cnpq.br/8489178778254136
This study focuses the granitoids of center-southern portion of Guyana Shield, southeastern Roraima, Brazil. The region is characterized by two tectono-stratigraphic domains, named as Central Guyana (GCD) and Uatumã-Anauá (UAD) and located probably in the limits of geochronological provinces (e.g. Ventuari-Tapajós or Tapajós-Parima, Central Amazonian and Maroni-Itacaiúnas or Transamazon). The aim this doctoral thesis is to provide new petrological and lithostratigraphical constraints on the granitoids and contribute to a better understanding of the origin and geodynamic evolution of Guyana Shield. The GCD is only locally studied near to the UAD boundary, and new geological data and two single zircon Pb-evaporation ages in mylonitic biotite granodiorite (1.89 Ga) and foliated hastingsite-biotite granite (1.72 Ga) are presented. These ages of the protholiths contrast with the lithostratigraphic picture in the other areas of CGD (1.96-1.93 Ga). Regional mapping, petrography, geochemistry and zircon geochronology carried out in the UAD have showed widespread paleoproterozoic calc-alkaline granitic magmatism. These granitoids are distributed into several magmatic associations with different paleoproterozoic (1.97-1.89 Ga) ages, structural and geochemical affinities. Detailed mapping, petrographic and geochronological studies have distinguished two main subdomains in UAD. In the northern UAD, the high-K calc-alkaline Martins Pereira (1.97 Ga) and Serra Dourada S-type granites (1.96 Ga) are affected by NE-SW and E-W ductile dextral shear-zones, showing coexistence of magmatic and deformational fabrics related to heterogeneous deformation. Inliers of basement (2.03 Ga) crop out to northeastern part of this area, and are formed by metavolcano-sedimentary sequence (Cauarane Group) and TTG-like calc-alkaline association (Anauá Complex). Xenoliths of meta-diorites (Anauá Complex) and paragneisses (Cauarane Group) reinforce the intrusive character of Martins Pereira Granite. On the other hand, xenoliths of Martins Pereira and biotitebearing enclaves are founded in the younger, undeformed, and SiO2-rich Igarapé Azul Granite (1.89 Ga). This last and the high-K calc-alkaline Caroebe Granite (1.90-1.89 Ga, Água Branca Suite), including coeval volcanic rocks (1.89 Ga, Jatapu volcanics) and charnockitoids (1.89 Ga, e.g. Santa Maria Enderbite), crop out in the southern UAD. This subdomain is characterized only by local and slight NE-SW ductile-brittle dextral shear zones. A-type granites such as Moderna (ca. 1.81 Ga) and Mapuera (ca. 1.87 Ga) granites, cross cut both areas of UAD. Furthermore, the geological mapping also identified three main types of metalotects in this region. Gold mineralization is observed in Martins Pereira-Serra Dourada granitoids (northern UAD), alluvial columbite-tantalite is related to Igarapé Azul granitoids (southern UAD), and amethyst is associated to pegmatites from Moderna A-type granites. The Nd-Pb isotope data suggest that all granitoids of UAD are generated by reworking of older and pre-existence crustal sources (sialic Rhyacian-Archean and/or juvenile Transamazonian origin) and mantle input is not problably a viable model. Although the dominant process may be one subduction in the early stage of NUAD evolution, post-colisional magmatism may be a significant process in the production of new continental crust in the southern UAD. It is possible that, following oceanic closure in the Anauá arc system (2.03 Ga) and subsequent collisional orogeny (1.97-1.94 Ga?), underplated mantle melts (basalt liquids) were trapped below preexisting lower crustal rocks of various compositions (e.g. granulites, metatonalites, amphibolites). The basalt liquids and subsequently melted lower crust could produced the immense volumes of granite (and volcanics) observed at 1.90-1.87 Ga. This geological picture is similar to the Tapajós Domain (TD) in the southern Amazonian Craton and suggest that both belongs to the same province (Ventuari-Tapajós or Tapajós-Parima). Nevertheless, the scarcity of S-type granites and high-grade metamorphic rocks show that the collisional stage is not so evident in TD.