ITEC - Instituto de Tecnologia
URI Permanente desta comunidadehttps://repositorio.ufpa.br/handle/2011/25
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Navegando ITEC - Instituto de Tecnologia por Assunto "Ácidos graxos"
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Item Acesso aberto (Open Access) Chemical composition of different muscle zones in pirarucu (Arapaima gigas)(Universidade Federal do Pará, 2017-04) MARTINS, Mayara Galvão; MARTINS, Déborah Elena Galvão; PENA, Rosinelson da SilvaIdentifying potential patterns in pirarucu (Arapaima gigas) composition, as a function of the different fish muscle zones (dorse, venter, ventrecha and tail), was the main objective of this research. For such, the different pirarucu muscle zones were evaluated, in order to obtain proximate composition and minerals content. It was also determined amino acids and fatty acids contents in fish muscle. The dorsal, ventral and tail muscle zones presented similar moisture (76.5-78.2%), protein (17.8-18.9%), total lipids (1.0-1.5%) and ash (0.9-1.2%) contents. On the other hand, the ventrecha zone presented 25.8% of protein and the major total lipids content (17.1%). The main minerals found in fish muscle were K (183.5-288.6 mg/100 g muscle) and Na (65.1-175.5 mg/100 g). Glutamic acid (3027.6 mg/100 g muscle) was the main amino acid found in fish muscle, which presented 48% of essential amino acids in the protein fraction. Lipids content showed 57.3% of unsaturated fatty acids and 42.7% of saturated fatty acids.Item Acesso aberto (Open Access) Fatty acid profiles and tocopherol contents of buriti (Mauritia flexuosa), patawa (Oenocarpus bataua), tucuma (Astrocaryum vulgare), mari (Poraqueiba paraensis) and inaja (Maximiliana maripa) fruits(2010) RODRIGUES, Antonio Manoel da Cruz; DARNET, Sylvain Henri; SILVA, Luiza Helena Meller daAmazonian fruits are rich in fat but have a fatty acid profile that may be beneficial in relation to risk of coronary heart disease. Amazonian fruits also contain other potentially cardioprotective constituents including tocopherols. Tocopherol profiles were determined by high performance liquid chromatography (HPLC), and fatty acid profiles were determined by gas chromatography (GC). In the present study, the total oil content, fatty acid composition and tocopherol content of the pulps of five Amazonian fruits (buriti, patawa, tucuma, mari and inaja) were measured. The total oil content of the fruits ranged from 31.0 to 41.8%. The major fatty acid in all of the fruits was oleic acid (C18:1), though substantial levels of palmitic acid (C16:0) were present. Linoleic acid (C18:2) was the main polyunsatured fatty acid observed. α-Tocopherol was the most prevalent tocopherol except in buriti pulp. Buriti and mari pulp have a high content in α-tocopherols with 297 and 155 µg g-1 of dry matter. Our data indicate that all five of these Amazonian fruits are good sources of unsaturated fatty acids and tocopherols.Item Acesso aberto (Open Access) High pressure vapor-liquid equilibria of palm fatty acids distillates-carbon dioxide system(1997-12) MACHADO, Nélio Teixeira de; BRUNNER, GerdVapor-Liquid equilibria of palm fatty acids distillates/carbon dioxide system has been investigated experimentally at temperatures of 333, 353, and 373 K and pressures of 20, 23, 26, and 29 MPa using the static method. Experimental data for the quasi-binary system palm fatty acids distillates/carbon dioxide has been correlated with Redlich-Kwong-Aspen equation of state. Modeling shows good agreement with experimental data. Selectivity obtained indicates that supercritical carbon dioxide is a reasonable solvent for separating saturated (palmitic acid) and unsaturated (oleic+linoleic acids) fatty acids from palm fatty acids distillates in a continuous multistage countercurrent column.Item Acesso aberto (Open Access) Nutritional composition, fatty acid and tocopherol contents of buriti (Mauritia flexuosa) and patawa (Oenocarpus bataua) fruit pulp from the amazon region(2011-06) DARNET, Sylvain Henri; SILVA, Luiza Helena Meller da; RODRIGUES, Antonio Manoel da Cruz; LINS, Roseana TellesBuriti and patawa are two endemic palm trees from the Amazon region. Their pulps are traditionally consumed by the local population, but are underused and lesser known worldwide. Nutritional composition, fatty acid and tocopherol contents of the two palm pulps were determined by modern analytical methods: Gas Chromatography (CG) and High Performance Liquid Chromatography (HPLC), based on the standards of AOCS (AMERICAN..., 2002) and AOAC (ASSOCIATION..., 1997), respectively. Buriti and patawa fruit pulps are highly nutritive, with respectively, high fat content (38.4% and 29.1% of dry matter (DM)), protein content (7.6% and 7.4% of DM) and dietary fibers (46% and 44.7% of DM). Buriti pulp can be considered healthy food due its high content of vitamin E (1169 µg.g-1 DM). Patawa pulp is highly oleaginous and its fatty acid composition is very similar to the ones of healthy oils, such as olive oil.Item Acesso aberto (Open Access) Separation of satured and unsaturated fatty acids from palm fatty acids distillates in continuous multistage countercurrent columns with supercritical carbon dioxide as solvent: a process design methodology(1997-12) MACHADO, Nélio Teixeira de; BRUNNER, GerdIn this work the separation of multicomponent mixtures in counter-current columns with supercritical carbon dioxide has been investigated using a process design methodology. First the separation task must be defined, then phase equilibria experiments are carried out, and the data obtained are correlated with thermodynamic models or empirical functions. Mutual solubilities, Ki-values, and separation factors aij are determined. Based on this data possible operating conditions for further extraction experiments can be determined. Separation analysis using graphical methods are performed to optimize the process parameters. Hydrodynamic experiments are carried out to determine the flow capacity diagram. Extraction experiments in laboratory scale are planned and carried out in order to determine HETP values, to validate the simulation results, and to provide new materials for additional phase equilibria experiments, needed to determine the dependence of separation factors on concetration. Numerical simulation of the separation process and auxiliary systems is carried out to optimize the number of stages, solvent-to-feed ratio, product purity, yield, and energy consumption. Scale-up and cost analysis close the process design. The separation of palmitic acid and (oleic+linoleic) acids from PFAD-Palm Fatty Acids Distillates was used as a case study.